A Born-Oppenheimer photolysis model of N_2O fractionation

The isotopically light N_2O produced by microbial activity is thought to be balanced by the return of heavy stratospheric nitrous oxide. The Yung and Miller [1997] method that first explained these trends yields photolytic fractionation factors ∼half those observed by experiment or predicted quantum mechanically, however. To address these issues, we present here a Born-Oppenheimer photolysis model that uses only commonly available spectroscopic data. The predicted fractionations quantitatively reproduce laboratory data, and have been incorporated into zonally averaged atmospheric simulations. Like McLinden et al. [2003] , who employ a three-dimensional chemical transport model with cross sections scaled to match laboratory data, we find excellent agreement between predictions and stratospheric measurements; additional processes that contribute to the mass independent anomaly in N_2O can only account for a fraction of its global budget

Nitrogen Incorporation in CH_4-N_2 Photochemical Aerosol Produced by Far Ultraviolet Irradiation

Nitrile incorporation into Titan aerosol accompanying hydrocarbon chemistry is thought to be driven by extreme UV wavelengths (λ120 nm is presently unaccounted for in atmospheric photochemical models. We suggest that reaction with CH radicals produced from CH_4 photolysis may provide a mechanism for incorporating N into the molecular structure of the aerosol. Further work is needed to understand the chemistry involved, as these processes may have significant implications for how we view prebiotic chemistry on early Earth and similar planets. Key Words: Titan—Photochemical aerosol—CH_4-N_2 photolysis—Far UV—Nitrogen activation

Photolytically generated aerosols in the mesosphere and thermosphere of Titan

Analysis of the Cassini Ultraviolet Imaging Spectrometer (UVIS) stellar and solar occultations at Titan to date include 12 species: N$_{2}$ (nitrogen), CH$_{4}$ (methane), C$_{2}$H$_{2}$ (acetylene), C$_{2}$H$_{4}$ (ethylene), C$_{2}$H$_{6}$ (ethane), C$_{4}$H$_{2}$ (diacetylene), C$_{6}$H$_{6}$ (benzene), C$_{6}$N$_{2}$ (dicyanodiacetylene), C$_{2}$N$_{2}$ (cyanogen), HCN (hydrogen cyanide), HC$_{3}$N (cyanoacetylene), and aerosols distinguished by a structureless continuum extinction (absorption plus scattering) of photons in the EUV. The introduction of aerosol particles, retaining the same refractive index properties as tholin with radius $\sim$125 \AA and using Mie theory, provides a satisfactory fit to the spectra. The derived vertical profile of aerosol density shows distinct structure, implying a reactive generation process reaching altitudes more than 1000 km above the surface. A photochemical model presented here provides a reference basis for examining the chemical and physical processes leading to the distinctive atmospheric opacity at Titan. We find that dicyanodiacetylene is condensable at $\sim$650 km, where the atmospheric temperature minimum is located. This species is the simplest molecule identified to be condensable. Observations are needed to confirm the existence and production rates of dicyanodiacetylene.Comment: A typo in Table 1 was made in the previous version. The corrected tholin abundance is 4.6x10^11. ApJL in press. Will be published on June 1st, or May 21 onlin

Aerosol influence on energy balance of the middle atmosphere of Jupiter

Aerosols are ubiquitous in planetary atmospheres in the Solar System. However, radiative forcing on Jupiter has traditionally been attributed to solar heating and infrared cooling of gaseous constituents only, while the significance of aerosol radiative effects has been a long-standing controversy. Here we show, based on observations from the NASA spacecraft Voyager and Cassini, that gases alone cannot maintain the global energy balance in the middle atmosphere of Jupiter. Instead, a thick aerosol layer consisting of fluffy, fractal aggregate particles produced by photochemistry and auroral chemistry dominates the stratospheric radiative heating at middle and high latitudes, exceeding the local gas heating rate by a factor of 5–10. On a global average, aerosol heating is comparable to the gas contribution and aerosol cooling is more important than previously thought. We argue that fractal aggregate particles may also have a significant role in controlling the atmospheric radiative energy balance on other planets, as on Jupiter

Nitrogen Incorporation in CH4-N2 Photochemical Aerosol Produced by Far UV Irradiation

Nitrile incorporation into Titan aerosol accompanying hydrocarbon chemistry is thought to be driven by extreme UV wavelengths (lambda 120 nm is presently unaccounted for in atmospheric photochemical models. We suggest that reaction with CH radicals produced from CH4 photolysis may provide a mechanism for incorporating N into the molecular structure of the aerosol. Further work is needed to understand the chemistry involved, as these processes may have significant implications for prebiotic chemistry on the early Earth and similar planets

{BOAO Photometric Survey of Galactic Open Clusters. II. Physical Parameters of 12 Open Clusters

We have initiated a long-term project, the BOAO photometric survey of open clusters, to enlarge our understanding of galactic structure using UBVI CCD photometry of open clusters which have been little studied before. This is the second paper of the project in which we present the photometry of 12 open clusters. We have determined the cluster parameters by fitting the Padova isochrones to the color-magnitude diagrams of the clusters. All the clusters except for Be 0 and NGC 1348 are found to be intermediate-age to old (0.2 - 4.0 Gyrs) open clusters with a mean metallicity of [Fe/H] = 0.0.Comment: 11 page

