Field experience with various slicing methods

Wafer slicing using internal diameter (ID) saw, multiblade slurry (MBS) saw and multiwire slurry (MWS) saw techniques were evaluated. Wafer parameters such as bow, taper, and roughness which may not be important factors for solar cell fabrication, were considerably better for ID saw than those of the MBS and MWS saw. Analysis of add-on slicing cost indicated that machine productivity seems to be a major limiting factor for ID saw, while expendible material costs are a major factor for both MBS and MWS saw. Slicing experience indicated that the most important factors controling final wafer cost are: (1) silicon cost (wafer thickness + kerf loss); (2) add-on slicing cost, and (3) mechanical yield. There is a very strong interaction between these parameters, suggesting a necessity of optimization of these parameters

Silicon solar cell process development, fabrication, and analysis

Two large cast ingots were evaluated. Solar cell performance versus substrate position within the ingots was obtained and the results are presented. Dendritic web samples were analyzed in terms of structural defects, and efforts were made to correlate the data with the performance of solar cells made from the webs

Assessment of Present State-of-the-art Sawing Technology of Large Diameter Ingots for Solar Sheet Material

Work is reported on: (1) slicing of the ingots with the multiblade slurry saw, the multiwire slurry saw and the I.D. saw, (2) characterization of the sliced wafers, and (3) analysis of add-on slicing cost based on Solar Array Manufacturing Industry Costing Standard

Silicon solar cell process development, fabrication and analysis

Solar cells were fabricated from EFG ribbons dendritic webs, cast ingots by heat exchanger method, and cast ingots by ubiquitous crystallization process. Baseline and other process variations were applied to fabricate solar cells. EFG ribbons grown in a carbon-containing gas atmosphere showed significant improvement in silicon quality. Baseline solar cells from dendritic webs of various runs indicated that the quality of the webs under investigation was not as good as the conventional CZ silicon, showing an average minority carrier diffusion length of about 60 um versus 120 um of CZ wafers. Detail evaluation of large cast ingots by HEM showed ingot reproducibility problems from run to run and uniformity problems of sheet quality within an ingot. Initial evaluation of the wafers prepared from the cast polycrystalline ingots by UCP suggested that the quality of the wafers from this process is considerably lower than the conventional CZ wafers. Overall performance was relatively uniform, except for a few cells which showed shunting problems caused by inclusions

Silicon Solar Cell Process Development, Fabrication and Analysis, Phase 1

Solar cells from RTR ribbons, EFG (RF and RH) ribbons, dendritic webs, Silso wafers, cast silicon by HEM, silicon on ceramic, and continuous Czochralski ingots were fabricated using a standard process typical of those used currently in the silicon solar cell industry. Back surface field (BSF) processing and other process modifications were included to give preliminary indications of possible improved performance. The parameters measured included open circuit voltage, short circuit current, curve fill factor, and conversion efficiency (all taken under AM0 illumination). Also measured for typical cells were spectral response, dark I-V characteristics, minority carrier diffusion length, and photoresponse by fine light spot scanning. the results were compared to the properties of cells made from conventional single crystalline Czochralski silicon with an emphasis on statistical evaluation. Limited efforts were made to identify growth defects which will influence solar cell performance

Demystification of Mizusaki’s α-factor for the positively-deviated defect behavior of hyperstoichiometric oxides

Many hyperstoichiometric (p-type) ternary or higher oxides of present technological interests, e.g., La1-xSrxCrO3-δ exhibit a positive deviation from the ideal defect structure. Mizusaki et al. [1] could beautifully explain the positively-deviated defect structure by introducing an empirical factor α such as ΔHxs=αδ. Here, ΔHxs stands for the excess enthalpy of oxidation reaction involving oxygen vacancies and holes or 1/2 O2+VO••=OOx+2h• . The authors[1] interpreted this α-factor as representing the interactions among lattice ions and defects, but its true physico-chemical face has since remained a mystery notwithstanding so frequent invoking to the defect chemistry stage. It has recently turned out that this factor corresponds to the first order approximation of the hole-degeneracy effect. We will demystify this α-factor in this line. [1] J. Mizusaki, S, Yamauchi, K. Fueki, and A. Ishikawa, “Nonstoichiometry of the perovskite-type oxide La1-xSrxCrO3-δ,” Solid State Ionics 12 (1984) 119

Monolithic arrays of surface emitting laser NOR logic devices

Monolithic, cascadable, laser-logic-device arrays have been realized and characterized. The monolithic surface-emitting laser logic (SELL) device consists of an AlGaAs superlattice lasing around 780 nm connected to a heterojunction phototransistor (HPT) in parallel and a resistor in series. Arrays up to 8×8 have been fabricated, and 2×2 arrays show uniform characteristics. The optical logic output is switched off with 40 μW incident optical input

Monolithic arrays of surface emitting laser NOR logic devices

Monolithic, cascadable, laser-logic-device arrays have been realized and characterized. The monolithic surface-emitting laser logic (SELL) device consists of an AlGaAs superlattice lasing around 780 nm connected to a heterojunction phototransistor (HPT) in parallel and a resistor in series. Arrays up to 8×8 have been fabricated, and 2×2 arrays show uniform characteristics. The optical logic output is switched off with 40 μW incident optical input

Studying Diquark Structure of Heavy Baryons in Relativistic Heavy Ion Collisions

We propose the enhancement of $\Lambda_c$ yield in heavy ion collisions at RHIC and LHC as a novel signal for the existence of diquarks in the strongly coupled quark-gluon plasma produced in these collisions as well as in the $\Lambda_c$. Assuming that stable bound diquarks can exist in the quark-gluon plasma, we argue that the yield of $\Lambda_c$ would be increased by two-body collisions between $ud$ diquarks and $c$ quarks, in addition to normal three-body collisions among $u$, $d$ and $c$ quarks. A quantitative study of this effect based on the coalescence model shows that including the contribution of diquarks to $\Lambda_c$ production indeed leads to a substantial enhancement of the $\Lambda_c/D$ ratio in heavy ion collisions.Comment: Prepared for Chiral Symmetry in Hadron and Nuclear Physics (Chiral07), Nov. 13-16, 2007, Osaka, Japa