Tunable, multi-modal, and multi-directional vibration energy harvester based on three-dimensional architected metastructures

Conventional vibration energy harvesters based on two-dimensional planar layouts have limited harvesting capacities due to narrow frequency bandwidth and because their vibratory motion is mainly restricted to one plane. Three-dimensional architected structures and advanced materials with multifunctional properties are being developed in a broad range of technological fields. Structural topologies exploiting compressive buckling deformation mechanisms however provide a versatile route to transform planar structures into sophisticated three-dimensional architectures and functional devices. Designed geometries and Kirigami cut patterns defined on planar precursors contribute to the controlled formation of diverse three-dimensional forms. In this work, we propose an energy harvesting system with tunable dynamic properties, where piezoelectric materials are integrated and strategically designed into three-dimensional compliant architected metastructures. This concept enables energy scavenging from vibrations not only in multiple directions but also across a broad frequency bandwidth, thus increasing the energy harvesting efficiency. The proposed system comprises a buckled ribbon with optional Kirigami cuts. This platform enables the induction of vibration modes across a wide range of resonance frequencies and in arbitrary directions, mechanically coupling with four cantilever piezoelectric beams to capture vibrations. The multi-modal and multi-directional harvesting performance of the proposed configurations has been demonstrated in comparison with planar systems. The results suggest this is a facile strategy for the realization of compliant and high-performance energy harvesting and advanced electronics systems based on mechanically assembled platforms

Two-dimensional graded metamaterials with auxetic rectangular perforations

This work describes the in-plane uniaxial tensile mechanical properties of two-dimensional graded rectangular perforations metamaterials using numerical homogenization finite element approaches benchmarked by experimental results. The metamaterial configuration is based on graded patterns of centre-symmetric perforated cells that can exhibit an auxetic (negative Poisson's ratio) behavior. Global and local equivalent mechanical properties of the metamaterial are measured using digital image correlation techniques mapped over Finite Element models to identify strain patterns and related stress distributions at different scales. The samples and their numerical counterpart are parametrized against the spacing and aspect ratios of the cells. The overall stiffness behavior of the graded perforated metamaterial plates features a higher degree of compliance that depends both on the geometries of the cells of the graded areas, but also on the graded pattern used. Local Poisson's ratio effects show a general constraint of the auxetic behavior compared to the case of uniform plates, but also interesting and controllable shape changes due to the uniaxial tensile loading applied

SnS2 quantum dots: facile synthesis, properties and applications in ultraviolet photodetector

Tin sulfide quantum dots (SnS2 QDs) are n-type wide band gap semiconductor. They exhibit a high optical absorption coefficient and strong photoconductive property in the ultraviolet and visible regions. Therefore, they have been found to have many potential applications, such as gas sensors, resistors, photodetectors, photocatalysts, and solar cells. However, the existing preparation methods for SnS2 QDs are complicated and require a high temperature and high pressure environment; hence they are unsuitable for large-scale industrial production. An effective method for the preparation of monodispersed SnS2 QDs at normal temperature and pressure will be discussed in this paper. The method is facile, green, and low-cost. In this work, the structure, morphology, optical, electrical, and photoelectric properties of SnS2 QDs are studied. The synthesized SnS2 QDs are homogeneous in size and exhibit good photoelectric performance. A photoelectric detector based on the SnS2 QDs is fabricated and its J-V and C-V characteristics are also studied. The detector responds under λ=365 nm light irradiation and reverse bias voltage. Its detectivity approximately stabilizes at 1011 Jones at room temperature. These results show the possible use of SnS2 QDs in photodetectors

In2S3 Quantum Dots: Preparation, Properties and Optoelectronic Application

Low-dimensional semiconductors exhibit remarkable performances in many device applications because of their unique physical, electrical, and optical properties. In this paper, we report a novel and facile method to synthesize In2S3 quantum dots (QDs) at atmospheric pressure and room temperature conditions. This involves the reaction of sodium sulfide with indium chloride and using sodium dodecyl sulfate (SDS) as a surfactant to produce In2S3 QDs with excellent crystal quality. The properties of the as-prepared In2S3 QDs were investigated and photodetectors based on the QDs were also fabricated to study the use of the material in optoelectronic applications. The results show that the detectivity of the device stabilizes at ~ 1013 Jones at room temperature under 365 nm ultraviolet light irradiation at reverse bias voltage

