2,485 research outputs found
Combinatorial screening yields discovery of 29 metal oxide photoanodes for solar fuel generation
Combinatorial synthesis combined with high throughput electrochemistry enabled discovery of 29 ternary oxide photoanodes, 15 with visible light response for oxygen evolution. Y₃Fe₅O₁₂ and trigonal V₂CoO₆ emerge as particularly promising candidates due to their photorepsonse at sub-2.4 eV illumination
The physical origin of the periodic activity for FRB 20180916B
Fast radio bursts (FRBs) are transient radio signals with
millisecond-duration, large dispersion measure (DM) and extremely high
brightness temperature. Among them, FRB 20180916B has been found to have a
16-day periodic activity. However, the physical origin of the periodicity is
still a mystery. Here, we utilize the comprehensive observational data to
diagnose the periodic models. We find that the ultra-long rotation model is the
most probable one for the periodic activity. However, this model cannot
reproduce the observed rotation measure (RM) variations. We propose a
self-consistent model, i.e., a massive binary containing a slowly rotational
neutron star and a massive star with large mass loss, which can naturally
accommodate the wealth of observational features for FRB 20180916B. In this
model, the RM variation is periodic, which can be tested by future
observations.Comment: 12 pages, 8 figure
Efficient electronic entanglement concentration assisted with single mobile electron
We present an efficient entanglement concentration protocol (ECP) for mobile
electrons with charge detection. This protocol is quite different from other
ECPs for one can obtain a maximally entangled pair from a pair of
less-entangled state and a single mobile electron with a certain probability.
With the help of charge detection, it can be repeated to reach a higher success
probability. It also does not need to know the coefficient of the original
less-entangled states. All these advantages may make this protocol useful in
current distributed quantum information processing.Comment: 6pages, 3figure
Spatial optical solitons in nonlinear photonic crystals
We study spatial optical solitons in a one-dimensional nonlinear photonic
crystal created by an array of thin-film nonlinear waveguides, the so-called
Dirac-comb nonlinear lattice. We analyze modulational instability of the
extended Bloch-wave modes and also investigate the existence and stability of
bright, dark, and ``twisted'' spatially localized modes in such periodic
structures. Additionally, we discuss both similarities and differences of our
general results with the simplified models of nonlinear periodic media
described by the discrete nonlinear Schrodinger equation, derived in the
tight-binding approximation, and the coupled-mode theory, valid for shallow
periodic modulations of the optical refractive index.Comment: 15 pages, 21 figure
Enhanced Bulk Transport in Copper Vanadate Photoanodes Identified by Combinatorial Alloying
The impact of alloying on the performance of β-Cu₂V₂O₇ photoanodes was investigated using inkjet printing of composition libraries containing 1,809 Cu₂V₂O₇-based photoanodes. Six elements (Zr, Ca, Hf, Gd, La, and Lu) were alloyed and pairwise co-alloyed at concentrations up to 7 at % into Cu-rich, stoichiometric, and Cu-deficient host Cu₂V₂O₇. A 1.7-fold increase in oxygen evolution photocurrent in pH 9.2 electrolyte was obtained by alloying Ca into β-Cu₂V₂O₇. Experiments employing a hole scavenger to better characterize bulk charge separation and transport revealed a 2.2-fold increase in photoactivity via alloying with Hf, Zr, and La, which increased to 2.7-fold upon co-alloying these elements with Ca. Concurrent with increased photoactivity is substantially decreased photon absorption between 1.5 and 2 eV, a range reported to coincide with high exciton absorption in β-Cu₂V₂O₇, motivating further exploration of whether these co-alloy compositions may destabilize the excitonic state that appears to have limited performance to date
Enhanced Bulk Transport in Copper Vanadate Photoanodes Identified by Combinatorial Alloying