ПРООКСИДАНТНО-АНТИОКСИДАНТНИЙ СТАТУС У ХВОРИХ ІЗ ЗАПАЛЬНО-ДЕСТРУКТИВНИМИ УРАЖЕННЯМИ ПАРОДОНТА НА ТЛІ ГАСТРОЕЗОФАГЕАЛЬНОЇ РЕФЛЮКСНОЇ ХВОРОБИ ЗАЛЕЖНО ВІД ПЕРЕБІГУ ЗАХВОРЮВАННЯ

У проведених дослідженнях довели, що у хворих із пародонтитом на тлі гастроезофагеальної рефлюксної хвороби в пацієнтів з ерозивною формою та ураженням тканин пародонта виявлено підвищення рівня малонового діальдигіду, зниження активності супероксиддисмутази й порушення рівноваги у системах пероксидного окиснення ліпідів та атиоксидантного захисту, порівняно з пацієнтами з гінгівітом на тлі ерозивної та неерозивної форм захворювання, так і стосовно хворих з інтактним пародонтом й гастроезофагеальною рефлюксною хворобою

Raman Spectroscopy Study of Rotated Double-Layer Graphene: Misorientation-Angle Dependence of Electronic Structure

We present a systematic Raman study of unconventionally stacked double-layer graphene, and find that the spectrum strongly depends on the relative rotation angle between layers. Rotation-dependent trends in the position, width and intensity of graphene 2D and G peaks are experimentally established and accounted for theoretically. Our theoretical analysis reveals that changes in electronic band structure due to the interlayer interaction, such as rotational-angle dependent Van Hove singularities, are responsible for the observed spectral features. Our combined experimental and theoretical study provides a deeper understanding of the electronic band structure of rotated double-layer graphene, and leads to a practical way to identify and analyze rotation angles of misoriented double-layer graphene.open1048

Constraints on Pluto’s H and CH₄ profiles from New Horizons Alice Lyα observations

The Alice spectrograph on New Horizons performed several far-ultraviolet (FUV) airglow observations during the July 2015 flyby of Pluto. One of these observations, named PColor2, was a short (226 s) scan across the dayside disk of Pluto from a range of ∼34,000 km, at about 40 minutes prior to closest approach. The brightest observed FUV airglow signal at Pluto is the Lyman alpha (Lyα) emission line of atomic hydrogen, which arises primarily through the resonant scattering of solar Lyα by H atoms in the upper atmosphere, with a brightness of about 30 Rayleighs. Pluto appears dark against the much brighter (∼100 Rayleigh) sky background; this sky background is likewise the result of resonantly scattered solar Lyα, in this case by H atoms in the interplanetary medium (IPM). Here we use an updated photochemical model and a resonance line radiative transfer model to perform detailed simulations of the Lyα emissions observed in the Alice PColor2 scan. The photochemical models show that H and CH₄ abundances in Pluto’s upper atmosphere are a very strong function of the near-surface mixing ratio of CH₄, and could provide a useful way to remotely monitor seasonal climate variations in Pluto’s lower atmosphere. The morphology of the PColor2 Lyα emissions provides constraints on the current abundance profiles of H atoms and CH₄ molecules in Pluto’s atmosphere, and indicate that the globally averaged near-surface mixing ratio of CH₄ is currently close to 0.4%. This new result thus provides independent confirmation of one of the primary results from the solar occultation, also observed with the New Horizons Alice ultraviolet spectrograph

Constraints on Pluto’s H and CH₄ profiles from New Horizons Alice Lyα observations

The Alice spectrograph on New Horizons performed several far-ultraviolet (FUV) airglow observations during the July 2015 flyby of Pluto. One of these observations, named PColor2, was a short (226 s) scan across the dayside disk of Pluto from a range of ∼34,000 km, at about 40 minutes prior to closest approach. The brightest observed FUV airglow signal at Pluto is the Lyman alpha (Lyα) emission line of atomic hydrogen, which arises primarily through the resonant scattering of solar Lyα by H atoms in the upper atmosphere, with a brightness of about 30 Rayleighs. Pluto appears dark against the much brighter (∼100 Rayleigh) sky background; this sky background is likewise the result of resonantly scattered solar Lyα, in this case by H atoms in the interplanetary medium (IPM). Here we use an updated photochemical model and a resonance line radiative transfer model to perform detailed simulations of the Lyα emissions observed in the Alice PColor2 scan. The photochemical models show that H and CH₄ abundances in Pluto’s upper atmosphere are a very strong function of the near-surface mixing ratio of CH₄, and could provide a useful way to remotely monitor seasonal climate variations in Pluto’s lower atmosphere. The morphology of the PColor2 Lyα emissions provides constraints on the current abundance profiles of H atoms and CH₄ molecules in Pluto’s atmosphere, and indicate that the globally averaged near-surface mixing ratio of CH₄ is currently close to 0.4%. This new result thus provides independent confirmation of one of the primary results from the solar occultation, also observed with the New Horizons Alice ultraviolet spectrograph