Atomic-scale combination of germanium-zinc nanofibers for structural and electrochemical evolution

Alloys are recently receiving considerable attention in the community of rechargeable batteries as possible alternatives to carbonaceous negative electrodes; however, challenges remain for the practical utilization of these materials. Herein, we report the synthesis of germanium-zinc alloy nanofibers through electrospinning and a subsequent calcination step. Evidenced by in situ transmission electron microscopy and electrochemical impedance spectroscopy characterizations, this one-dimensional design possesses unique structures. Both germanium and zinc atoms are homogenously distributed allowing for outstanding electronic conductivity and high available capacity for lithium storage. The as-prepared materials present high rate capability (capacity of similar to 50% at 20 C compared to that at 0.2 C-rate) and cycle retention (73% at 3.0 C-rate) with a retaining capacity of 546 mAh g(-1) even after 1000 cycles. When assembled in a full cell, high energy density can be maintained during 400 cycles, which indicates that the current material has the potential to be used in a large-scale energy storage system

Vibrational Modes in LiBC: Theory Compared with Experiment

The search for other superconductors in the MgB2 class currently is focussed on Li{1-x}BC, which when hole-doped (concentration x) should be a metal with the potential to be a better superconductor than MgB2. Here we present the calculated phonon spectrum of the parent semiconductor LiBC. The calculated Raman-active modes are in excellent agreement with a recent observation, and comparison of calculated IR-active modes with a recent report provides a prediction of the LO--TO splitting for these four modes, which is small for the B-C bond stretching mode at ~1200 cm^{-1}, but large for clearly resolved modes at 540 cm^{-1} and 620 cm^{-1}.Comment: 4 pages, two embedded figures. Physica B (in press

A Revised Effective Temperature Scale for the Kepler Input Catalog

We present a catalog of revised effective temperatures for stars observed in long-cadence mode in the Kepler Input Catalog (KIC). We use SDSS griz filters tied to the fundamental temperature scale. Polynomials for griz color-temperature relations are presented, along with correction terms for surface gravity effects, metallicity, and statistical corrections for binary companions or blending. We compare our temperature scale to the published infrared flux method (IRFM) scale for VJKs in both open clusters and the Kepler fields. We find good agreement overall, with some deviations between (J - Ks)-based temperatures from the IRFM and both SDSS filter and other diagnostic IRFM color-temperature relationships above 6000 K. For field dwarfs we find a mean shift towards hotter temperatures relative to the KIC, of order 215 K, in the regime where the IRFM scale is well-defined (4000 K to 6500 K). This change is of comparable magnitude in both color systems and in spectroscopy for stars with Teff below 6000 K. Systematic differences between temperature estimators appear for hotter stars, and we define corrections to put the SDSS temperatures on the IRFM scale for them. When the theoretical dependence on gravity is accounted for we find a similar temperature scale offset between the fundamental and KIC scales for giants. We demonstrate that statistical corrections to color-based temperatures from binaries are significant. Typical errors, mostly from uncertainties in extinction, are of order 100 K. Implications for other applications of the KIC are discussed.Comment: Corrected for sign flip errors in the gravity corrections. Erratum to this paper is attached in Appendix. Full version of revised Table 7 can be found at http://home.ewha.ac.kr/~deokkeun/kic/sdssteff_v2.dat.g

The Absolute Magnitudes of Red Horizontal Branch Stars in the ugriz System

Based on photometric data of the central parts of eight globular clusters and one open cluster presented by An and his collaborators, we select red horizontal branch (RHB) stars in the (g-r)0-g0 diagram and make a statistical study of the distributions of their colors and absolute magnitudes in the SDSS ugriz system. Meanwhile, absolute magnitudes in the Johnson VRI system are calculated through the translation formulae between gri and VRI in the literature. The calibrations of absolute magnitude as functions of metallicity and age are established by linear regressions of the data. It is found that metallicity coefficients in these calibrations decrease, while age coefficients increase, from the blue $u$ filter to the red $z$ filter. The calibration of Mi= 0.06[Fe/H]+0.040t+0.03 has the smallest scatter of 0.04 mag, and thus i is the best filter in the $ugriz$ system when RHB stars are used for distance indicators. The comparison of the MI calibration from our data with that from red clump stars indicates that the previous suggestion that the $I$ filter is better than the V filter in distance determination may not be true because of its significant dependence on age.Comment: 19 pages, 7 figures, accepted by Ap

Binary pulsars as probes of a Galactic dark matter disk

As a binary pulsar moves through a wind of dark matter particles, the resulting dynamical friction modifies the binary's orbit. We study this effect for the double disk dark matter (DDDM) scenario, where a fraction of the dark matter is dissipative and settles into a thin disk. For binaries within the dark disk, this effect is enhanced due to the higher dark matter density and lower velocity dispersion of the dark disk, and due to its co-rotation with the baryonic disk.We estimate the effect and compare it with observations for two different limits in the Knudsen number ($Kn$). First, in the case where DDDM is effectively collisionless within the characteristic scale of the binary ($Kn\gg1$) and ignoring the possible interaction between the pair of dark matter wakes. Second, in the fully collisional case ($Kn\ll1$), where a fluid description can be adopted and the interaction of the pair of wakes is taken into account. We find that the change in the orbital period is of the same order of magnitude in both limits. A comparison with observations reveals good prospects to probe currently allowed DDDM models with timing data from binary pulsars in the near future. We finally comment on the possibility of extending the analysis to the intermediate (rarefied gas) case with $Kn\sim1$.Comment: 15 pages, 6 figures. Few comments and references added, version accepted for publication in Physics of the Dark Universe (PDU

A Multivariate Surface-Based Analysis of the Putamen in Premature Newborns: Regional Differences within the Ventral Striatum

Many children born preterm exhibit frontal executive dysfunction, behavioral problems including attentional deficit/hyperactivity disorder and attention related learning disabilities. Anomalies in regional specificity of cortico-striato-thalamo-cortical circuits may underlie deficits in these disorders. Nonspecific volumetric deficits of striatal structures have been documented in these subjects, but little is known about surface deformation in these structures. For the first time, here we found regional surface morphological differences in the preterm neonatal ventral striatum. We performed regional group comparisons of the surface anatomy of the striatum (putamen and globus pallidus) between 17 preterm and 19 term-born neonates at term-equivalent age. We reconstructed striatal surfaces from manually segmented brain magnetic resonance images and analyzed them using our in-house conformal mapping program. All surfaces were registered to a template with a new surface fluid registration method. Vertex-based statistical comparisons between the two groups were performed via four methods: univariate and multivariate tensor-based morphometry, the commonly used medial axis distance, and a combination of the last two statistics. We found statistically significant differences in regional morphology between the two groups that are consistent across statistics, but more extensive for multivariate measures. Differences were localized to the ventral aspect of the striatum. In particular, we found abnormalities in the preterm anterior/inferior putamen, which is interconnected with the medial orbital/prefrontal cortex and the midline thalamic nuclei including the medial dorsal nucleus and pulvinar. These findings support the hypothesis that the ventral striatum is vulnerable, within the cortico-stiato-thalamo-cortical neural circuitry, which may underlie the risk for long-term development of frontal executive dysfunction, attention deficit hyperactivity disorder and attention-related learning disabilities in preterm neonates. © 2013 Shi et al