Recrystallization behavior of a hot-rolled TiBw/TA15 composite under electropulsing heat treatment

In the present work, low-current-density electropulsing was applied to study the recrystallization behavior of a hot-rolled TiBw/TA15 composite. To highlight the athermal effect of electropulsing, traditional heat treatment experiments on composite materials were conducted under the same conditions. Test results indicated that recrystallization behavior can be improved compared with that in traditional heat treatment. The potential mechanism by which electropulsing promotes recrystallization was investigated, and the influence of the reinforcement phase on recrystallization was discussed. This work will provide freedom for the composite's process design and microstructure control

Multiscale crystal plasticity finite element simulations of the deformation inhomogeneity of TiBw/TA15 composites with network-structured during hot rolling

Understanding the micromechanical responses during hot forming between TiB whiskers (TiBw) and matrix titanium alloy as well as grains is essential to effectively control the properties of the final products. In this work, a method to study the deformation inhomogeneity of network-structured TiBw/TA15 composites during rolling in high temperature single-phase regions at macro and micro scales was proposed. A crystal plastic finite element model with dislocation slip and grain boundary (GB) sliding as the deformation mechanism was established. Results showed that the discontinuous distribution of TiBw reinforcements along the GB reduced the strain difference between the network boundary region and the matrix region during high temperature deformation. Therefore, the plasticity of the composites was improved. For the high temperature β-phase, the {110} with higher activity was the main deformation mode. The difference in stress distribution between the grains was caused by the different combinations of the “soft” and “hard” states of adjacent grains, which was determined by whether the value of Schmid factors was greater than 0.45. The local stress concentrations tended to spread at the interface of “soft-hard” grains. The TiBw reinforcements increased the GB strength and reduced the deformation difference between the GB and intragranular

Functional Block Copolymers Carrying One Double-Stranded Ladderphane and One Single-Stranded Block in a Facile Metathesis Cyclopolymerization Procedure

In order to improve the poor film-forming ability of polymeric ladderphane, di-block copolymers containing perylene diimide (PDI)-linked double-stranded poly(1,6–heptadiyne) ladderphane and branched alkyl side chains modified single-stranded poly(1,6–heptadiyne) were synthesized by metathesis cyclopolymerization (MCP) using Grubbs third-generation catalyst (Ru–III) in tetrahydrofuran solvent. The first block containing the ladderphane structure leads to higher thermal-stability, wider UV–vis absorption, lower LUMO level and ladderphane-induced rigidity and poor film-forming ability. The second block containing long alkyl chains is crucial for the guarantee of excellent film-forming ability. By comparing the effect of ladderphane structure on the resulted copolymers, single-stranded poly(1,6–heptadiyne) derivatives with PDI pedant were also processed. The structures of copolymers were proved by 1H NMR and gel permeation chromatography, electrochemical, photophysical, and thermal-stability performance were achieved by cyclic voltammetry (CV), UV-visible spectroscopy and thermogravimetric analysis (TGA) measurements. According to the experiment results, both copolymers possessed outstanding film-forming ability, which cannot be realized by small PDI molecules and oligomers. And they can serve as a superior candidate as for n-type materials, especially for their relatively wide range of light absorption (λ = 200~800 nm), and lower LUMO level (−4.3 and −4.0 eV)