Differential thermal analysis and solution growth of intermetallic compounds

To obtain single crystals by solution growth, an exposed primary solidification surface in the appropriate, but often unknown, equilibrium alloy phase diagram is required. Furthermore, an appropriate crucible material is needed, necessary to hold the molten alloy during growth, without being attacked by it. Recently, we have used the comparison of realistic simulations with experimental differential thermal analysis (DTA) curves to address both these problems. We have found: 1) complex DTA curves can be interpreted to determine an appropriate heat treatment and starting composition for solution growth, without having to determine the underlying phase diagrams in detail. 2) DTA can facilitate identification of appropriate crucible materials. DTA can thus be used to make the procedure to obtain single crystals of a desired phase by solution growth more efficient. We will use some of the systems for which we have recently obtained single-crystalline samples using the combination of DTA and solution growth as examples. These systems are TbAl, Pr$_7$Ni$_2$Si$_5$, and YMn$_4$Al$_8$.Comment: 17 pages, 8 figure

The granular silo as a continuum plastic flow: the hour-glass vs the clepsydra

The granular silo is one of the many interesting illustrations of the thixotropic property of granular matter: a rapid flow develops at the outlet, propagating upwards through a dense shear flow while material at the bottom corners of the container remains static. For large enough outlets, the discharge flow is continuous; however, by contrast with the clepsydra for which the flow velocity depends on the height of fluid left in the container, the discharge rate of granular silos is constant. Implementing a plastic rheology in a 2D Navier-Stokes solver (following the mu(I)-rheology or a constant friction), we simulate the continuum counterpart of the granular silo. Doing so, we obtain a constant flow rate during the discharge and recover the Beverloo scaling independently of the initial filling height of the silo. We show that lowering the value of the coefficient of friction leads to a transition toward a different behavior, similar to that of a viscous fluid, and where the filling height becomes active in the discharge process. The pressure field shows that large enough values of the coefficient of friction ($\simeq$ 0.3) allow for a low-pressure cavity to form above the outlet, and can thus explain the Beverloo scaling. In conclusion, the difference between the discharge of a hourglass and a clepsydra seems to reside in the existence or not of a plastic yield stress.Comment: 6 pages, 6 figure

Very Long Baseline Interferometry Measured Proper Motion and Parallax of the γ\gamma-ray Millisecond Pulsar PSR J0218+4232

PSR J0218$+$4232 is a millisecond pulsar (MSP) with a flux density $\sim$ 0.9 mJy at 1.4 GHz. It is very bright in the high-energy X-ray and $\gamma$-ray domains. We conducted an astrometric program using the European VLBI Network (EVN) at 1.6 GHz to measure its proper motion and parallax. A model-independent distance would also help constrain its $\gamma$-ray luminosity. We achieved a detection of signal-to-noise ratio S/N > 37 for the weak pulsar in all five epochs. Using an extragalactic radio source lying 20 arcmin away from the pulsar, we estimate the pulsar's proper motion to be $\mu_{\alpha}\cos\delta=5.35\pm0.05$ mas yr$^{-1}$ and $\mu_{\delta}=-3.74\pm 0.12$ mas yr$^{-1}$, and a parallax of $\pi=0.16\pm0.09$ mas. The very long baseline interferometry (VLBI) proper motion has significantly improved upon the estimates from long-term pulsar timing observations. The VLBI parallax provides the first model-independent distance constraints: $d=6.3^{+8.0}_{-2.3}$ kpc, with a corresponding $3\sigma$ lower-limit of $d=2.3$ kpc. This is the first pulsar trigonometric parallax measurement based solely on EVN observations. Using the derived distance, we believe that PSR J0218$+$4232 is the most energetic $\gamma$-ray MSP known to date. The luminosity based on even our 3$\sigma$ lower-limit distance is high enough to pose challenges to the conventional outer gap and slot gap models.Comment: 5 pages, 2 figures, 2 tables; published in the Astrophysical Journal Letters on 2014 Feb. 1

Multistage Zeeman deceleration of atomic and molecular oxygen

Multistage Zeeman deceleration is a technique used to reduce the velocity of neutral molecules with a magnetic dipole moment. Here we present a Zeeman decelerator that consists of 100 solenoids and 100 magnetic hexapoles, that is based on a short prototype design presented recently [Phys. Rev. A 95, 043415 (2017)]. The decelerator features a modular design with excellent thermal and vacuum properties, and is robustly operated at a 10 Hz repetition rate. This multistage Zeeman decelerator is particularly optimized to produce molecular beams for applications in crossed beam molecular scattering experiments. We characterize the decelerator using beams of atomic and molecular oxygen. For atomic oxygen, the magnetic fields produced by the solenoids are used to tune the final longitudinal velocity in the 500 - 125 m/s range, while for molecular oxygen the velocity is tunable in the 350 - 150 m/s range. This corresponds to a maximum kinetic energy reduction of 95% and 80% for atomic and molecular oxygen, respectively.Comment: Latest version as accepted by Physical Review

AgroDataCube and AGINFRA+: Operationalising Big Data for Agricultural Informatics

Big Data methods and tools are becoming widely adopted by the ICT industry and create new opportunities for data intensive science in the agro-environmental domain. However, Big Data adoption is still in its infancy for Agricultural Information Systems, and many barriers still exist for wider use of big data analysis ..

Charge Transport Properties of a Metal-free Phthalocyanine Discotic Liquid Crystal

Discotic liquid crystals can self-align to form one-dimensional semiconducting wires, many tens of microns long. In this letter, we describe the preparation of semiconducting films where the stacking direction of the disc-like molecules is perpendicular to the substrate surface. We present measurements of the charge carrier mobility, applying temperature-dependent time-of-flight transient photoconductivity, space-charge limited current measurements, and field-effect mobility measurements. We provide experimental verification of the highly anisotropic nature of semiconducting films of discotic liquid crystals, with charge carrier mobilities of up to 2.8x10$^{-3}$cm$^2$/Vs. These properties make discotics an interesting choice for applications such as organic photovoltaics.Comment: 5 pages, 5 figure