1,285 research outputs found
Poster 85: Subacromial Impingement Syndrome as a Consequence of a Long Thoracic Neuropathy: A Case Report
Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/147003/1/pmr2s43a.pd
Poster 101 Pediatric Mononeuritis Multiplex Secondary to a Nonsystemic Vasculitis: A Case Report
Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/147008/1/pmr2s203a.pd
Poster 350: Neurosarcoidosis Presenting as a Central Cord Syndrome: A Case Report
Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/146922/1/pmr2s256a.pd
Photocatalytic ozonation under visible light for the remediation of water effluents and its integration with an electro-membrane bioreactor
Photocatalysis and photocatalytic ozonation under visible light have been applied for the purification of a complex aqueous matrix such as the grey water of Masdar City (UAE), by using N-doped brookite-rutile catalysts. Preliminary runs on 4-nitrophenol (4-NP) solutions allowed to test the reaction system in the presence of a model pollutant and to afford the relevant kinetic parameters of the process. Subsequently, the remediation of grey water effluent has been evaluated in terms of the reduction of total organic carbon (TOC) and bacterial counts. The concentration of the most abundant inorganic ionic species in the effluent has been also monitored during reaction. Photocatalytic ozonation under visible light allowed to reduce the TOC content of the grey water by ca. 60% in the optimized experimental conditions and to reduce the total bacterial count by ca. 97%. The extent of TOC mineralization reached ca. 80% when the photocatalytic ozonation occurred downstream to a preliminary electro-membrane bioreactor (eMBR). Coupling the two processes enhanced the global efficiency. In fact, the eMBR treatment lowered the turbidity and the organic load of the effluent entering the photocatalytic ozonation treatment, which in turn enhanced the extent of purification and disinfection
Highly stable defective TiO2-x with tuned exposed facets induced by fluorine: Impact of surface and bulk properties on selective UV/visible alcohol photo-oxidation
Titanium dioxide samples were prepared in the presence of different amounts of fluorine via hydrothermal method. It has been found that the presence of fluoride influenced the physico-chemical properties of TiO2 in various ways as polymorphic form stability, surface hydroxylation, generation of hydroxyl radicals under irradiation and formation of Ti3+ centers and oxygen vacancies. The generation rate of [rad]OH radicals was investigated by the photoluminescence technique in the presence of terephthalic acid. X-ray diffractometry indicated that fluorine stabilized the anatase TiO2. X-Ray photoelectron spectroscopy (XPS) revealed the presence of fluorine on the surface and the shift of the valence band edge towards less negative potentials, electron paramagnetic resonance (EPR) confirmed the formation of Ti3+ in the bulk of the photocatalysts, UVâvis spectra showed the extension of the TiO2 photo-response in the visible light region. 2-Propanol degradation and 4-methoxybenzyl alcohol partial oxidation were studied as probe reactions by using the home prepared powders as photocatalysts. Surprisingly, the photocatalytic activity resulted to be mainly affected by [rad]OH radicals formation ability under irradiation, rather than by the presence of {0 0 1} facets, although it cannot be excluded that the latter could influence the ability to form radicals under irradiation
Higher spin fields and the problem of cosmological constant
The cosmological evolution of free massless vector or tensor (but not gauge)
fields minimally coupled to gravity is analyzed. It is shown that there are
some unstable solutions for these fields in De Sitter background. The back
reaction of the energy-momentum tensor of such solutions to the original
cosmological constant exactly cancels the latter and the expansion regime
changes from the exponential to the power law one. In contrast to the
adjustment mechanism realized by a scalar field the gravitational coupling
constant in this model is time-independent and the resulting cosmology may
resemble the realistic one.Comment: 15 pages, Latex twic
On the perturbative chiral ring for marginally deformed N=4 SYM theories
For \cal{N}=1 SU(N) SYM theories obtained as marginal deformations of the
\cal{N}=4 parent theory we study perturbatively some sectors of the chiral ring
in the weak coupling regime and for finite N. By exploiting the relation
between the definition of chiral ring and the effective superpotential we
develop a procedure which allows us to easily determine protected chiral
operators up to n loops once the superpotential has been computed up to (n-1)
order. In particular, for the Lunin-Maldacena beta-deformed theory we determine
the quantum structure of a large class of operators up to three loops. We
extend our procedure to more general Leigh-Strassler deformations whose chiral
ring is not fully understood yet and determine the weight-two and weight-three
sectors up to two loops. We use our results to infer general properties of the
chiral ring.Comment: LaTex, 40 pages, 4 figures, uses JHEP3; v2: minor correction
The Operator Product Expansion of the Lowest Higher Spin Current at Finite N
For the N=2 Kazama-Suzuki(KS) model on CP^3, the lowest higher spin current
with spins (2, 5/2, 5/2,3) is obtained from the generalized GKO coset
construction. By computing the operator product expansion of this current and
itself, the next higher spin current with spins (3, 7/2, 7/2, 4) is also
derived. This is a realization of the N=2 W_{N+1} algebra with N=3 in the
supersymmetric WZW model. By incorporating the self-coupling constant of lowest
higher spin current which is known for the general (N,k), we present the
complete nonlinear operator product expansion of the lowest higher spin current
with spins (2, 5/2, 5/2, 3) in the N=2 KS model on CP^N space. This should
coincide with the asymptotic symmetry of the higher spin AdS_3 supergravity at
the quantum level. The large (N,k) 't Hooft limit and the corresponding
classical nonlinear algebra are also discussed.Comment: 62 pages; the footnotes added, some redundant appendices removed, the
presentations in the whole paper improved and to appear in JHE
Simultaneous quantification of 12 different nucleotides and nucleosides released from renal epithelium and in human urine samples using ion-pair reversed-phase HPLC
Nucleotides and nucleosides are not only involved in cellular metabolism but also act extracellularly via P1 and P2 receptors, to elicit a wide variety of physiological and pathophysiological responses through paracrine and autocrine signalling pathways. For the first time, we have used an ion-pair reversed-phase high-performance liquid chromatography ultraviolet (UV)-coupled method to rapidly and simultaneously quantify 12 different nucleotides and nucleosides (adenosine triphosphate, adenosine diphosphate, adenosine monophosphate, adenosine, uridine triphosphate, uridine diphosphate, uridine monophosphate, uridine, guanosine triphosphate, guanosine diphosphate, guanosine monophosphate, guanosine): (1) released from a mouse renal cell line (M1 cortical collecting duct) and (2) in human biological samples (i.e., urine). To facilitate analysis of urine samples, a solid-phase extraction step was incorporated (overall recovery rate ? 98 %). All samples were analyzed following injection (100 ?l) into a Synergi Polar-RP 80 Ă
(250 Ă 4.6 mm) reversed-phase column with a particle size of 10 ?m, protected with a guard column. A gradient elution profile was run with a mobile phase (phosphate buffer plus ion-pairing agent tetrabutylammonium hydrogen sulfate; pH 6) in 2-30 % acetonitrile (v/v) for 35 min (including equilibration time) at 1 ml min(-1) flow rate. Eluted compounds were detected by UV absorbance at 254 nm and quantified using standard curves for nucleotide and nucleoside mixtures of known concentration. Following validation (specificity, linearity, limits of detection and quantitation, system precision, accuracy, and intermediate precision parameters), this protocol was successfully and reproducibly used to quantify picomolar to nanomolar concentrations of nucleosides and nucleotides in isotonic and hypotonic cell buffers that transiently bathed M1 cells, and urine samples from normal subjects and overactive bladder patients
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