Characterization, dissolution and solubility of the hydroxypyromorphite–hydroxyapatite solid solution [(PbxCa1−x)5(PO4)3OH] at 25 °C and pH 2–9

Additional file 1: Appendix A. Supplementary data—X-ray diffractograms (XRD) of the hydroxypyromorphite–hydroxyapatite solid solution [(PbxCa1−x)5(PO4)3(OH)] after dissolution at 25 ˚C and an initial pH of 5.60 and 9.00 for 300d

Fixed-bed column adsorption of arsenic(V) by porous composite of magnetite/hematite/carbon with eucalyptus wood microstructure

The fixed-bed column adsorption-desorption of As(V) by the porous composite of iron oxides and carbon with eucalyptus wood hierarchical microstructure (PC-Fe/C) was experimentally studied. The increase in the influent As(V) concentration and the inflow rate resulted in an earlier exhaustion of the column. The breakthrough curves indicated that a larger adsorbent mass, a smaller adsorbent grain size and a lower influent pH prolonged the column life span. The operating temperature had negligible effect. All breakthrough curves could be well fitted with the Thomas and Yoon–Nelson models. Under the condition of the influent flow rate of 5.136 mL/min, the influent As(V) concentration of 20 mg/L, the influent pH of 3, the adsorbent mass of 2 g, the adsorbent grain size of <100 mesh, and the operating temperature of 35 °C, the equilibrium adsorption capacity reached 10.49 mg/g, which was greater than those of natural/synthetic iron oxides adsorbents and iron-oxide-coated adsorbents

Realization of chirped fibre Bragg gratings by strain gradients and their applications for fibre dispersing compensation

M.Phil.Linearly chirped fibre Bragg gratings can be used to compensate dispersions in a fibre transmission system. Various methods have been developed to chirp fibre gratings. It is proposed that a uniform period grating can be chirped by applying an axially linear strain gradient. In this project, we shall demonstate a novel method for making chirped fibre Bragg gratings, which involves bonding an unchirped fibre Bragg grating of 5cm length to the surface of a tapered stainless steel plate which is strained by bending or dilating. This allows a strain gradient to be formed along the grating length through the transferring of strains from the plate to the fibre. The profiles of tapered stainless steel plates have been determined by means of the finite element method and computer simulations to establish the strain gradient during loading. Ten conventional resistive strain gauges are also bonded on the other surface for strain measurements. Because of the strain gradient, the local Bragg wavelength is a function of the position along the length of the fibre grating so that the grating chirp is an automatic consequence of the strain gradient. This method provides the dynamic control of Bragg wavelength shift, peak reflectivity and spectral bandwidth, and its tunability is also suitable for optimising pulse compression and optical fibre dispersion compensation. Using couple-mode equations, we have also calculated the reflection response of a chirped fibre grating. It is shown that the close agreement between the theoretical and the experimental results suggests that the strain gradient technique provides good control of the Bragg grating chirp and the center wavelength of a chirped fibre Bragg grating

Fabrication of long-period gratings and their applications in optical fibre communications and sensing systems

