Inventory management in railway sleepers: A simulation model for replacement strategies

This paper describes the development of a simulation model to assess the inventory requirements of alternative rail sleeper replacement strategies. The main aim of the model is to determine the optimal replacement strategy, given replacement costs and resultant train operating cost benefits. We consider the replacement problem under the following assumptions: The time to failure under constant stress follows a Weibull distribution and the scale parameter is a function of stress level and the three stress levels under normal (all adjacent units are good), medium-stress (one adjacent unit has failed) and high-stress conditions (two adjacent units are failed) are considered. The cumulative exposure model is used to model the failure distributions. The operational cost per unit time depends on the maximum number of consecutive failed units. The replacement cost consists of the fixed cost and variable cost proportional to the number of units replaced. A finite horizon is considered and total expected cost is a criterion for comparing the proposed policies. The model has been tested using rail system data and the results are presented in this paper

Scope and Mechanistic Study of the Ruthenium-Catalyzed \u3cem\u3eortho\u3c/em\u3e-C−H Bond Activation and Cyclization Reactions of Arylamines with Terminal Alkynes

The cationic ruthenium hydride complex [(PCy3)2(CO)(CH3CN)2RuH]+BF4- was found to be a highly effective catalyst for the C−H bond activation reaction of arylamines and terminal alkynes. The regioselective catalytic synthesis of substituted quinoline and quinoxaline derivatives was achieved from the ortho-C−H bond activation reaction of arylamines and terminal alkynes by using the catalyst Ru3(CO)12/HBF4·OEt2. The normal isotope effect (kCH/kCD = 2.5) was observed for the reaction of C6H5NH2 and C6D5NH2 with propyne. A highly negative Hammett value (ρ = −4.4) was obtained from the correlation of the relative rates from a series of meta-substituted anilines, m-XC6H4NH2, with σp in the presence of Ru3(CO)12/HBF4·OEt2 (3 mol % Ru, 1:3 molar ratio). The deuterium labeling studies from the reactions of both indoline and acyclic arylamines with DC⋮CPh showed that the alkyne C−H bond activation step is reversible. The crossover experiment from the reaction of 1-(2-amino-1-phenyl)pyrrole with DC⋮CPh and HC⋮CC6H4-p-OMe led to preferential deuterium incorporation to the phenyl-substituted quinoline product. A mechanism involving rate-determining ortho-C−H bond activation and intramolecular C−N bond formation steps via an unsaturated cationic ruthenium acetylide complex has been proposed

Stability issues of black hole in non-local gravity

We discuss stability issues of Schwarzschild black hole in non-local gravity. It is shown that the stability analysis of black hole for the unitary and renormalizable non-local gravity with $\gamma_2=-2\gamma_0$ cannot be performed in the Lichnerowicz operator approach. On the other hand, for the unitary and non-renormalizable case with $\gamma_2=0$, the black hole is stable against the metric perturbations. For non-unitary and renormalizable local gravity with $\gamma_2=-2\gamma_0={\rm const}$ (fourth-order gravity), the small black holes are unstable against the metric perturbations. This implies that what makes the problem difficult in stability analysis of black hole is the simultaneous requirement of unitarity and renormalizability around the Minkowski spacetime.Comment: 1+15 pages, one figure, version to appear in Physics Letters