Development of bond coats for extending lifetime of TBCs

This talk will be focused to study the MCrAlY bond coat for thermal barrier coating applications. First of all, residual stresses in the bond coat have been measured with use of X-ray diffraction, in which effect of temperature and thermal cycling will be studied. Secondly, rumpling phenomena of such bond coat after thermal treatments have been examined to identify factors affecting the stress evolution and rumpling of the bond coat. Thirdly, effect of the bond coat microstructure on early oxidation of the bond coat has been investigated to understand how the grain size in the bond coat affected both oxidation products and oxidation kinetics. Finally, the comparison of MCrAlY bond coat vs the NiPtAl bond coat will be made in terms of residual stress evolution, residual stresses, and oxidation kinetics to illustrate the effect of these factors on failure and lifetime of TBCs

Warped Brane worlds in Critical Gravity

We investigate the brane models in arbitrary dimensional critical gravity presented in [Phys. Rev. Lett. 106, 181302 (2011)]. For the model of the thin branes with codimension one, the Gibbons-Hawking surface term and the junction conditions are derived, with which the analytical solutions for the flat, AdS, and dS branes are obtained at the critical point of the critical gravity. It is found that all these branes are embedded in an AdS$_{n}$ spacetime, but, in general, the effective cosmological constant $\Lambda$ of the AdS$_{n}$ spacetime is not equal to the naked one $\Lambda_0$ in the critical gravity, which can be positive, zero, and negative. Another interesting result is that the brane tension can also be positive, zero, or negative, depending on the symmetry of the thin brane and the values of the parameters of the theory, which is very different from the case in general relativity. It is shown that the mass hierarchy problem can be solved in the braneworld model in the higher-derivative critical gravity. We also study the thick brane model and find analytical and numerical solutions of the flat, AdS, and dS branes. It is find that some branes will have inner structure when some parameters of the theory are larger than their critical values, which may result in resonant KK modes for some bulk matter fields. The flat branes with positive energy density and AdS branes with negative energy density are embedded in an $n$-dimensional AdS spacetime, while the dS branes with positive energy density are embedded in an $n$-dimensional Minkowski one.Comment: 14 pages, 7 figures, updated version, accepted by EPJ

Micromechanical Testing of Thermal Barrier Coatings

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Gene-to-metabolite network for biosynthesis of lignans in MeJA-elicited Isatis indigotica hairy root cultures.

Root and leaf tissue of Isatis indigotica shows notable anti-viral efficacy, and are widely used as "Banlangen" and "Daqingye" in traditional Chinese medicine. The plants' pharmacological activity is attributed to phenylpropanoids, especially a group of lignan metabolites. However, the biosynthesis of lignans in I. indigotica remains opaque. This study describes the discovery and analysis of biosynthetic genes and AP2/ERF-type transcription factors involved in lignan biosynthesis in I. indigotica. MeJA treatment revealed differential expression of three genes involved in phenylpropanoid backbone biosynthesis (IiPAL, IiC4H, Ii4CL), five genes involved in lignan biosynthesis (IiCAD, IiC3H, IiCCR, IiDIR, and IiPLR), and 112 putative AP2/ERF transcription factors. In addition, four intermediates of lariciresinol biosynthesis were found to be induced. Based on these results, a canonical correlation analysis using Pearson's correlation coefficient was performed to construct gene-to-metabolite networks and identify putative key genes and rate-limiting reactions in lignan biosynthesis. Over-expression of IiC3H, identified as a key pathway gene, was used for metabolic engineering of I. indigotica hairy roots, and resulted in an increase in lariciresinol production. These findings illustrate the utility of canonical correlation analysis for the discovery and metabolic engineering of key metabolic genes in plants