Momentum Distribution of Near-Zero-Energy Photoelectrons in the Strong-Field Tunneling Ionization in the Long Wavelength Limit

We investigate the ionization dynamics of Argon atoms irradiated by an ultrashort intense laser of a wavelength up to 3100 nm, addressing the momentum distribution of the photoelectrons with near-zero-energy. We find a surprising accumulation in the momentum distribution corresponding to meV energy and a \textquotedblleft V"-like structure at the slightly larger transverse momenta. Semiclassical simulations indicate the crucial role of the Coulomb attraction between the escaping electron and the remaining ion at extremely large distance. Tracing back classical trajectories, we find the tunneling electrons born in a certain window of the field phase and transverse velocity are responsible for the striking accumulation. Our theoretical results are consistent with recent meV-resolved high-precision measurements.Comment: 5 pages, 4 figure

Oxidative stress-mediated reperfusion injury: mechanism and therapies

published_or_final_versio

Enhanced Xylitol Production from Statistically Optimized Fermentation of Cotton Stalk Hydrolysate by Immobilized Candida tropicalis

Dilute-acid hydrolysate of cotton stalk was prepared for the xylitol production, immobilized Candida tropicalis was used as the fermentation inoculum. The fermentative conditions were selected by single factor experiments, three factors were chosen as main conditions from five parameters to design the response surface test using a central composite design. Regression equation and analysis of variance were proposed with regard to the effects of reducing sugar concentration, initial pH value and inoculation ratio of yeast. The results showed that the correlation between actual and predicted values were significantly predicted by the model, the optimized fermentative conditions were determined as follows: reducing sugar concentration of hydrolysate was 94 g L–1, inoculation ratio of the immobilized Candida tropicalis was 5.7 % (w/v), initial pH value was 5.1. Under the optimal conditions, the experimental concentration of xylitol was 13.02 ± 1.10 g L–1, which was close to the theoretical predicted value, and shows that the model is feasible

An effective scheme for QoS estimation via alternating direction method-based matrix factorization

Accurately estimating unknown quality-of-service (QoS) data based on historical records of Web-service invocations is vital for automatic service selection. This work presents an effective scheme for addressing this issue via alternating direction method-based matrix factorization. Its main idea consists of a) adopting the principle of the alternating direction method to decompose the task of building a matrix factorization-based QoS-estimator into small subtasks, where each one trains a subset of desired parameters based on the latest status of the whole parameter set; b) building an ensemble of diversified single models with sophisticated diversifying and aggregating mechanism; and c) parallelizing the construction process of the ensemble to drastically reduce the time cost. Experimental results on two industrial QoS datasets demonstrate that with the proposed scheme, more accurate QoS estimates can be achieved than its peers with comparable computing time with the help of its practical parallelization.This work was supported in part by the FDCT (Fundo para o Desenvolvimento das Ciências e da Tecnologia) under Grant119/2014/A3, in part by the National Natu-ral Science Foundation of China under Grant 61370150, and Grant 61433014; in part by the Young Scientist Foun-dation of Chongqing under Grant cstc2014kjrc-qnrc40005; in part by the Chongqing Research Program of Basic Re-search and Frontier Technology under Grant cstc2015jcyjB0244; in part by the Postdoctoral Science Funded Project of Chongqing under Grant Xm2014043; in part by the Fundamental Research Funds for the Central Universities under Grant 106112015CDJXY180005; in part by the Specialized Research Fund for the Doctoral Pro-gram of Higher Education under Grant 20120191120030

Polyoxometallates@zeolitic-imidazolate-framework derived bimetallic tungsten-cobalt sulfide/porous carbon nanocomposites as efficient bifunctional electrocatalysts for hydrogen and oxygen evolution

