996 research outputs found

    Witness preparation in the ICC: an opportunity for principled pragmatism

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    In January 2013, Trial Chamber V of the International Criminal Court (ICC) in the cases of William Ruto and Joshua Sang and of Francis Muthaura and Uhuru Kenyatta, collectively known as the ‘Kenya decisions’, made a marked departure from the firm prohibition on ‘witness proofing’ established by the ICC's Pre-Trial and Trial Chamber I in the Lubanga decisions. This reversal illustrates the polarization of an issue that has caused considerable controversy in the international legal community and demonstrates the challenges faced by the Court in navigating such a controversy. While the practice may be viewed as a fault line between two different procedural cultures, forever destined to be subject to debate, this article explores an alternative view, examining the reasons for this turnaround and proposing an approach based on ‘principled pragmatism’. In doing so, it considers whether witness preparation is coming to be regarded as a necessary part of ICC practice

    Negative Differential Resistance, Memory and Reconfigurable Logic Functions based on Monolayer Devices derived from Gold Nanoparticles Functionalized with Electro-polymerizable Thiophene-EDOT Units

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    We report on hybrid memristive devices made of a network of gold nanoparticles (10 nm diameter) functionalized by tailored 3,4(ethylenedioxy)thiophene (TEDOT) molecules, deposited between two planar electrodes with nanometer and micrometer gaps (100 nm to 10 um apart), and electropolymerized in situ to form a monolayer film of conjugated polymer with embedded gold nanoparticles (AuNPs). Electrical properties of these films exhibit two interesting behaviors: (i) a NDR (negative differential resistance) behavior with a peak/valley ratio up to 17, and (ii) a memory behavior with an ON/OFF current ratio of about 1E3 to 1E4. A careful study of the switching dynamics and programming voltage window is conducted demonstrating a non-volatile memory. The data retention of the ON and OFF states is stable (tested up to 24h), well controlled by the voltage and preserved when repeating the switching cycles (800 in this study). We demonstrate reconfigurable Boolean functions in multiterminal connected NP molecule devices.Comment: Full manuscript, figures and supporting information, J. Phys. Chem. C, on line, asap (2017

    A case of chronic progressive Lyme encephalitis as a manifestation of late Lyme neuroborreliosis

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    A 54-year-old female living in Europe presented with gait ataxia, dizziness, and bilateral hearing loss. Magnetic resonance imaging (MRI) revealed non-specific white matter changes. The patient's condition gradually deteriorated over two years without diagnosis. The patient continued to decline cognitively and neurologically with worsening ataxia and upper motor neuron signs. Repeat MRI showed worsening white matter changes. Lumbar puncture, not previously done, showed positive Lyme testing. Treatment with intravenous ceftriaxone resulted in marked neurological improvement. Four years after symptom, the patient has short-term memory deficits and chronic fatigue, but is otherwise neurologically, cognitively, and functionally intact. Follow up MRI findings remain largely unchanged. Because cases of intraparenchymal or encephalopathic neuroborreliosis in America are lacking, so are treatment options. We present a rare case and discuss our experience with antibiotic treatment. This case lends evidence to define optimal treatment of this disease, imperative for hastening neurological recovery

    Intra-Ring Variations in Mature Douglas-Fir Trees From Provenance Plantations

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    Variations in seven intra-ring characteristics were studied in juvenile and mature wood from two Douglas-fir [Pseudotsuga menziesii (Mirb.) Franco] genetic plantations. Samples were collected from 30 families representing 10 provenances with two replicates in each plantation. The following characteristics were determined by X-ray densitometry: earlywood density (EWD), latewood density (LWD), average ring density (RD), earlywood width (EWW), latewood width (LWW), total ring width (RW), and latewood proportion (LWP). Variation patterns were analyzed by two models: (1) families pooled across provenances and (2) provenances and families-within-provenances.Differences between plantations were significant for all traits except juvenile RD and mature RW and EWD. Variance components associated with families (pooled across provenances) remained the same with stand development and were biased upwards as a result of provenance variation. Genetic variation resulting from provenances was evident for RD and EWD, but (except for LWP) was relatively unimportant for RW parameters. Selection for families within populations can contribute to juvenile RW, as well as to mature RD and LWP

    Functionalized Gold Nanoparticles with Electropolymerizable π-Conjugated Systems for a Neuro-inspired Memristive Nanoparticle Organic Synapse-Transistor

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    Nanoparticle Organic Memory Field-Effect Transistors (NOMFET) are molecule-based devices that exhibit the main behavior of a biological spiking synapse. This behavior is obtained by virtue of the combination of two properties of the NOMFET: the transconductance gain of the transistor and the memory effect due to the presence of nanoparticles (NPs) which are used as nanoscale capacitors to store the electrical charges, and which are embedded into an organic semiconducting layer [1]. Thus, the transconductance of the transistor can be dynamically tuned by the amount of charge in the NPs. In this context, we present here a novel method for the elaboration of NOMFET active materials based on the electrochemical deposition of gold NPs grafted with alkanethiol-terminated π-conjugated precursors combining low oxidation potential and high reactivity. The straightforward electropolymerization of these new precursors leads to the formation of a semiconducting network in which the electronic and transport properties and the charging/discharging speed of the gold NPs can be modulated. Such hybrid material could advantageously replace the pentacene layer generally used in NOMFETs. This novel approach is based on previously demonstrated enhancement of charge-tunneling across monolayers of SAMs of alkanethiol-bithiophenic systems on a planar gold surface after electrochemical conversion into more extended conjugated systems [2]. The synthesis of the precursors and nanoparticles will be described and the morphology and electronic properties of the hybrid electropolymerized films will be discussed with regard to the behavior of the resulting NOMFET-devices. [1] F. Alibart, S. Pleutin, D. Guerin, C. Novembre, S. Lenfant, K. Lmimouni, C. Gamrat, D. Vuillaume, Adv. Funct. Mater. 2010, 20, 330-337. [2] M. Oçafrain, T. K. Tran, P. Blanchard, S. Lenfant, S. Godey, D. Vuillaume, J. Roncali, Adv. Funct. Mater. 2008, 18, 2163-2171

    The Moderating Effect of Audit Quality on the Links Between Stock Market Segmentations, Surplus Free Cash Flow, and Income-increasing Discretionary Accruals

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    The objective of this paper is to examine the impacts of stock market segmentations (SMS) and surplus free cash flow (SFCF) on income-increasing discretionary accruals. The study also provides the initial evidence regarding the influence of audit quality (AQ) as a moderating variable on those relationships. A sample of non-financial firms was taken from the list of Amman Stock Exchange over the period 2013-2019. Using Huber-White’s sandwich estimator for pooled OLS regression, the current research presents empirical evidence harmonious with the prediction in all hypotheses. Further, the findings document that a Big 4 auditor weakens the SMS-DAC and SFCF-DAC associations, which suggests that the role of Big 4 audit firms is effective in mitigating management’s opportunistic behaviour. However, the reported results provide beneficial information to investors, regulators, external auditors, policymakers, shareholders, and other countries with similar institutional environment
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