Inflating hollow nanocrystals through a repeated Kirkendall cavitation process.

The Kirkendall effect has been recently used to produce hollow nanostructures by taking advantage of the different diffusion rates of species involved in the chemical transformations of nanoscale objects. Here we demonstrate a nanoscale Kirkendall cavitation process that can transform solid palladium nanocrystals into hollow palladium nanocrystals through insertion and extraction of phosphorus. The key to success in producing monometallic hollow nanocrystals is the effective extraction of phosphorus through an oxidation reaction, which promotes the outward diffusion of phosphorus from the compound nanocrystals of palladium phosphide and consequently the inward diffusion of vacancies and their coalescence into larger voids. We further demonstrate that this Kirkendall cavitation process can be repeated a number of times to gradually inflate the hollow metal nanocrystals, producing nanoshells of increased diameters and decreased thicknesses. The resulting thin palladium nanoshells exhibit enhanced catalytic activity and high durability toward formic acid oxidation

Clustering Instabilities in Gas-Solid Systems: Role of Dissipative Collisions vs. Viscous Losses

https://digitalrepository.unm.edu/abq_mj_news/4755/thumbnail.jp

Robust image steganography against lossy JPEG compression based on embedding domain selection and adaptive error correction

Transmitting images for communication on social networks has become routine, which is helpful for covert communication. The traditional steganography algorithm is unable to successfully convey secret information since the social network channel will perform lossy operations on images, such as JPEG compression. Previous studies tried to solve this problem by enhancing the robustness or making the cover adapt to the channel processing. In this study, we proposed a robust image steganography method against lossy JPEG compression based on embedding domain selection and adaptive error correction. To improve anti-steganalysis performance, the embedding domain is selected adaptively. To increase robustness and lessen the impact on anti-steganalysis performance, the error correction capacity of the error correction code is adaptively adjusted to eliminate redundancy. The experimental results show that the proposed method achieves better anti-steganalysis and robustness