This is the author accepted manuscript. The final version is available from Elsevier via the DOI in this record.Hydrogen is one of the most promising sustainable energy among numerous new energy resources. Electrocatalytic water splitting for H2 generation is a clean and sustainable approach due to the use of widely existed water as resource. The searching for efficient and low-cost non-precious metal based electrocatalysts for water splitting, including both cathodic hydrogen evolution reaction (HER) and anodic oxygen evolution reaction (OER), still remains a great challenge. In this work we report a simple method that utilizes the one-pot in-situ synthesized POMs@ZIFs (POMs = Polyoxometallates, ZIFs = Zeolitic imidazolate frameworks) as precursor for the production of WS2/Co1-xS/N, S co-doped porous carbon nanocomposite as efficient electrocatalysts. These precursors POMs@ZIFs can effectively prevent the agglomeration of metal compound particles during heat treatment and leads to homogeneous dispersion of metal active sites within carbon matrix. The resulting bimetallic Co–W sulfide/heteroatom doped porous carbon composites show significant improvement in electrocatalytic activity towards both OER (Tafel slop of 53 mV dec−1 with overpotential of 0.365 V @10 mA cm−2 current density in 1 M KOH media) and HER (Tafel slop of 64 mV dec−1 with overpotential of 0.250 V @10 mA cm−2 current density in 0.5 M H2SO4 solution). This work opens up a new way to obtain low cost bifunctional electrocatalysts towards both OER and HER in water splitting.European CommissionEngineering and Physical Sciences Research Council (EPSRC

Effectiveness of a community-based multifaceted fall-prevention intervention in active and independent older Chinese adults

This paper is freely available online under the BMJ Journals unlocked scheme, se

Improved Hydrogen Release from Ammonia Borane Confined in Microporous Carbon with Narrow Pore Size Distribution

This is the author accepted manuscript. The final version is available from Royal Society of Chemistry via the DOI in this record.Ammonia borane is a promising hydrogen storage candidate due to its high hydrogen capacity and good stability at room temperature, but there are still some barriers to be overcome before it can be used for practical applications. We present the hydrogen release from ammonia borane confined in templated microporous carbon with extremely narrow pore size distribution. Compared with neat ammonia borane, hydrogen release temperature of ammonia borane confined in microporous carbon with pore size of 1.05 nm is significantly reduced, starting at 50 C and with peak dehydrogenation temperature centred at 86 C. The dehydrogenation kinetics of ammonia borane confined in templated microporous carbon is significantly improved and by-products including ammonia and diborane are also completely prohibited without any catalysts involved. The remarkable fast hydrogen release rate and high hydrogen storage capacity from ammonia borane confined in microporous carbon is due to the dramatic decrease in the activation energy of ammonia borane. This is so far the best performance among porous carbon materials used as the confinement scaffolds for ammonia borane in hydrogen storage, making AB confined in microporous carbon a very promising candidate for hydrogen storage.The financial support by the Royal Society and University of Exeter is greatly acknowledged

KDM2B/FBXL10 targets c-Fos for ubiquitylation and degradation in response to mitogenic stimulation.

KDM2B (also known as FBXL10) controls stem cell self-renewal, somatic cell reprogramming and senescence, and tumorigenesis. KDM2B contains multiple functional domains, including a JmjC domain that catalyzes H3K36 demethylation and a CxxC zinc-finger that recognizes CpG islands and recruits the polycomb repressive complex 1. Here, we report that KDM2B, via its F-box domain, functions as a subunit of the CUL1-RING ubiquitin ligase (CRL1/SCF(KDM2B)) complex. KDM2B targets c-Fos for polyubiquitylation and regulates c-Fos protein levels. Unlike the phosphorylation of other SCF (SKP1-CUL1-F-box)/CRL1 substrates that promotes substrates binding to F-box, epidermal growth factor (EGF)-induced c-Fos S374 phosphorylation dissociates c-Fos from KDM2B and stabilizes c-Fos protein. Non-phosphorylatable and phosphomimetic mutations at S374 result in c-Fos protein which cannot be induced by EGF or accumulates constitutively and lead to decreased or increased cell proliferation, respectively. Multiple tumor-derived KDM2B mutations impaired the function of KDM2B to target c-Fos degradation and to suppress cell proliferation. These results reveal a novel function of KDM2B in the negative regulation of cell proliferation by assembling an E3 ligase to targeting c-Fos protein degradation that is antagonized by mitogenic stimulations