25 research outputs found

    An investigation of annealing methods for benzodithiophene terthiophene rhodanine based all small molecule organic solar cells

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    Mainstream organic solar cells (OSCs) suffer a great variation of photovoltaic performance among different batches of polymers, which brings an opportunity for all-small-molecule OSCs to take leading position of industrialization. In recent years, benzodithiophene terthiophene rhodamine (BTR), as small molecule donor, has played an important role in this field. Here we investigated two typical BTR based all-small-molecule OSCs processed with different annealing methods, to explore the morphology optimization brought by them. As a result, BTR:PC71BM system was optimized by solvent vapor annealing (SVA) reaching an excellent fill factor (FF) of 79.1% via tuning molecular packing intensity, while BTR:Y6 with temperature annealing (TA) yielded a power conversion efficiency (PCE) of 12.125% whose molecular packing orientation had been changed. Additionally, by crossing using SVA and TA methods, we found that these two method can't be utilized together to further improve the PCE for either system. Therefore, our work offers better PCEs for these two reported combinations and further studies the compatibility between specific BTR based active layers and designated annealing methods, providing deeper understanding of device engineering on all-small-molecule OSCs.publishe

    Effect of acupuncture inclusion in the enhanced recovery after surgery protocol on tumor patient gastrointestinal function: a systematic review and meta-analysis of randomized controlled studies

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    IntroductionAcupuncture has been shown to be effective in restoring gastrointestinal function in tumor patients receiving the enhanced recovery after surgery (ERAS) protocol. The present systematic review and meta-analysis aimed to evaluate the rationality and efficacy of integrating acupuncture in the ERAS strategy to recuperate gastrointestinal function.MethodsWe searched eleven databases for relevant randomized clinical trials (RCTs) of acupuncture for the treatment of gastrointestinal dysfunction in tumor patients treated with the ERAS protocol. The quality of each article was assessed using the Cochrane Collaboration risk of bias criteria and the modified Jadad Scale. As individual symptoms, the primary outcomes were time to postoperative oral food intake, time to first flatus, time to first distension and peristaltic sound recovery time (PSRT). Pain control, adverse events, and acupoint names reported in the included studies were also investigated.ResultsOf the 211 reviewed abstracts, 9 studies (702 patients) met eligibility criteria and were included in the present systematic review and meta‑analysis. Compared to control groups, acupuncture groups showed a significant reduction in time to postoperative oral food intake [standardized mean difference (SMD) = -0.77, 95% confidence interval (CI) -1.18 to -0.35], time to first flatus (SMD=-0.81, 95% CI -1.13 to -0.48), time to first defecation (SMD=-0.91, 95% CI -1.41 to -0.41, PSRT (SMD=-0.92, 95% CI -1.93 to 0.08), and pain intensity (SMD=-0.60, 95% CI -0.83 to -0.37).The Zusanli (ST36) and Shangjuxu (ST37) acupoints were used in eight of the nine included studies. Adverse events related to acupuncture were observed in two studies, and only one case of bruising was reported. DiscussionThe present systematic review and meta‑analysis suggested that acupuncture significantly improves recovery of gastrointestinal function and pain control in tumor patients receiving the ERAS protocol compared to the control group. Moreover, ST36 and ST37 were the most frequently used acupoints. Although the safety of acupuncture was poorly described in the included studies, the available data suggested that acupuncture is a safe treatment with only mild side effects. These findings provide evidence-based recommendations for the inclusion of acupuncture in the ERAS protocol for tumor patients.Systematic review registrationhttps://www.crd.york.ac.uk/prospero/ PROSPERO, identifier CRD42023430211

    Evaluation of Serum Des-Gamma-Carboxy Prothrombin for the Diagnosis of Hepatitis B Virus-Related Hepatocellular Carcinoma: A Meta-Analysis

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    Aim. To explore the diagnostic efficacy of des-gamma-carboxy prothrombin (DCP) in hepatitis B virus- (HBV-) related hepatocellular carcinoma (HCC). Methods. A retrospective study of 459 cases from June 2016 to March 2018 was undertaken, and records of the DCP levels were extracted. The sensitivity, specificity, and cutoff points were calculated using SPSS 17.0 software. A systematic search in PubMed, Web of Science, and the Cochrane Central Register of Controlled Trials was performed for articles published in English from 1997 to 2017, focusing on serum DCP for HBV-related HCC. Data on sensitivity, specificity, the positive likelihood ratio (PLR), negative likelihood ratio (NLR), and diagnostic odds ratio (DOR) were extracted from five studies by systematic search and one study of our own. The summary receiver operating characteristic (sROC) curve was obtained, and the area under the receiver operating characteristic (AUROC) curve was calculated. Results. The pooled sensitivity, specificity, PLR, NLR, and DOR were 0.71 (95% CI: 0.59, 0.80), 0.93 (95% CI: 0.87, 0.96), 9.5 (95% CI: 5.2, 17.5), 0.32 (95% CI: 0.22, 0.46), and 30 (95% CI: 13, 72), respectively. The AUROC curve was 0.91 (95% CI: 0.88, 0.93). Conclusions. In the diagnosis of HBV-related hepatocellular carcinoma (HCC), DCP is an ideal marker that should be considered for surveillance purposes

