Phosphate Rocks: A Review of Sedimentary and Igneous Occurrences in Morocco

International audiencePhosphate rocks are a vital resource for world food supply and security. They are the primary raw material for phosphoric acid and fertilizers used in agriculture, and are increasingly considered to be a potential source of rare earth elements. Phosphate rocks occur either as sedimentary deposits or igneous ores associated with alkaline rocks. In both cases, the genesis of high-grade phosphate rocks results from complex concentration mechanisms involving several (bio)geochemical processes. Some of these ore-forming processes remain poorly understood and subject to scientific debate. Morocco holds the world’s largest deposits of sedimentary phosphate rocks, and also possesses several alkaline complexes with the potential to bear igneous phosphate ores that are still largely underexplored. This paper summarizes the main geological features and driving processes of sedimentary and igneous phosphates, and discusses their global reserve/resource situation. It also provides a comprehensive review of the published data and information on Moroccan sedimentary and igneous phosphates. It reveals significant knowledge gaps and a lack of data, inter alia, regarding the geochemistry of phosphates and basin-scale correlations. Owing to the unique situation of Moroccan phosphates on the global market, they clearly deserve more thorough studies that may, in turn, help to constrain future resources and/or reserves, and answer outstanding questions on the genesis of phosphates

Gravity study of the Western Bahira Basin and the Gantour Phosphatic Plateau, Central Morocco: interpretation and hydrogeological implications

International audienceThe Western Bahira Basin (WBB), located in Central Morocco, is known for its large reserves of phosphate, which are currently being extracted through open pit mines within the Gantour Phosphatic Plateau (GPP). This mining activity, as well as the increasing agricultural development that this region has been experiencing during the last few decades, has subjected the groundwater in this semi-arid region to intense exploitation through pumping. Consequently, thorough knowledge of the underground water resources is essential for sustained activity. This study uses gravity data to investigate the deep geologic structure of the western Bahira and Gantour plateau area. Its main purpose is to improve the knowledge of this structure that influences the groundwater dynamics. The methodology involves, in addition to the qualitative and quantitative interpretation of the gravity data, the use of various filtering and analysis techniques to highlight the major geological structures. In fact, a qualitative analysis of the residual gravity map shows that the observed anomalies can be explained in terms of the bedrock topography of the study area. Positive anomalies spatially correlate with the outcrops of this bedrock in the Hercynian massifs of Jebilet and Rehamna, as well as with the Douar Rhirat structural high. The negative anomalies, on the other hand, tend to reflect increased thicknesses of sedimentary sequences, such as in the southern part of the WBB. Moreover, the Brikyine granite in the north of the study area is noticeably associated with the highest amplitude negative anomaly. Analysis of the residual gravity data using the total horizontal gradient, upward continuation, and Euler deconvolution techniques provides a quantitative assessment of the geologic structure. These methods help delineate various structures oriented in two main directions: N45E and N105E. Among these structures, several major faults have been identified. They are rooted at a maximum depth in excess of 2800 m. These faults are responsible for the general structure of the study area and the morphology of the basement

Highly variable content of fluorapatite-hosted CO32- in the Upper Cretaceous/Paleogene phosphorites (Morocco) and implications for paleodepositional conditions

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Phosphate δ13Corg chemostratigraphy from the Gantour basin, Morocco: A proof of concept from the K–Pg transition to mid-Thanetian

The Late Cretaceous–early Paleogene interval is globally associated with transient to long-term changes in the stable carbon isotopic composition of marine carbonates (δ13Ccarb). Based on biostratigraphic reconstruction, this critical period of Earth's history is thought to coincide with the deposition of world heritage Paleocene phosphate deposits (phosphorites) in northwestern Morocco. However, the detailed stratigraphy of the Gantour basin, one of the most important Moroccan phosphate deposits, has not yet been constrained. For instance, the former “Montian” Stage has been used to tentatively approximate the Danian, whereas the succeeding Selandian Stage remains to be identified. Here, we develop a detailed organic carbon isotopic (δ13Corg) curve from phosphorus-rich horizons of the western Gantour sedimentary sequence in an attempt to constrain their stratigraphic placement and depositional age model. Upsection, these strata host long-term negative and positive δ13Corg trends that tend to correlate with global δ13Ccarb records of the Cretaceous–Paleogene and mid-Thanetian transitional boundaries. The data support the presence of Danian and Selandian rocks in the Gantour basin, which are succeeded by strata containing characteristic signatures of the well-known Cenozoic δ13C maximum at 58–57.5 Ma (the Paleocene Carbon Isotope Maximum). Our results shift the previously proposed Cretaceous–Paleogene transition in the Gantour basin further down into the older sediment CM layer without interfering with recorded massive biological turnover in faunal diversity and abundance. Moreover, the refined stratigraphy suggests that the deposition of the Gantour phosphorites spanned ~8.5 Myr. Our results confirm the utility of δ13Corg chemostratigraphy for dating and correlating phosphate-bearing deposits of the Tethyan province. They have important implications for deciphering Paleocene phosphogenesis, the co-evolution of associated vertebrate groups, and for prospecting phosphorus-rich mineral deposits