3,302 research outputs found
Exact Zeros of the Partition Function for a Continuum System with Double Gaussian Peaks
We calculate the exact zeros of the partition function for a continuum system
where the probability distribution for the order parameter is given by two
asymmetric Gaussian peaks. When the positions of the two peaks coincide, the
two separate loci of zeros which used to give first-order transition touch each
other, with density of zeros vanishing at the contact point on the positive
real axis. Instead of the second-order transition of Ehrenfast classification
as one might naively expect, one finds a critical behavior in this limit.Comment: 13 pages, 6 figures, revtex, minor changes in fig.2, to be published
in Physical Review
Resonant x-ray scattering study on multiferroic BiMnO3
Resonant x-ray scattering is performed near the Mn K-absorption edge for an
epitaxial thin film of BiMnO3. The azimuthal angle dependence of the resonant
(003) peak (in monoclinic indices) is measured with different photon
polarizations; for the channel a 3-fold symmetric oscillation
is observed in the intensity variation, while the scattering
intensity remains constant. These features are accounted for in terms of the
peculiar ordering of the manganese 3d orbitals in BiMnO3. It is demonstrated
that the resonant peak persists up to 770 K with an anomaly around 440 K; these
high and low temperatures coincide with the structural transition temperatures,
seen in bulk, with and without a symmetry change, respectively. A possible
relationship of the orbital order with the ferroelectricity of the system is
discussed.Comment: 14 pages, 4 figure
A Generalized Circle Theorem on Zeros of Partition Function at Asymmetric First Order Transitions
We present a generalized circle theorem which includes the Lee-Yang theorem
for symmetric transitions as a special case. It is found that zeros of the
partition function can be written in terms of discontinuities in the
derivatives of the free energy. For asymmetric transitions, the locus of the
zeros is tangent to the unit circle at the positive real axis in the
thermodynamic limit. For finite-size systems, they lie off the unit circle if
the partition functions of the two phases are added up with unequal prefactors.
This conclusion is substantiated by explicit calculation of zeros of the
partition function for the Blume-Capel model near and at the triple line at low
temperatures.Comment: 10 pages, RevTeX. To be published in PRL. 3 Figures will be sent upon
reques
Orbital ordering and enhanced magnetic frustration of strained BiMnO3 thin films
Epitaxial thin films of multiferroic perovskite BiMnO3 were synthesized on
SrTiO3 substrates, and orbital ordering and magnetic properties of the thin
films were investigated. The ordering of the Mn^{3+} e_g orbitals at a wave
vector (1/4 1/4 1/4) was detected by Mn K-edge resonant x-ray scattering. This
peculiar orbital order inherently contains magnetic frustration. While bulk
BiMnO3 is known to exhibit simple ferromagnetism, the frustration enhanced by
in-plane compressive strains in the films brings about cluster-glass-like
properties.Comment: 8 pages, 4 figures, accepted to Europhysics Letter
The behaviour of stacking fault energy upon interstitial alloying
Stacking fault energy is one of key parameters for understanding the mechanical properties of face-centered cubic materials. It is well known that the plastic deformation mechanism is closely related to the size of stacking fault energy. Although alloying is a conventional method to modify the physical parameter, the underlying microscopic mechanisms are not yet clearly established. Here, we propose a simple model for determining the effect of interstitial alloying on the stacking fault energy. We derive a volumetric behaviour of stacking fault energy from the harmonic approximation to the energy-lattice curve and relate it to the contents of interstitials. The stacking fault energy is found to change linearly with the interstitial content in the usual low concentration domain. This is in good agreement with previously reported experimental and theoretical data.111Ysciescopu
The mechanism of striation formation in plasma display panels
Despite the high pressure employed in plasma display panels, the energy balance of low-energy
electrons is found to be dominated by inelastic collisions, and the resulting nonlocal electron
kinetics plays a key role in the striation formation. Surface charge accumulation on the anode
dielectric, however, is also needed for striations to form. It is the combined effect of surface charges
and nonlocal electron kinetics that results in the striation formation in plasma display panel cells.