The impact of alloying on the performance of β-Cu₂V₂O₇ photoanodes was investigated using inkjet printing of composition libraries containing 1,809 Cu₂V₂O₇-based photoanodes. Six elements (Zr, Ca, Hf, Gd, La, and Lu) were alloyed and pairwise co-alloyed at concentrations up to 7 at % into Cu-rich, stoichiometric, and Cu-deficient host Cu₂V₂O₇. A 1.7-fold increase in oxygen evolution photocurrent in pH 9.2 electrolyte was obtained by alloying Ca into β-Cu₂V₂O₇. Experiments employing a hole scavenger to better characterize bulk charge separation and transport revealed a 2.2-fold increase in photoactivity via alloying with Hf, Zr, and La, which increased to 2.7-fold upon co-alloying these elements with Ca. Concurrent with increased photoactivity is substantially decreased photon absorption between 1.5 and 2 eV, a range reported to coincide with high exciton absorption in β-Cu₂V₂O₇, motivating further exploration of whether these co-alloy compositions may destabilize the excitonic state that appears to have limited performance to date
Single-molecule magnet behavior in 2,2 \u27-bipyrimidine-bridged dilanthanide complexes
A series of 2,2’-bipyrimidine-bridged dinuclear lanthanide complexes with the general formula [Ln(tmhd)3]2bpm (tmhd = 2,2,6,6-tetramethyl-3,5-heptanedionate, bpm = 2,2’-bipyrimidine, Ln = Gd(III), 1; Tb(III), 2; Dy(III), 3; Ho(III), 4 and Er(III), 5) has been synthesized and characterized. Sublimation of [Tb(tmhd)3]2bpm onto a Au(111) surface leads to the formation of a homogeneous film with hexagonal pattern, which was studied by scanning tunneling microscopy (STM). The bulk magnetic properties of all complexes have been studied comprehensively. The dynamic magnetic behavior of the Dy(III) and Er(III) compounds clearly exhibits single molecule magnet (SMM) characteristics with an energy barrier of 97 and 25 K, respectively. Moreover, micro-SQUID measurements on single crystals confirm their SMM behavior with the presence of hysteresis loops
Combinatorial screening yields discovery of 29 metal oxide photoanodes for solar fuel generation
Combinatorial synthesis combined with high throughput electrochemistry enabled discovery of 29 ternary oxide photoanodes, 15 with visible light response for oxygen evolution. Y₃Fe₅O₁₂ and trigonal V₂CoO₆ emerge as particularly promising candidates due to their photorepsonse at sub-2.4 eV illumination
Thomson and Compton scattering with an intense laser pulse
Our paper concerns the scattering of intense laser radiation on free
electrons and it is focused on the relation between nonlinear Compton and
nonlinear Thomson scattering. The analysis is performed for a laser field
modeled by an ideal pulse with a finite duration, a fixed direction of
propagation and indefinitely extended in the plane perpendicular to it. We
derive the classical limit of the quantum spectral and angular distribution of
the emitted radiation, for an arbitrary polarization of the laser pulse. We
also rederive our result directly, in the framework of classical
electrodynamics, obtaining, at the same time, the distribution for the emitted
radiation with a well defined polarization. The results reduce to those
established by Krafft et al. [Phys. Rev. E 72, 056502 (2005)] in the particular
case of linear polarization of the pulse, orthogonal to the initial electron
momentum. Conditions in which the differences between classical and quantum
results are visible are discussed and illustrated by graphs
The Fabrication of Nano-Particles in Aqueous Solution From Oxyfluoride Glass Ceramics by Thermal Induction and Corrosion Treatment
An innovative route is reported to fabricate nano-particles in aqueous solution from oxyfluoride glass by the thermal induction and corrosion treatment in this letter. The investigations of X-ray diffraction and transmission electron microscope based on nano-particles in glass ceramics (GCs) and aqueous solution indicate that the nano-particles formed in glass matrix during the thermal induction process are released to aqueous solution and their structure, shape and luminescent properties in glass host can be kept. Owing to the designable composition of the nano-particles during glass preparation process, the method is a novel way to obtain nano-particles in aqueous solution from GCs
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