12 research outputs found

    Wafer-Level Artificial Photosynthesis for CO<sub>2</sub> Reduction into CH<sub>4</sub> and CO Using GaN Nanowires

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    We report on the first demonstration of high-conversion-rate photochemical reduction of carbon dioxide (CO<sub>2</sub>) on gallium nitride (GaN) nanowire arrays into methane (CH<sub>4</sub>) and carbon monoxide (CO). It was observed that the reduction of CO<sub>2</sub> to CO dominates on as-grown GaN nanowires under ultraviolet light irradiation. However, the production of CH<sub>4</sub> is significantly increased by using the Rh/Cr<sub>2</sub>O<sub>3</sub> core/shell cocatalyst, with an average rate of ∼3.5 μmol g<sub>cat</sub><sup>–1</sup> h<sup>–1</sup> in 24 h. In this process, the rate of CO<sub>2</sub> to CO conversion is suppressed by nearly an order of magnitude. The rate of photoreduction of CO<sub>2</sub> to CH<sub>4</sub> can be further enhanced and can reach ∼14.8 μmol g<sub>cat</sub><sup>–1</sup> h<sup>–1</sup> by promoting Pt nanoparticles on the lateral <i>m</i>-plane surfaces of GaN nanowires, which is nearly an order of magnitude higher than that measured on as-grown GaN nanowire arrays. This work establishes the potential use of metal-nitride nanowire arrays as a highly efficient photocatalyst for the direct photoreduction of CO<sub>2</sub> into chemical fuels. It also reveals the potential of engineered core/shell cocatalysts in improving the selectivity toward more valuable fuels

    Pt nanoclusters on GaN nanowires for solar-asssisted seawater hydrogen evolution

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    Seawater is the most abundant water source for hydrogen fuel production. Here the authors report a binary photoelectrode of Pt catalyst-GaN semiconductor with promising efficiency, productivity, and stability for seawater hydrogen evolution

    Development and evaluation of an efficient and real-time monitoring system for the vector mosquitoes, Aedes albopictus and Culex quinquefasciatus

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    BackgroundThe surveillance of vector mosquitoes is essential for prevention and control of mosquito-borne diseases. In this study, we developed an internet-based vector mosquito monitor, MS-300, and evaluated its efficiency for the capture of the important vector mosquitoes, Aedes albopictus and Culex quinquefasciatus, in laboratory and field trials.Methodology/principal findingsThe linear sizes of adult Ae. albopictus and Cx. quinquefasciatus were measured and an infrared window was designed based on these data. A device to specifically attract these two species and automatically transmit the number of captured mosquitoes to the internet was developed. The efficiency of the device in capturing the two species was tested in laboratory, semi-field and open field trials. The efficiency results for MS-300 for catching and identifying Ae. albopictus in laboratory mosquito-net cages were 98.5% and 99.3%, and 95.8% and 98.6%, respectively, for Cx. quinquefasciatus. In a wire-gauze screened house in semi-field trials, the efficiencies of MS-300 baited with a lure in catching Ae. albopictus and Cx. quinquefasciatus were 54.2% and 51.3%, respectively, which were significantly higher than 4% and 4.2% without the lure. The real-time monitoring data revealed two daily activity peaks for Ae. albopictus (8:00-10:00 and 17:00-19:00), and one peak for Cx. quinquefasciatus (20:00-24:00). During a 98-day surveillance trial in the field, totals of 1,118 Ae. albopictus and 2,302 Cx. quinquefasciatus were captured by MS-300. There is a close correlation between the number of captured mosquitoes and the temperature in the field, and a positive correlation in the species composition of the captured samples among the mosquitoes using MS-300, BioGents Sentinel traps and human landing catches.Conclusions/significanceThe data support the conclusion that MS-300 can specifically and efficiently capture Ae. albopictus and Cx. quinquefasciatus, and monitor their density automatically in real-time. Therefore, MS-300 has potential for use as a surveillance tool for prevention and control of vector mosquitoes

    Photoelectrochemical Urea Synthesis from Nitrate and Carbon Dioxide on GaN Nanowires

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    Semiconductor photoelectrodes can be used to synthesize urea from carbon dioxide and nitrate under solar light. We find that GaN nanowires (NWs) have inherent catalytic activity for nitrate conversion to nitrite, while Ag cocatalysts loaded onto GaN NWs further promote the performance of photoelectrochemical urea synthesis. Under optimized conditions, a high faradaic efficiency of 75.6 ± 2.6% was achieved at a potential of −0.3 vs reversible hydrogen electrode. Control experiments and theoretical calculations suggest that the high selectivity of urea originates from the facilitated C–N coupling between key intermediates of NO2 and COO– at an early stage of the reduction reaction. This work demonstrates the potential of GaN NWs with loaded Ag cocatalysts to achieve solar-powered urea synthesis with an efficiency higher than that of previously reported methods
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