Controlled Morphological Structure of Ceria Nanoparticles Prepared by Spray Pyrolysis

AbstractCeria based materials have been widely used as catalyst supporters and electrolytes. Different applications require different morphologies, and the microstructural control during the synthesis is crucial. In the study, ceria particles were prepared from various precursors using a spray pyrolysis (SP). Comparing to the hollow and porous particles, the formation mechanism with solid spherical structure is not clarified readily. The ceria particles were characterized by transmission electron microscopy, thermogravimetry analysis and X-ray photoelectron spectroscopy. This experimental result suggests that the morphology is controlled by the precursors and could be related to their decomposed behavior during the heating process in SP

Female media use behavior and agreement with publicly promoted agenda-specific health messages.

This study set out to explore the relationship between female media use behavior and agreement with agenda-specific publicly promoted health messages. A random digit dial telephone cross-sectional survey was conducted using a nationally representative sample of female residents aged 25 and over. Respondents' agreement with health messages was measured by a six-item Health Information Scale (HIS). Data were analyzed using chi-square tests and multiple logistic regression. This survey achieved a response rate of 86% (n = 1074). In this study the longest duration of daily television news watching (OR = 2.32), high self-efficacy (OR = 1.56), and greater attention to medical and health news (OR = 5.41) were all correlates of greater agreement with the selected health messages. Surprisingly, Internet use was not significant in the final model. Many women that public health interventions need to be targeting are not receptive to health information that can be accessed through Internet searches. However, they may be more readily targeted by television campaigns. Agenda-specific public health campaigns aiming to empower women to serve as nodes of information transmission and achieve efficient trickle down through the family unit might do better to invest more heavily in television promotion

KINEMATIC ANALYSIS OF THE SUPPORTING LEG BETWEEN DIFFERENT WEIGHT DIVISIONS IN THE ROUNDHOUSE KICK OF TAEKWONDO

The purpose of this study was to compare kinematic differences in the supporting leg between two weight divisions in the Taekwondo Roundhouse Kick. Collegiate Taekwondo athletes participated in the study and differences in maximum joint angles and ranges of motion on the supporting leg during executing the Roundhouse Kick were examined. The results showed significantly larger (

Preparation and Characterization of Carrot Nanocellulose and Ethylene/Vinyl Acetate Copolymer-Based Green Composites

This study aims to investigate the effect of nanocellulose on the properties and physical foaming of ethylene/vinyl acetate (EVA) copolymer. The nanocellulose is prepared from waste carrot residue using the 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) oxidation method (CT) and is further modified through suspension polymerization of methyl methacrylate (MMA) monomer (CM). The obtained nanocellulose samples (CT or CM) are added to EVA to create a series of nanocomposites. Moreover, the EVA and CM/EVA composite were further foamed using supercritical carbon dioxide physical foaming. TEM results show that the average diameters of CT and CM are 24.35 ± 3.15 nm and 30.45 ± 1.86 nm, respectively. The analysis of mechanical properties demonstrated that the tensile strength of pure EVA increased from 10.02 MPa to 13.01 MPa with the addition of only 0.2 wt% of CM. Furthermore, the addition of CM to EVA enhanced the melt strength of the polymer, leading to improvements in the physical foaming properties of the material. The results demonstrate that the pore size of the CM/EVA foam material is smaller than that of pure EVA foam. Additionally, the cell density of the CM/EVA foam material can reach 3.23 × 1011 cells/cm3

Interactions between Amyloid-β and Hemoglobin: Implications for Amyloid Plaque Formation in Alzheimer's Disease

Accumulation of amyloid-β (Aβ) peptides in the brain is one of the central pathogenic events in Alzheimer's disease (AD). However, why and how Aβ aggregates within the brain of AD patients remains elusive. Previously, we demonstrated hemoglobin (Hb) binds to Aβ and co-localizes with the plaque and vascular amyloid deposits in post-mortem AD brains. In this study, we further characterize the interactions between Hb and Aβ in vitro and in vivo and report the following observations: 1) the binding of Hb to Aβ required iron-containing heme; 2) other heme-containing proteins, such as myoglobin and cytochrome C, also bound to Aβ; 3) hemin-induced cytotoxicity was reduced in neuroblastoma cells by low levels of Aβ; 4) Hb was detected in neurons and glial cells of post-mortem AD brains and was up-regulated in aging and APP/PS1 transgenic mice; 5) microinjection of human Hb into the dorsal hippocampi of the APP/PS1 transgenic mice induced the formation of an envelope-like structure composed of Aβ surrounding the Hb droplets. Our results reveal an enhanced endogenous expression of Hb in aging brain cells, probably serving as a compensatory mechanism against hypoxia. In addition, Aβ binds to Hb and other hemoproteins via the iron-containing heme moiety, thereby reducing Hb/heme/iron-induced cytotoxicity. As some of the brain Hb could be derived from the peripheral circulation due to a compromised blood-brain barrier frequently observed in aged and AD brains, our work also suggests the genesis of some plaques may be a consequence of sustained amyloid accretion at sites of vascular injury

Synthesis of SnO 2

Zinc oxides deposited on Tin dioxide nanowires have been successfully synthesized by atomic layer deposition (ALD). The diameter of SnO2-ZnO core-shell nanowires is 100 nm by ALD 200 cycles. The result of electricity measurements shows that the resistance of SnO2-ZnO core-shell nanowires (ALD: 200 cycles) is 925 Ω, which is much lower than pure SnO2 nanowires (3.6 × 106 Ω). The result of UV light test shows that the recovery time of SnO2-ZnO core-shell nanowires (ALD: 200 cycles) is 328 seconds, which is lower than pure SnO2 nanowires (938 seconds). These results demonstrated that the SnO2-ZnO core-shell nanowires have potential application as UV photodetectors with high photon-sensing properties

The genome sequence of Salmonella enterica serovar Choleraesuis, a highly invasive and resistant zoonotic pathogen

Salmonella enterica serovar Choleraesuis (S.Choleraesuis), a highly invasive serovar among non-typhoidal Salmonella, usually causes sepsis or extra-intestinal focal infections in humans. S.Choleraesuis infections have now become particularly difficult to treat because of the emergence of resistance to multiple antimicrobial agents. The 4.7 Mb genome sequence of a multidrug-resistant S.Choleraesuis strain SC-B67 was determined. Genome wide comparison of three sequenced Salmonella genomes revealed that more deletion events occurred in S.Choleraesuis SC-B67 and S.Typhi CT18 relative to S.Typhimurium LT2. S.Choleraesuis has 151 pseudogenes, which, among the three Salmonella genomes, include the highest percentage of pseudogenes arising from the genes involved in bacterial chemotaxis signal-transduction pathways. Mutations in these genes may increase smooth swimming of the bacteria, potentially allowing more effective interactions with and invasion of host cells to occur. A key regulatory gene of TetR/AcrR family, acrR, was inactivated through the introduction of an internal stop codon resulting in overexpression of AcrAB that appears to be associated with ciprofloxacin resistance. While lateral gene transfer providing basic functions to allow niche expansion in the host and environment is maintained during the evolution of different serovars of Salmonella, genes providing little overall selective benefit may be lost rapidly. Our findings suggest that the formation of pseudogenes may provide a simple evolutionary pathway that complements gene acquisition to enhance virulence and antimicrobial resistance in S.Choleraesuis