Metal doped semiconductor nanocrystals and methods of making the same

Provide doped semiconductor nanocrystals and methods of making the same

Water-Borne Perovskite Quantum Dot-Loaded, Polystyrene Latex Ink

Highly lipophilic nanocrystals (NCs) of cesium lead halides were successfully embedded in polystyrene (PS) particles by deliberately controlling the swelling of the PS particles in the mixtures of good and bad organic solvents. The resulting composite particles were readily transferred into water via simple stepwise solvent exchange, which yielded water-borne perovskite NC-based inks with outstanding structural and chemical stability in aqueous media. Minimal change in the photoluminescence (PL) of the NCs loaded in the PS particles was visible after 1 month of incubation of the composite particles in water in a broad pH range from 1 to 14, which could otherwise be hardly realized. Loading into the PS particles also made the NCs highly stable against polar organic solvents, such as ethanol, intense light irradiation, and heat. The NC PL intensity slightly changed after the composite particles were heated at 75°C and under irradiation of strong blue light (@365 nm) for 1 h. Furthermore, the PS matrices could effectively inhibit the exchange of halide anions between two differently sized perovskite NCs loaded therein, thereby offering a considerable technical advantage in the application of multiple perovskite NCs for multicolor display in the future

Zinc Chalcogenide Seed-Mediated Synthesis of CdSe Nanocrystals: Nails, Chesses and Tetrahedrons

Systematically shape-controlled synthesis of colloidal semiconductor nanocrystals (NCs) has attracted increasing attention recently for both fundamental and technological interest. The study on the synthesis of colloidal CdSe NCs has given rise to well-developed methods for producing diverse shapes such as rods, wires, cubs and discs. In the current study, we demonstrate the shape evolution of CdSe NCs by using a seed-mediated approach by control reaction temperature and injection methods. The synthesis utilizes small (2.0–3.0 nm) zinc chalcogenide NCs with zincblende structure as seeds for subsequent growth, which results in distinct shapes of nail-shaped, tetrahedron-shaped, chess piece-shaped, and Y-shaped CdSe NCs with high yield and good uniformity. The morphologies and crystal structures of the prepared CdSe NCs were well characterized by transmission electron microscopy (TEM), high resolution TEM, and X-ray diffraction measurements. This wide variation of shapes provides important information on the growth of CdSe NCs and promotes the shape-controlled synthesis of other NCs by seed-mediated synthetic method

Treatment of AC dislocation by reconstructing CC and AC ligaments with allogenic tendons compared with hook plates

Abstract Background The purpose of this study was to compare outcomes between allograft reconstruction and hook plate fixation for acute dislocation of the acromioclavicular joint with a minimum 2-year follow-up. Methods A retrospective comparative study of patients treated for acute acromioclavicular joint dislocation from February 2010 to December 2014 in our hospital, consisting of 16 patients who were followed-up, was performed. Eight patients were treated for acute AC dislocation and underwent surgical reconstruction as follows: the coracoclavicular and acromioclavicular ligaments were reconstructed with the allogenic tendon. The other eight patients were treated with hook plates to maintain the AC joint reset. At the latest follow-up, radiographic analysis and the Constant and University of California-Los Angeles (UCLA) scores were used to evaluate shoulder function. The satisfaction of the patients in terms of the efficacy and visual analog scale (VAS) data were also recorded. Results After an average follow-up of 30.3 months (range 24–46 months), no patient had dislocated their joint again at the final follow-up based on X-ray examination. The Constant score was 94.4 for the allogenic tendon group and 93.8 for the hook plate group (P = 0.57). According to the UCLA scale (P = 0.23) or VAS (P = 0.16), we found no significant difference between the two groups. All patients reported that they were very satisfied or satisfied with the outcome of surgery, and no significant difference (P = 0.08) was found between the two groups. Conclusions The use of allogenic tendon for reconstruction of the coracoclavicular and acromioclavicular ligaments shows excellent outcomes in terms of the recovery of clinical function or radiographic outcomes for acute AC dislocation. Compared with the hook plate, the hardware did not need to be removed

Assemblies of semiconductor quantum dots and light-harvesting-complex ii

A novel hybrid system composed of fluorescent core/shell semiconductor quantum dots and the light harvesting complex II (LHCIIb), a membrane protein of higher plants, has been assembled. Experiments with different mutants show that hybrid formation can be mediated by a C-terminal His(6) tag attached to the protein as well as by positive charges of the first N-terminal amino acids of LHCIIb. Quenching of the quantum dot fluorescence upon binding of LHCIIb was partially attributed to energy transfer from the quantum dots to LHCIIb. (c) 2009 Elsevier B.V. All rights reserved

Dot–Wire–Platelet–Cube: Step Growth and Structural Transformations in CsPbBr₃ Perovskite Nanocrystals

While the classical mechanism for the growth of colloidal chalcogenide nanocrystals is largely understood, fundamental insights for the growth of perovskite nanocrystals still remain elusive. Using nanoclusters of ∼0.6 nm diameter as monomers and growing to more than 25 nm in a single reaction, herein, the step growth process of perovskite CsPbBr₃ nanocrystals is reported. This is performed with a step-rise of the reaction temperature with correlating annealing time. The growth is so precise that ∼0.6 nm (nearly one unit cell) increments were successively monitored in parallel with the conversion of clusters to nanowires and then to thickness tunable platelets and finally to size-tunable cube-shaped nanostructures. The entire reaction was monitored optically and microscopically, and their step growths were correlated. From these observations, the possible growth mechanism for perovskite nanocrystals along with their shape transformations was proposed

Correlation of CdS Nanocrystal Formation with Elemental Sulfur Activation and Its Implication in Synthetic Development

Formation of CdS nanocrystals in the classic approach (with octadecene (ODE) as the solvent and elemental sulfur and cadmium carboxylate as the precursors) was found to be kinetically dependent on reduction of elemental sulfur by ODE, which possessed a critical temperature (∼180 °C). After elemental sulfur was activated by ODE, the formation reaction of CdS followed closely. 2-tetradecylthiophene from the activation of S by ODE and fatty acids from the formation reaction of CdS were found to be the only soluble side products. The overall reaction stoichiometry further suggested that oxidation of each ODE molecule generated two molecules of H₂S, which in turn reacted with two molecules of cadmium carboxylate molecules to yield two CdS molecular units and four molecules of fatty acids. In comparison to alkanes, octadecene was found to be substantially more active as a reductant for elemental sulfur. To the best of our knowledge, this is the first example of quantitative correlation between chemical reactions and formation of high-quality nanocrystals under synthetic conditions. To demonstrate the importance of such discovery, we designed two independent and simplified synthetic approaches for synthesis of CdS nanocrystals. One approach with its reaction temperature at the critical temperature of S activation (180 °C) used the same reactant composition as the classic approach but without any hot injection. The other approach performed at an ordinary laboratory temperature (≤100 °C) and in a common organic solvent (toluene) was achieved by addition of fatty amine as activation reagent of elemental sulfur

Turn-on Fluorescent InP Nanoprobe for Detection of Cadmium Ions with High Selectivity and Sensitivity

We reported a “turn-on” fluorescent InP nanoprobe for detection of cadmium ions in hydrophobic and hydrophilic media. The method based on the turn-on fluorescence detection of cadmium ions has shown its high selectivity and sensitivity, which are independent of the pH of the tested samples. Also, this approach exhibits an immediate response to cadmium ions, and visualized detection of cadmium ions has further been demonstrated under a UV lamp