All-solid flexible fiber-shaped lithium ion batteries

We propose fabrication of the fiber-shaped lithium ion batteries assembled by twisting a cathode filament together with an anode filament. The cathode filament is fabricated by depositing a LiFePO4 (LFP)-composite layer onto a steel-filled polyester conductive thread (SPCT). As anode filaments, we propose several scenarios including a Li4Ti5O12 (LTO)-composite coated SPCT (dip-and-dry deposition), a tin-coated SPCT (PVD deposition) as well as a bare tin wire. An electrolyte composite layer consisting of LiPF6 and polyethylene oxide (PEO) is then deposited onto both the anode and cathode filament before the battery assembly. By twisting the cathode filament and anode filament together using a customized jig, the batteries are then assembled. The open-circuit voltage is found to be ~ 2.3 V for the battery using the LTO@SPCT anode, and ~3.3 V for the battery using the tin@SPCT anode and the tin wire anode. Charge-discharge tests are carried out at different C rates for each battery sample. Experimental results suggest that the LIBs using the LTO@SPCT anode, the tin@SPCT anode and the bare tin wire anode could achieve a specific capacity of ~64, ~67, and ~96 mAh/g, respectively, when charge-discharged at 0.5-C rate. The battery could retain well its capacity after 80 charge-discharge cycles. During operation of all the batteries reported in this paper, their coulombic efficiency remained above 80%. Among the advantages of the proposed LIB are light weight, ease of fabrication, high specific capacitance, high energy density, and good durability. Finally, employing cheap and commercially-available steel-filled polyester threads as a base material in our batteries, makes them potentially suitable for integration into wearables using various standard textile manufacturing techniques

A hierarchical statistical framework for emergent constraints: application to snow-albedo feedback

Emergent constraints use relationships between future and current climate states to constrain projections of climate response. Here, we introduce a statistical, hierarchical emergent constraint (HEC) framework in order to link future and current climate with observations. Under Gaussian assumptions, the mean and variance of the future state is shown analytically to be a function of the signal-to-noise (SNR) ratio between data-model error and current-climate uncertainty, and the correlation between future and current climate states. We apply the HEC to the climate-change, snow-albedo feedback, which is related to the seasonal cycle in the Northern Hemisphere. We obtain a snow-albedo-feedback prediction interval of $(-1.25, -0.58)$ \%$K^{-1}$. The critical dependence on SNR and correlation shows that neglecting these terms can lead to bias and under-estimated uncertainty in constrained projections. The flexibility of using HEC under general assumptions throughout the Earth System is discussed.Comment: 19 pages, 5 Figure

Interannual variability of the South China Sea throughflow inferred from wind data and an ocean data assimilation product

Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geophysical Research Letters 33 (2006): L14605, doi:10.1029/2006GL026316.The Luzon Strait transport, as an index for the South China Sea throughflow, has attracted much attention. In this study the interannual variability of the Luzon Strait transport is examined, using the Island Rule and results from an ocean general circulation model. Transport variability obtained from these two approaches are consistent with each other. Assessment of contribution from each integral segment involved in the Island Rule indicates that wind stress in the western and central equatorial Pacific is the key factor regulating the interannual variability of the Luzon Strait transport, whereas the effect of local wind stress in the vicinity of the Luzon Strait is secondary. Analysis also shows that when the westerly (easterly) wind anomalies in the tropical Pacific break out, the Luzon Strait transport increases (decreases), consistent with the variations in the North Equatorial Current during El Niño (La Niña) events.This research was supported by NSF of China (Grants Nos. 40136010 and 40406006). YD and TQ were supported by the National Aeronautics and Space Administration through grant NAG5-12756, and TQ also supported by Japan Agency for Marine-Earth Science and Technology through its sponsorship of the International Pacific Research Center