D.Phil.This dissertation deals with the fabrication, characterisation, and applications of long-period gratings in optical fibre communications and sensing systems. The aim of this project is to assess long-period gratings as media for active or passive fibre devices, particularly as components for the telecommunications industry. A review of the properties and characteristics of fibre gratings associated with the photosensitivity of germanosilicate fibres is provided, which includes a theoretical analysis of the principles of operation for short-period gratings (fibre Bragg gratings) and long-period gratings. The simulations of the spectral response from these two types of gratings are also presented. A number of long-period grating fabrication methods and techniques, which were reported by some researchers, are reviewed. In this project, the normal long-period gratings and phase-shifted long-period gratings are fabricated by using a line-narrowed KrF excimer laser combined with the metal amplitude mask technique. The metal mask is made of a stainless steel sheet, and the slot width (periodicity) is processed by using high quality photographic tooling. Three normal long-period gratings with different periodicities and one phase-shifted long-period grating can be manufactured simultaneously because there are four metal masks imprinted in one inexpensive stainless steel sheet. The mass-production of long-period gratings becomes possible, and the number of gratings that can be written is limited only by the excimer laser beam or metal mask dimension orthogonal to the fibre axis. The fibres that are used in our experiments are photosensitive optical fibres (PS1500). Long-period gratings can be written directly into these fibres without hydrogenation. Two types of long-period grating devices are investigated and developed for applications in dense wavelength division multiplexing (DWDM)networks: erbium-doped fibre amplifier (EDFA) gain-flattening filters and wavelength-tuneable add/drop multiplexers. Firstly, the transmission characteristics of phase-shifted long-period gratings are simulated theoretically by a combination of the coupled-mode theory and the fundamental-matrix method. It is suggested that a phase-shifted long-period grating device cascaded with another normal long-period grating can be used to flatten the gain spectrum of an EDFA containing three gain peaks. The experimental results show that a broad amplifier with peak-to-peak variations of less than 0.7 dB over 36 nm from 1526 to 1562 nm, which covers the entire C-band of the EDFA, can be realized practically. Next, a wavelength-tuneable add/drop multiplexer is designed and configured. In this device, four identical long-period gratings are assembled on piezoelectric ceramic fibre stretchers. The modelling of the device predicts that 50 ITU DWDM-channel signals could be selected in the wavelength range from 1526.25 to 1563.75 nm with 0.75 nm channel spacing and the cross-talk is less than –39 dB while the total insertion loss is about 0.24 dB. There are some significant advantages of wavelength-tuneable add/drop multiplexing devices over conventional fibre Bragg grating-based devices. (1) There is back reflected light and almost no cross-talk power penalty because the long-period grating couples light into forward-propagating modes. (2) Signal channel isolation is very high due to three stages of coupling mechanisms used in this device, which includes core-cladding, cladding-cladding and cladding-core, efficiently filtering out non-resonant light. (3) The insertion loss of the device is limited only by the separation of two long-period gratings, because there are no losses on non-resonant wavelengths of long-period gratings. Several other applications of long-period gratings in optical sensing systems are also described, and some are experimented on including axial strain sensors, structural bend sensors, temperature sensors, refractive index sensors and chemical concentration sensors

Characterization, Dissolution, and Solubility of Lead Hydroxypyromorphite [Pb5(PO4)3OH] at 25–45°C

Dissolution of the hydroxypyromorphite [lead hydroxyapatite, Pb5(PO4)3OH] in HNO3 solution (pH = 2.00), ultrapure water (pH = 5.60), and NaOH solution (pH = 9.00) was experimentally studied at 25°C, 35°C, and 45°C. The XRD, FT-IR, and FE-SEM analyses indicated that the hydroxypyromorphite solids were observed to have indistinguishable change during dissolution. For the hydroxypyromorphite dissolution in aqueous acidic media at initial pH 2.00 and 25°C, the aqueous phosphate concentrations rose quickly and reached the peak values after 1 h dissolution, while the aqueous lead concentrations rose slowly and reached the peak values after 1440 h. The solution Pb/P molar ratio increased constantly from 1.10 to 1.65 near the stoichiometric ratio of 1.67 to 209.85~597.72 and then decreased to 74.76~237.26 for the dissolution at initial pH 2.00 and 25°C~45°C. The average Ksp values for Pb5(PO4)3OH were determined to be 10−80.77 (10−80.57−10−80.96) at 25°C, 10−80.65 (10−80.38−10−80.99) at 35°C, and 10−79.96 (10−79.38−10−80.71) at 45°C. From the obtained solubility data for the dissolution at initial pH 2.00 and 25°C, the Gibbs free energy of formation [ΔGfo] for Pb5(PO4)3OH was calculated to be −3796.71 kJ/mol (−3795.55~−3797.78 kJ/mol)