Two-dimensional fluid simulations, which assume local electron kinetics, and two-dimensional
particle-in-cell Monte Carlo collision simulations with a bare conducting anode show that striations
do not form if either the nonlocal electron kinetics or the surface charge accumulation is not considered
The adjunctive effect of polydeoxyribonucleotide on bone formation in alveolar ridge preservation: A pre-clinical in vivo study
AimThis study investigated the adjunctive effect of polydeoxyribonucleotide (PDRN) on bone formation in alveolar ridge preservation (ARP) sockets.Materials and MethodsBoth mandibular second, third and fourth premolars of eight beagle dogs were randomly divided into ARP and ARP/PDRN groups. Following tooth extraction, ARP procedures were conducted using collagenized alloplastic graft material and bilayer collagen membrane soaked with normal saline (ARP group) or PDRN (ARP/PDRN group) for 10 min before application. Both groups were also randomly allocated to 2-, 4- or 12-week healing subgroups. The primary endpoint of this study was to compare histomorphometric differences between ARP and ARP/PDRN. The secondary endpoints of this study were to compare micro-CT analysis and three-dimensional volumetric measurement between the two groups.ResultsIn the histomorphometric analysis, the ARP/PDRN group exhibited greater new bone formation at coronal, middle and total position compared with the ARP group at 2-week healing. The number of newly formed blood vessels was higher in the ARP/PDRN group than in the ARP group at 2- and 4-week healing. In micro-CT analysis, the mean new bone volume/total bone volume between ARP and ARP/PDRN was statistically significant at 2-week healing. Ridge volume alterations were significantly decreased in the ARP/PDRN group during entire healing time compared with the ARP group, especially on the buccal side.ConclusionsThe application of PDRN in ARP might provide additional benefits for early bone regeneration and maintenance of buccal ridge volume
Activation of spleen tyrosine kinase is required for TNF-α-induced endothelin-1 upregulation in human aortic endothelial cells
AbstractEndothelin-1 (ET-1) promotes atherosclerosis. We tested whether spleen tyrosine kinase (Syk) mediates tumor necrosis factor-α (TNF-α)-induced ET-1 upregulation in human aortic endothelial cells (HAECs) and sought to identify the signal pathways involved. TNF-α-induced reactive oxygen species (ROS) activated Syk and phosphatidylinositol 3-kinase (PI3K), which was required for the activation of AP-1 and subsequent ET-1 gene transcription. ROS mediated c-Jun NH2-terminal kinase (JNK) is also required for AP-1 activation, but Syk and PI3K regulated AP-1 activation independently of JNK. Through regulation of ET-1 production, Syk could be implicated in atherosclerosis
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Surface-to-Bulk Redox Coupling through Thermally Driven Li Redistribution in Li- and Mn-Rich Layered Cathode Materials.
Li- and Mn-rich (LMR) layered cathode materials have demonstrated impressive capacity and specific energy density thanks to their intertwined redox centers including transition metal cations and oxygen anions. Although tremendous efforts have been devoted to the investigation of the electrochemically driven redox evolution in LMR cathode at ambient temperature, their behavior under a mildly elevated temperature (up to ∼100 °C), with or without electrochemical driving force, remains largely unexplored. Here we show a systematic study of the thermally driven surface-to-bulk redox coupling effect in charged Li1.2Ni0.15Co0.1Mn0.55O2. We for the first time observed a charge transfer between the bulk oxygen anions and the surface transition metal cations under ∼100 °C, which is attributed to the thermally driven redistribution of Li ions. This finding highlights the nonequilibrium state and dynamic nature of the LMR material at deeply delithiated state upon a mild temperature perturbation
Bedside prediction of right subclavian venous catheter insertion length
AbstractBackground and objectiveThe present study aimed to evaluate whether right subclavian vein (SCV) catheter insertion depth can be predicted reliably by the distances from the SCV insertion site to the ipsilateral clavicular notch directly (denoted as I-IC), via the top of the SCV arch, or via the clavicle (denoted as I-T-IC and I-C-IC, respectively).MethodIn total, 70 SCV catheterizations were studied. The I-IC, I-T-IC, and I-C-IC distances in each case were measured after ultrasound-guided SCV catheter insertion. The actual length of the catheter between the insertion site and the ipsilateral clavicular notch, denoted as L, was calculated by using chest X-ray.ResultsL differed from the I-T-IC, I-C-IC, and I-IC distances by 0.14±0.53, 2.19±1.17, and −0.45±0.68cm, respectively. The mean I-T-IC distance was the most similar to the mean L (intraclass correlation coefficient=0.89). The mean I-IC was significantly shorter than L, while the mean I-C-IC was significantly longer. Linear regression analysis provided the following formula: Predicted SCV catheter insertion length (cm)=−0.037+0.036×Height (cm)+0.903×I-T-IC (cm) (adjusted r2=0.64).ConclusionThe I-T-IC distance may be a reliable bedside predictor of the optimal insertion length for a right SCV cannulation
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