SENSING MECHANISM AND APPLICATION OF MECHANICAL STRAIN SENSOR: A MINI-REVIEW

This study reviews the potential of flexible strain sensors based on nanomaterials such as carbon nanotubes (CNTs), graphene, and metal nanowires (NWs). These nanomaterials have excellent flexibility, conductivity, and mechanical properties, which enable them to be integrated into clothing or attached to the skin for the real-time monitoring of various activities. However, the main challenge is balancing high stretchability and sensitivity. This paper explains the basic concept of strain sensors that can convert mechanical deformation into electrical signals. Moreover, this paper focuses on simple, flexible, and stretchable resistive and capacitive sensors. It also discusses the important factors in choosing materials and fabrication methods, emphasizing the crucial role of suitable polymers in high-performance strain sensing. This study reviews the fabrication processes, mechanisms, performance, and applications of stretchable strain sensors in detail. It analyzes key aspects, such as sensitivity, stretchability, linearity, response time, and durability. This review provides useful insights into the current status and prospects of stretchable strain sensors in wearable technology and human–machine interfaces

Effect of Mechanical Properties of Substrates on Flexibility of Ag Nanowire Electrodes under a Large Number of Bending Cycles

Ag nanowire electrodes have attracted considerable attention because of their potential applications in next-generation flexible electronics. However, there is a paucity of studies on the mechanical properties of Ag nanowire electrodes subjected to a large number of bending cycles. In this study, the effects of the substrate on the mechanical behavior of Ag nanowire electrodes were studied for a high bending frequency. The mechanical reliability of the Ag nanowire electrodes fabricated on a polyethylene terephthalate (PET) substrate was better than that for a polyimide (PI) substrate; the increase in the resistance of the PET-based Ag nanowire electrode was 1.07%, while that of the PI-based one was 1.23%. Nanoindentation tests showed that the elastic modulus of PI was larger than that of PET. This resulted in a lower bending strain on PET-based Ag nanowire electrodes compared to those on PI-based ones, because of the smaller distance from the neutral plane of the PET-based system. Our study showed that the mechanical properties of the substrate influenced the strain imposed on the thin layer on the substrates, which, in turn, determines the mechanical reliability of the thin-layer/substrate multilayer system

Polypyrrole–MnO₂‑Coated Textile-Based Flexible-Stretchable Supercapacitor with High Electrochemical and Mechanical Reliability

Carbon-nanotube (CNT)-based textile supercapacitors with MnO₂ nanoparticles have excellent power and energy densities, but MnO₂ nanoparticles can be delaminated during charge–discharge cycles, which results in significant degradation in capacitance. In this study, polypyrrole conductive polymer was coated on top of MnO₂ nanoparticles that are deposited on CNT textile supercapacitor to prevent delamination of MnO₂ nanoparticles. An increase of 38% in electrochemical energy capacity to 461 F/g was observed, while cyclic reliability also improved, as 93.8% of energy capacity was retained over 10 000 cycles. Energy density and power density were measured to be 31.1 Wh/kg and 22.1 kW/kg, respectively. An in situ electrochemical–mechanical study revealed that polypyrrole–MnO₂-coated CNT textile supercapacitor can retain 98.5% of its initial energy capacity upon application of 21% tensile strain and showed no observable energy storage capacity change upon application of 13% bending strain. After imposing cyclic bending of 750 000 cycles, the capacitance was retained to 96.3%. Therefore, the results from this study confirmed for the first time that the polypyrrole–MnO₂-coated CNT textile can reliably operate with high energy and power densities with in situ application of both tensile and bending strains

Highly Reliable Yarn-Type Supercapacitor Using Conductive Silk Yarns with Multilayered Active Materials

The fibrous supercapacitor is a promising candidate for wearable energy-storage systems due to excellent mechanical reliability under deformation. In this study, a mechanically reliable fibrous supercapacitor with high volumetric power density and energy density was developed using fiber electrodes composed of multilayered active materials coated on silk yarns. The conductive silk yarn electrodes are fabricated via a sequential dip-coating process of silver nanowires, multi-walled carbon nanotubes (MWCNT, three to seven walls), and poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS). The composite-coated silk yarn electrodes were stable under cyclic bending as well as under washing in water. Due to the synergetic effect of the three conducting materials, an excellent electrochemical performance was obtained resulting in high volumetric energy and power densities of 8–13 mWh cm−3 and 8–19\ua0W cm−3, respectively. A yarn-type supercapacitor was demonstrated by integrating composite-coated silk yarn electrodes with a hydrogel electrolyte, showing a promising stability as evidenced by the retention of over 94% and 93% of the specific capacitance after 90-degree bending and stretching

Three-Dimensional Nanofibrous Air Electrode Assembled With Carbon Nanotubes-Bridged Hollow Fe₂O₃ Nanoparticles for High-Performance Lithium–Oxygen Batteries

Lithium–oxygen batteries have been considered as one of the most viable energy source options for electric vehicles due to their high energy density. However, they are still faced with technical challenges, such as low round-trip efficiency and short cycle life, which mainly originate from the cathode part of the battery. In this work, we designed a three-dimensional nanofibrous air electrode consisted of hierarchically structured carbon nanotube-bridged hollow Fe₂O₃ nanoparticles (H-Fe₂O₃/CNT NFs). Composite nanofibers consisted of hollow Fe₂O₃ NPs anchored by multiple CNTs offered enhanced catalytic sites (interconnected hollow Fe₂O₃ NPs) and fast charge-transport highway (bridged CNTs) for facile formation and decomposition of Li₂O₂, leading to outstanding cell performance: (1) Swagelok cell exhibited highly reversible cycling characteristics for 250 cycles with a fixed capacity of 1000 mAh g^–1 at a current density of 500 mA g^–1. (2) A module composed of two pouch-type cells stably powered an light-emitting diode lamp operated at 5.0 V