The Couplings of Rock/Carbonate Groundwater/Cement Leachate

Hyper-alkaline cement leachates generated from the cement buffer of a nuclear waste disposal site have significant influences on the mineralogy of the host rock, creating a chemically disturbed zone (CDZ). Three major types of cement leachates are formed during the evolution process. Most of the existing scenario modelling research has been focused on the influence of the cement leachate on the host rock. However, the influence of the groundwater in the host rock on the evolution of the CDZ remains unexplored. This paper presents a numerical scenario modelling of the couplings among carbonate groundwater, cement leachates and rock minerals. The results reveal that the high carbonate groundwater significantly affects the precipitation of calcium silicate hydrate (C-S-H) and calcite, and consequently alters the physical and chemical properties of the host rock. This finding provides an essential guide for selection of the location of geological disposal facility (GDF) in terms of the groundwater chemistry

Importance of soil thermal regime in terrestrial ecosystem carbon dynamics in the circumpolar north

© The Author(s), 2016. This is the author's version of the work and is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Global and Planetary Change 142 (2016): 28-40, doi:10.1016/j.gloplacha.2016.04.011.In the circumpolar north (45-90°N), permafrost plays an important role in vegetation and carbon (C) dynamics. Permafrost thawing has been accelerated by the warming climate and exerts a positive feedback to climate through increasing soil C release to the atmosphere. To evaluate the influence of permafrost on C dynamics, changes in soil temperature profiles should be considered in global C models. This study incorporates a sophisticated soil thermal model (STM) into a dynamic global vegetation model (LPJ-DGVM) to improve simulations of changes in soil temperature profiles from the ground surface to 3 m depth, and its impacts on C pools and fluxes during the 20th and 21st centuries.With cooler simulated soil temperatures during the summer, LPJ-STM estimates ~0.4 Pg C yr-1 lower present-day heterotrophic respiration but ~0.5 Pg C yr-1 higher net primary production than the original LPJ model resulting in an additional 0.8 to 1.0 Pg C yr-1 being sequestered in circumpolar ecosystems. Under a suite of projected warming scenarios, we show that the increasing active layer thickness results in the mobilization of permafrost C, which contributes to a more rapid increase in heterotrophic respiration in LPJ-STM compared to the stand-alone LPJ model. Except under the extreme warming conditions, increases in plant production due to warming and rising CO2, overwhelm the enhanced ecosystem respiration so that both boreal forest and arctic tundra ecosystems remain a net C sink over the 21st century. This study highlights the importance of considering changes in the soil thermal regime when quantifying the C budget in the circumpolar north.This research is supported by funded projects to Q. Z. National Science Foundation (NSF- 1028291 and NSF- 0919331), the NSF Carbon and Water in the Earth Program (NSF-0630319), the NASA Land Use and Land Cover Change program (NASA- NNX09AI26G), and Department of Energy (DE-FG02-08ER64599).2017-05-0

Extremely thinned continental crust underneath the Ligurian Basin?

The Ligurian Basin is situated at the transition from the western Alpine orogeny to the Apennine system, an area where a change in subduction polarity is observed. The back-arc basin was generated by the southeast trench retreat of the Apennines-Calabrian subduction zone. The opening took place from late Oligocene to Miocene. While the extension led to continental thinning and subsidence, oceanic spreading with unroofing of mantle material was proposed for the late opening period, 21-16 Ma. To shed light on the present day crustal and lithospheric architecture of the Ligurian Basin, active and passive seismic data have been recorded on ocean bottom seismometers of a long-term network consisting of 29 broad-band stations, installed from June 2017 to February 2018 in the framework of SPP2017 4D-MB, the German component of AlpArray. Two refraction seismic profiles were shot to serve two aspects: (1) Determine the orientation of the horizontal components of the long-term instruments and (2) estimate the velocity distribution of the upper lithosphere, to provide a velocity model for the passive seismic data analysis. Good quality data have been recorded, regional and teleseismic events as well as active shots could be detected by the network stations. The majority of the refraction seismic data show mantle phases at offsets up to 70 km and a very prominent wide-angle reflection originating at the crust mantle boundary. Its features share a number of characteristics (i.e. offset range, continuity) generally associated with continental settings rather than mimicking seafloor spreading lithosphere emplaced in back-arc basins. Based on traveltime tomography along the refraction lines, the crust-mantle boundary is determined at ~9.5 km depth below seafloor. The acoustic basement is difficult to map seismically. The transition to the crystalline basement is indicated at a depth of ~6.5 km below seafloor. The absolute seismic velocities can be interpreted as hyper-extended continental crust or serpentinised mantle. The thick sedimentary coverage allows for long lasting extension of the crust. The crustal portion interpreted from the seismic velocities thickens towards the north which is in good agreement with the anti-clockwise rotation of the Corsica-Sardinia block and an associated gradual opening of the Ligurian Basin