12,330 research outputs found

    Nonequilibrium transport through a quantum dot weakly coupled to Luttinger liquids

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    We study the nonequlibrium transport through a quantum dot weakly coupled to Luttinger liquids (LL). A general current expression is derived by using nonequilibrium Green function method. Then a special case of the dot with only a single energy level is discussed. As a function of the dot's energy level, we find that the current as well as differential conductance is strongly renormalized by the interaction in the LL leads. In comparison with the system with Fermi liquid (FL) leads, the current is suppressed, consistent with the suppression of the electron tunneling density of states of the LL; and the outset of the resonant tunneling is shifted to higher bias voltages. Besides, the linear conductance obtained by Furusaki using master equation can be reproduced from our result.Comment: 8 pages, 3 figures, Late

    Enzymatic Cross-Linking of Dynamic Thiol-Norbornene Click Hydrogels

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    Enzyme-mediated in situ forming hydrogels are attractive for many biomedical applications because gelation afforded by enzymatic reactions can be readily controlled not only by tuning macromer compositions, but also by adjusting enzyme kinetics. For example, horseradish peroxidase (HRP) has been used extensively for in situ cross-linking of macromers containing hydroxyl-phenol groups. The use of HRP to initiate thiol-allylether polymerization has also been reported, yet no prior study has demonstrated enzymatic initiation of thiol-norbornene gelation. In this study, we discovered that HRP can generate the thiyl radicals needed for initiating thiol-norbornene hydrogelation, which has only been demonstrated previously using photopolymerization. Enzymatic thiol-norbornene gelation not only overcomes light attenuation issue commonly observed in photopolymerized hydrogels, but also preserves modularity of the cross-linking. In particular, we prepared modular hydrogels from two sets of norbornene-modified macromers, 8-arm poly(ethylene glycol)-norbornene (PEG8NB) and gelatin-norbornene (GelNB). Bis-cysteine-containing peptides or PEG-tetra-thiol (PEG4SH) was used as a cross-linker for forming enzymatically and orthogonally polymerized hydrogel. For HRP-initiated PEG-peptide hydrogel cross-linking, gelation efficiency was significantly improved via adding tyrosine residues on the peptide cross-linkers. Interestingly, these additional tyrosine residues did not form permanent dityrosine cross-links following HRP-induced gelation. As a result, they remained available for tyrosinase-mediated secondary cross-linking, which dynamically increased hydrogel stiffness. In addition to material characterizations, we also found that both PEG- and gelatin-based hydrogels exhibited excellent cytocompatibility for dynamic 3D cell culture. The enzymatic thiol-norbornene gelation scheme presented here offers a new cross-linking mechanism for preparing modularly and dynamically cross-linked hydrogels

    The Effects of Language Difference on Operational Performance and Satisfaction with B2B E-Marketplace Interface

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    This study integrated the user interface and information content of the business-to-business (B2B) electronic marketplace (e-marketplace) with language to analyze whether language differences affect the definition of good interface design and the information content that should be provided via an e-marketplace. An experimental design was adopted for collecting data from tasks, and then the Questionnaire for User Interface Satisfaction (QUIS) was used to ascertain how satisfied subjects were with regard to using the B2B e-marketplace interfaces. Study results showed that the language, the e-marketplace interface the subject used, and a combination of the two predict a person’s operational performance and satisfaction with a B2B e-marketplace. This study’s results provide a better understanding of whether B2B e-marketplace service providers should develop interfaces based on specific languages

    Probing Transverse Momentum Broadening via Dihadron and Hadron-jet Angular Correlations in Relativistic Heavy-ion Collisions

