To obtain single crystals by solution growth, an exposed primary
solidification surface in the appropriate, but often unknown, equilibrium alloy
phase diagram is required. Furthermore, an appropriate crucible material is
needed, necessary to hold the molten alloy during growth, without being
attacked by it. Recently, we have used the comparison of realistic simulations
with experimental differential thermal analysis (DTA) curves to address both
these problems. We have found: 1) complex DTA curves can be interpreted to
determine an appropriate heat treatment and starting composition for solution
growth, without having to determine the underlying phase diagrams in detail. 2)
DTA can facilitate identification of appropriate crucible materials. DTA can
thus be used to make the procedure to obtain single crystals of a desired phase
by solution growth more efficient. We will use some of the systems for which we
have recently obtained single-crystalline samples using the combination of DTA
and solution growth as examples. These systems are TbAl, Pr7​Ni2​Si5​,
and YMn4​Al8​.Comment: 17 pages, 8 figure