Markers of masculinity in Khanty, Russian, Kazakh and Chinese folklore: Pragma-Cognitive aspect

The article is devoted to the analysis of the psycholinguistic features of the male portrait in fairy tales in the different structural linguistic cultures: Khanty, Russian, Kazakh and Chinese. The choice is determined by the belonging of these peoples to traditional cultures with varying degrees of transformation of behavioral stereotypes. Traditional culture considers a man as the head of a large family, a protector, a breadwinner, a landowner with the competencies of a fisherman and a hunter, so a woman with children needs his help and care. In this regard, the purpose of this study is the need, based on the psycholinguistic features of personal characteristics, to reveal the masculine image in the tales of Khanty, Russians, Kazakhs and Chinese. The authors analyze the psycholinguistic and stylistic means of representing masculine traits in the fairy tales of these peoples. Kazakh, Khanty, Russian and Chinese fairy tales for the first time become the object of psycholinguistic characterization of personal characteristics on the example of the image of masculinity. The course of reasoning on the topic of the study leads the authors to the conclusion that the analyzed original texts of fairy tales contrast with a reliable representation of the ethnic group.  The traditional male portrait is shown from the position of describing the psycholinguistic features of personal characteristics, through the relationship of the main characters, through their external and internal speech. This approach makes it possible to identify a set of ethnic, social, historical and geographical factors inextricably linked with language, on the one hand, and on the other – caused by psychological manifestations

Inorganic Nitrile Halides in the Synthesis of Halogen-, Nitro- and Halogenated Nitro-Products

Проведено теоретическое и экспериментальное изучение неорганических нитрилгалогенидов в реакциях галогенирования, нитрования и нитрогалогенирования аренов и алкинов. Показано, что при использовании системы I2 (Hal-) в присутствии нитратов щелочных металлов в среде уксусной кислоты возможно образование нитрилгалогенидов. В зависимости от природы галогенида получены продукты йодирования, нитрования, нитрогалогенирования, циклизации, окисления органических субстратов. Для осуществления направленного синтеза проведены теоретические квантово-химические расчеты промежуточных частиц – нитрилгалогенидов – с использованием стандартного пакета программ Gaussian‑03. Расчет показал возможность образования частиц NO2Hal, их геометрию и распад по гомо- или гетеролитическому механизмуInorganic nitrile halides have been studied theoretically by quantum-chemical approach and experimentally in the reactions of halogenation, nitration and nitro halogenation of aromatic compounds and alkynes. The generation of nitrile halides was eventually proved can be can be carried out using the iodine system (alkali metal halides) in the presence of alkali metal nitrates in an acetic acid medium. It has been found that the reaction can give the products of iodination, nitration, nitro halogenation, as well as products of cyclization, and oxidation depending on the nature of the halogen. To predict the products of reaction theoretical quantum-chemical calculations for intermediate particles – nitrile halides using the standard Gaussian‑03 software package were carried out. The possibility of NO2Hal formation was approved from quantum calculations. Furthermore the geometry of NO2Hal particles and mechanism of their homo- or heterolytic decay were represente