Mechanically active materials in three-dimensional mesostructures

Complex, three-dimensional (3D) mesostructures that incorporate advanced, mechanically active materials are of broad, growing interest for their potential use in many emerging systems. The technology implications range from precision-sensing microelectromechanical systems, to tissue scaffolds that exploit the principles of mechanobiology, to mechanical energy harvesters that support broad bandwidth operation. The work presented here introduces strategies in guided assembly and heterogeneous materials integration as routes to complex, 3D microscale mechanical frameworks that incorporatemultiple, independently addressable piezoelectric thin-film actuators for vibratory excitation and precise control. The approach combines transfer printing as a scheme formaterials integrationwith structural buckling as ameans for 2D-to-3D geometric transformation, for designs that range from simple, symmetric layouts to complex, hierarchical configurations, on planar or curvilinear surfaces. Systematic experimental and computational studies reveal the underlying characteristics and capabilities, including selective excitation of targeted vibrational modes for simultaneous measurements of viscosity and density of surrounding fluids. The results serve as the foundations for unusual classes of mechanically active 3D mesostructures with unique functions relevant to biosensing, mechanobiology, energy harvesting, and others

Red blood cell distribution width/platelet ratio on admission as a predictor for in-hospital mortality in patients with acute myocardial infarction: a retrospective analysis from MIMIC-IV Database

Abstract Background Red blood cell distribution width (RDW) to platelet ratio (RPR) is a novel inflammatory indicator. It integrates the risk prediction of RDW and platelet, which is associated with adverse outcomes. However, the predictive power of RPR in mortality for patients with acute myocardial infarction (AMI) remains uncertain. Thus, we aimed to explore the association between RPR and 180-day in-hospital mortality in patients with AMI. Methods Data on patients with AMI were extracted from the Medical Information Mart for Intensive Care IV (MIMIC-IV) database. Patients were divided into two groups according to the optimal RPR cut-off value. The survival curve between high and low RPR groups was plotted via the Kaplan-Meier (KM) method. Univariate and multivariate Cox regression analyses were performed to determine the association between RPR on admission and 180-day in-hospital mortality. Results A total of 1266 patients were enrolled, of which 83 (6.8%) died within 180 days during the hospitalization. Compared with the survivor group, the non-survivor group had higher RPR on admission (0.11 ± 0.07 vs. 0.08 ± 0.06, P < 0.001). The KM curve indicated that the survival probability of low RPR group was higher than that of high RPR group. Multivariate Cox regression analysis demonstrated that higher RPR on admission was an independent and effective predictor of 180-day mortality in patients with AMI (hazard ratio [HR]: 2.677, 95% confidence interval [CI]: 1.159–6.188, P = 0.021). Conclusion Higher RPR was associated with higher in-hospital 180-day mortality in patients with AMI

Continuous removal of small nonviable suspended mammalian cells and debris from bioreactors using inertial microfluidics

Removing nonviable cells from a cell suspension is crucial in biotechnology and biomanufacturing. Label-free microfluidic cell separation devices based on dielectrophoresis, acoustophoresis, and deterministic lateral displacement are used to remove nonviable cells. However, their volumetric throughputs and test cell concentrations are generally too low to be useful in typical bioreactors in biomanufacturing. In this study, we demonstrate the efficient removal of small (<10 μm) nonviable cells from bioreactors while maintaining viable cells using inertial microfluidic cell sorting devices and characterize their performance. Despite the size overlap between viable and nonviable cell populations, the devices demonstrated 3.5-28.0% dead cell removal efficiency with 88.3-83.6% removal purity as well as 97.8-99.8% live cell retention efficiency at 4 million cells per mL with 80% viability. Cascaded and parallel configurations increased the cell concentration capacity (10 million cells per mL) and volumetric throughput (6-8 mL min-1). The system can be used for the removal of small nonviable cells from a cell suspension during continuous perfusion cell culture operations

Synthesis and Catalytic Activity of Activated Carbon Supported Sulfonated Cobalt Phthalocyanine in the Preparation of Dimethyl Disulfide

The Merox process was widely applied in the fine chemical industry to convert mercaptans into disulfides by oxidation with oxygen, including dimethyl disulfide (DMDS). In this paper, a new activated carbon (AC)-supported sulfonated cobalt phthalocyanine (AC-CoPcS) catalyst was prepared through the chemical linkage of ethylenediamine between them. UV&minus;VIS, FT-IR, BET, and XPS were used to characterize the structure of the new catalyst. Then AC-CoPcS was applied to catalyze sodium methylmercaptide (SMM) oxidation for the preparation of DMDS. The effect of process parameters, such as reaction time, catalyst dosage, reaction temperature, and oxygen pressure on SMM conversion per pass (CPPSMM), yield (YieldDMDS), and purity of the DMDS (PurityDMDS) product were investigated to evaluate the catalytic performance of AC-CoPcS. The new supported catalyst exhibits better catalytic performance than the commercial one and can be properly reused four times to obtain CPPSMM and YieldDMDS higher than 90% and 70%. Under the optimum experimental conditions, the CPPSMM and YieldDMDS could reach as high as 98.7% and 86.8%, respectively, and the purity of the DMDS product is as high as 99.8%. This new supported catalyst exhibits good industrial application prospects