319 research outputs found
Automated online preconcentration system for the determination of trace amounts of lead using Pb-selective resin and inductively coupled plasma-atomic emission spectrometry
An automated sequential-injection online preconcentration system was developed for the determination of lead by inductively coupled plasma - atomic emission spectrometry (ICP-AES). The preconcentration of lead was performed with a minicolumn containing a lead-selective resin, Analig Pb-01, which was installed between a selection and a switching valve. In an acidic condition ( pH 1), lead could be adsorbed on the resin. The concentrated lead was afterward eluted with 25 mu L of 0.06 M nitrilotriacetic acid (NTA) solution ( pH 9) and was subsequently transported into the nebulizer of ICP-AES for quantification. The selectivity of the resin toward lead was examined using a solution containing a mixture of 61 elements. When a sample volume of 5 mL was used, the quantitative collection of lead ( >= 97%) was achieved, along with an enrichment factor of 19, a sampling frequency of 12 samples hr(-1), a detection limit of 70 pg mL(-1), and a lowest quantification limit of 100 pg mL(-1). The linear dynamic range was 0.1 to 5 ng mL(-1), and the relative standard deviation (n = 9) was 0.5% at a 5 ng mL(-1) Pb level. The detection limit of 30 pg mL(-1) and lowest quantification limit of 50 pg mL(-1) could be achieved when 10 mL of sample volume was used. The accuracy of the proposed method was validated by determining lead in the standard reference material of river water (SLRS-4), and its applicability to the determination of lead in environmental river water samples was demonstrated.</p
XMM-Newton Observation of IC 310 in the Outer Region of the Perseus Cluster of Galaxies
We present results from an XMM-Newton observation of the head-tail radio
galaxy IC 310 located in the southwest region of the Perseus cluster. The
spectrum is well-fitted by an absorbed power-law model with a photon index of
with no significant absorption excess. The X-ray image shows a
point-like emission at IC 310 without any signs of a structure correlated with
the radio halo tail. The temperature of the intracluster medium surrounding IC
310 declines as a function of distance from the cluster center, from keV in the northeast corner of the field of view to about 3 keV in the
southwest region. Although we do not find any sharp edges in the surface
brightness profile, a brightness excess over a smooth model by about
20% is seen. The temperature also rises by about 10% in the same region. This
indicates that the IC 310 region is a subcluster probably infalling into the
Perseus cluster, and the gas in front of IC 310 towards the Perseus cluster is
likely to be compressed by the large-scale motion, which supports the view that
the IC 310 system is undergoing a merger.Comment: 7 pages, 8 figures (including color), accepted for publication in
PAS
Chandra observation of the core of the galaxy cluster AWM7
We present results from a Chandra observation of the core region of the
nearby X-ray bright galaxy cluster AWM7. There are blob-like substructures,
which are seen in the energy band 2--10 keV, within 10 kpc (20'') of the cD
galaxy NGC1129, and the brightest sub-peak has a spatial extent more than 4
kpc. We also notice that the central soft X-ray peak is slightly offset from
the optical center by 1 kpc. These structures have no correlated features in
optical, infrared, or radio band. Energy spectrum of the hard sub-peak
indicates a temperature higher than 3 keV with a metallicity less than 0.3
solar, or a power-law spectrum with photon index 1.2. A hardness ratio map and
a narrow Fe-K band image jointly indicate two Fe-rich blobs symmetrically
located around the cD galaxy, with the direction perpendicular to the sub-peak
direction. In larger scales (r<60 kpc), the temperature gradually drops from 4
keV to 2 keV toward the cluster center and the metal abundance rises steeply to
a peak of 1.5 solar at r=7 kpc. These results indicate that a dynamical process
is going on in the central region of AWM7, which probably creates heated gas
blobs and drives metal injection.Comment: 12 pages, 7 figures (including color), accepted for publication in
ApJ. Postscript is also available at
http://www-x.phys.metro-u.ac.jp/~furusho/papers.htm
Locating the Warm-Hot Intergalactic Medium in the Simulated Local Universe
We present an analysis of mock spectral observation of warm-hot intergalactic
medium (WHIM) using a constrained simulation of the local universe. The
simulated map of oxygen emission lines from local WHIM reproduces well the
observed structures traced by galaxies in the real local universe. We further
attempt to perform mock observations of outer parts of simulated Coma cluster
and A3627 adopting the expected performance of DIOS (Diffuse Intergalactic
Oxygen Surveyor), which is proposed as a dedicated soft X-ray mission to search
for cosmic missing baryons. We find that WHIMs surrounding nearby clusters are
detectable with a typical exposure time of a day, and thus constitute realistic
and promising targets for DIOS. We also find that an X-ray emitting clump in
front of Coma cluster, recently reported in the XMM-Newton observation, has a
counterpart in the simulated local universe, and its observed spectrum can be
well reproduced in the simulated local universe if the gas temperature is set
to the observationally estimated value.Comment: 25 pages, 3 tables, 16 figures. Accepted for publication in PASJ.
High resolution PS/PDF files are available at
http://www-utap.phys.s.u-tokyo.ac.jp/~kohji/research/x-ray/index.htm
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