Prediction and Evaluation of the Mixture Toxicity of Twelve Phenols and Ten Anilines to the Freshwater Photobacterium Vibrio qinghaiensis sp.-Q67

Twelve substituted phenols and ten substituted anilines were chosen to investigate if the dose addition and independent action models can be used to evaluate the mixture toxicity of phenolic and aniline derivatives (PADs). Their photobacterium toxicity to the freshwater luminescent bacterium Vibrio qinghaiensis sp.-Q67 showed that the two-parameter Weibull or Logit function could be effectively applied to describe the dose-response relationships. The joint toxicity of three equivalent-effect concentration ratio (EECR) mixtures and twelve uniform design concentration ratio (UDCR) mixtures could be well evaluated using the dose addition (DA) or the independent action (IA) model within 95% confidence intervals

Dissolution and Solubility Product of Cd-Fluorapatite [Cd5(PO4)3F] at pH of 2–9 and 25–45°C

Dissolution of the synthetic cadmium fluorapatite [Cd5(PO4)3F] at 25°C, 35°C, and 45°C was experimentally examined in HNO3 solution, pure water, and NaOH solution. The characterization results confirmed that the cadmium fluorapatite nanorods used in the experiments showed no obvious variation after dissolution. During the dissolution of Cd5(PO4)3F in HNO3 solution (pH = 2) at 25°C, the fluoride, phosphate, and cadmium ions were rapidly released from solid to solution, and their aqueous concentrations had reached the highest values after dissolution for <1 h, 1440 h, and 2880 h, respectively. After that, the total dissolution rates declined slowly though the solution Cd/P molar ratios increased incessantly from 1.55∼1.67 to 3.18∼3.22. The solubility product for Cd5(PO4)3F (Ksp) was determined to be 10−60.03 (10−59.74∼10−60.46) at 25°C, 10−60.38 (10−60.32∼10−60.48) at 35°C, and 10−60.45 (10−60.33∼10−60.63) at 45°C. Based on the log Ksp values obtained at an initial pH of 2 and 25°C, the Gibbs free energy of formation for Cd5(PO4)3F (ΔGf0) was calculated to be −4065.76 kJ/mol (−4064.11∼−4068.23 kJ/mol). The thermodynamic parameters for the dissolution process were computed to be 342515.78 J/K·mol, −85088.80 J/mol, −1434.91 J/K·mol, and 2339.50 J/K·mol for ΔG0, ΔH0, ΔS0, and ΔCp0, correspondingly

Characterization, Dissolution, and Solubility of Zn-Substituted Hydroxylapatites [(ZnxCa1−x)5(PO4)3OH] at 25°C

A series of Zn-substituted hydroxylapatites [(ZnxCa1−x)5(PO4)3OH, Zn-Ca-HA] with the Zn/(Zn + Ca) molar ratio (XZn) of 0~0.16 was prepared and characterized, and then the dissolution of the synthesized solids in aqueous solution was investigated by batch experiment. The results indicated that the aqueous zinc, calcium, and phosphate concentrations greatly depended on the Zn/(Zn + Ca) molar ratio of the Zn-Ca-HA solids (XZn). For the Zn-Ca-HA dissolution at 25°C with an initial pH of 2.00, the final solution pH increased, while the final solution calcium and phosphate concentrations decreased with the increasing XZn. The final solution zinc concentrations increased with the increasing XZn when XZn≤0.08 and decreased with the increasing XZn when XZn = 0.08~0.16. The mean Ksp values for (ZnxCa1−x)5(PO4)3OH at 25°C decreased from 10−57.75 to 10−58.59 with the increasing XZn from 0.00 to 0.08 and then increased from 10–58.59 to 10–56.63 with the increasing XZn from 0.08 to 0.16. This tendency was consistent with the dependency of the lattice parameter a on XZn. The corresponding free energies of formation (ΔGfo) increased lineally from −6310.45 kJ/mol to −5979.39 kJ/mol with the increasing XZn from 0.00 to 0.16