    Analysis of cooperation equilibrium of participants in power battery recycling chains considering information barrier

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    In the era of large-scale retirement of power batteries, there are information barriers and high recovery costs in their recycling. In view of this, in this study we constructed a tripartite evolutionary game model of the cooperation between power battery production and recycling enterprises and government participation. We analyzed the strategic choice of the three parties in the process of power battery recycling and simulated the influence of participants' willingness and information barriers on the strategic choices of the parties. The results showed that power battery production and recycling enterprises, and the government are affected by each other's willingness to participate at different degrees. The willingness of power battery manufacturers and recycling enterprises to cooperate with each other decreased with increases in information barriers.By analyzing the impact of information barrier on power battery recycling, some suggestions are put forward to provide decision-making reference for promoting the sustainable development of power battery industry

    The Effect and Potential Mechanism of Fulvic Acid on Flavonoids in Lemon Leaves

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    Citrus limon (L.) Burm. f. is a horticultural crop known for its abundance of valuable secondary metabolites, including flavonoids, which are found in its fruits and leaves. Our previous research has shown that treating C. limon with fulvic acid (FA) can enhance the levels of vitamin C, total acid, total sugar, total flavonoids, and phenols in its fruits as well as the volatiles and total flavonoids in its leaves. In this current study, we established a method to analyze eight specific flavonoids in lemon leaves and evaluated the impact of irrigation with FA on the content of these flavonoids over a six-month period using HPLC-DAD/MS analysis. Moreover, we investigated the potential mechanisms of FA through ELISA and q-PCR methods. The results indicated that FA increased the contents of four flavonoids, namely, isoorientin, eriocitrin, vitexin, and rutin, and promoted the activity and gene expression of phenylalanineammonialyase (PAL), 4-coumaric acid coenzyme A ligase (4CL), chalcone synthase (CHS), flavonoid 3′-hydroxylase (F3′H), and flavonol synthase (FLS). Furthermore, the relationship between flavonoid content and the activities of biosynthetic enzymes was analyzed using orthogonal partial least squares discriminant analysis (OPLS-DA), which revealed a positive correlation between seven flavonoid levels and the activity of five biosynthetic enzymes under FA treatment

    Regenerative braking control strategy for pure electric vehicles based on fuzzy neural network

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    This study investigates the efficiency and safety of regenerative brake energy recuperation systems for electric vehicles. A three-input single-output fuzzy controller is developed to allocate hydraulic and electric braking forces, considering brake intensity, vehicle speed, and battery SOC's impact on regenerative braking performance. Fuzzy neural networks are utilized due to their effectiveness in solving complex, nonlinear, and fuzzy systems, along with their robustness to parameter changes and external disturbances. The fuzzy process of the controller is optimized using a self-tuning algorithm for designing membership function parameters, resulting in a fuzzy neural network controller. Moreover, electric and hydraulic braking forces are redistributed. Simulation using AVL Cruise software is conducted under NEDC and FTP-75 working conditions. The suggested brake energy recovery control approach using fuzzy neural networks successfully recovers braking energy, achieving energy recovery efficiencies of 14.52% and 39.61% under NEDC and FTP-75 conditions, respectively

    Two-Dimension Conjugated Acceptors Based on Benzodi(cyclopentadithiophene) Core with Thiophene-Fused Ending Group for Efficient Polymer Solar Cells

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    The previously reported nonfullerene small molecule ITIC-SF achieved via side chain tuning, promotes the power conversion efficiency of polymer solar cells (PSCs) with PBDB-T-SF as the donor from 10.1% and ITIC2 acceptors up to 12.2% for ITIC-SF acceptors. To further this research, benzene end groups of molecules are herein substituted with thiophene rings, obtaining two new molecules BDTCH-IC with alkylthio substituents, and BDTSF-IC with alkylthio and fluorine substituents on their thiophene-conjugated side chains. The absorption edges of BDTCH-IC and BDTSF-IC are red-shifted to 824 and 793 nm, respectively. Strengthened molecular crystallinity, promoted charge extraction, and upgraded morphology endorse the advancement of photovoltaic performance of the small molecular acceptors. Using donor PM6, the two small molecule acceptors show good photovoltaic performance, although the highest occupied molecular orbit energy offsets are small between donor and acceptor materials. As a combination of side-chain and end-group engineering, the photovoltaic performance of the PSCs is increased to 13.1%, together with the best short-circuit current (J(SC)) and fill factor reported thus far for this series of molecules. The results indicate that the modification of side chain and end groups is an effective way to improve the photovoltaic performance of small molecule acceptors
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