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    Dijet, dihadron, hadron-jet angular correlations have been reckoned as important probes of the transverse momentum broadening effects in relativistic nuclear collisions. When a pair of high-energy jets created in hard collisions traverse the quark-gluon plasma produced in heavy-ion collisions, they become de-correlated due to the vacuum soft gluon radiation associated with the Sudakov logarithms and the medium-induced transverse momentum broadening. For the first time, we employ the systematical resummation formalism and establish a baseline calculation to describe the dihadron and hadron-jet angular correlation data in pppp and peripheral AAAA collisions where the medium effect is negligible. We demonstrate that the medium-induced broadening ⟨p⊥2⟩\langle p_\perp^2\rangle and the so-called jet quenching parameter q^\hat q can be extracted from the angular de-correlations observed in AAAA collisions. A global χ2\chi^2 analysis of dihadron and hadron-jet angular correlation data renders the best fit ⟨p⊥2⟩∼13 GeV2\langle p_\perp^2 \rangle \sim 13~\textrm{GeV}^2 for a quark jet at RHIC top energy. Further experimental and theoretical efforts along the direction of this work shall significantly advance the quantitative understanding of transverse momentum broadening and help us acquire unprecedented knowledge of jet quenching parameter in relativistic heavy-ion collisions.Comment: 6 pages, 3 figure

    Improving gelation efficiency and cytocompatibility of visible light polymerized thiol-norbornene hydrogels via addition of soluble tyrosine

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    Hydrogels immobilized with biomimetic peptides have been used widely for tissue engineering and drug delivery applications. Photopolymerization has been among the most commonly used techniques to fabricate peptide-immobilized hydrogels as it offers rapid and robust peptide immobilization within a crosslinked hydrogel network. Both chain-growth and step-growth photopolymerizations can be used to immobilize peptides within covalently crosslinked hydrogels. A previously developed visible light mediated step-growth thiol-norbornene gelation scheme has demonstrated efficient crosslinking of hydrogels composed of an inert poly(ethylene glycol)-norbornene (PEGNB) macromer and a small molecular weight bis-thiol linker, such as dithiothreitol (DTT). Compared with conventional visible light mediated chain-polymerizations where multiple initiator components are required, step-growth photopolymerized thiol-norbornene hydrogels are more cytocompatible for the in situ encapsulation of radical sensitive cells (e.g., pancreatic β-cells). This contribution explored visible light based crosslinking of various bis-cysteine containing peptides with macromer 8-arm PEGNB to form biomimetic hydrogels suitable for in situ cell encapsulation. It was found that the addition of soluble tyrosine during polymerization not only significantly accelerated gelation, but also improved the crosslinking efficiency of PEG-peptide hydrogels as evidenced by a decreased gel point and enhanced gel modulus. In addition, soluble tyrosine drastically enhanced the cytocompatibility of the resulting PEG-peptide hydrogels, as demonstrated by in situ encapsulation and culture of pancreatic MIN6 β-cells. This visible light based thiol-norbornene crosslinking mechanism provides an attractive gelation method for preparing cytocompatible PEG-peptide hydrogels for tissue engineering applications

    The cultural politics of English as a global language in Taiwan.

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    This thesis explores how English is perceived in Taiwan and what impact it has on society and culture by drawing on three kinds of data: (i) analysis of policy and documents, (ii) critical discourse analysis of textual data, and (iii) interviews with respondents from different levels of the education system. It aims to provide an indepth study of the role and cultural politics of English in Taiwan. Rather than offering a general and quantitative picture of global English, this research concentrates on qualitative and contextual data. It focuses on issues which arise when English is given an important role in national policy and when English instruction is introduced into Taiwan's elementary education system. By analysing governmental documents, educational publications and media texts, this research identifies a number of ideological assumptions about English in Taiwan and argues that the ideology of English in Taiwan is based on a strong association between English, globalization and economic competitiveness. It also reflects, to an extent, the underlying uncertainty and anxiety regarding Taiwanese's politico-economic future. Furthermore, in the investigation of perceptions of English in Taiwan, informants' responses corresponded somewhat with ideological assumptions embedded in discourses on English. English is highly approved of in areas related to national and personal economic well-being, while the prevalence of English also leads to concern about local languages and cultures. This research suggests that the overall impact of English is considered more positive than negative. Moreover, since the necessity of English is assumed by Taiwanese society, the main concern is thus how to adapt global English effectively without undermining local languages and cultures. Taiwan can be regarded as a typical case among East Asian countries in terms of the socio-economic and educational impact ofEnglish, while the ideological assumptions and perceptions of global English reflect Taiwan's unique cultural, economic and political status in the world
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