Do climate change regulatory pressures increase corporate environmental sustainability performance? The moderating roles of foreign market exposure and industry carbon intensity

This study focuses on climate change regulatory pressures at the national/regional level, which can be considered emergent institutions – newly established and subject to change – in contrast to established institutions. We explore their impact on the environmental sustainability performance of multinational enterprises, advancing beyond the extant literature's focus on their binary compliance reactions. Utilizing a sample of Standard & Poor's 1200 firms, our findings indicate that variations in climate change regulatory pressures at the national/regional level can account for differences in environmental sustainability performance at the corporate level. Moreover, this relationship is moderated by two critical firm characteristics: foreign market exposure and industry carbon intensity. Foreign market exposure, particularly in the context of developing countries, can diminish the positive effects of a home country's climate change regulatory pressures, while industry carbon intensity can amplify these effects

Evolution of entanglement for quantum mixed states

A simple relation is introduced for concurrence to describe how much the entanglement of bipartite system is at least left if either (or both) subsystem undergoes an arbitrary physical process. This provides a lower bound for concurrence of mixed states (pure states are included) in contrast to the upper bound given by Konrad et al [Nature Physics \textbf{4}, 99 (2008)]. Our results are also suitable for a general high dimensional bipartite quantum systems.Comment: 6 pages and 1 figur

Internal friction and Jahn-Teller effect in the charge-ordered La1-xCaxMnO3 (0.5<x<0.87)

The Jahn-Teller effect in the charge-ordered (CO) state for La1-xCaxMnO3 (0.5<x<0.87) was studied by measuring the low-temperature powder x-ray diffraction, internal friction, and shear modulus. We find that the electron-lattice interaction with the static Jahn-Teller distortion is the strongest near x=0.75 in the CO state. It was particularly observed that a crossover of the Jahn-Teller vibration mode from Q2 to Q3 near x=0.75 induces crossovers of the crystal structure from tetragonally compressed to tetragonally elongated orthorhombic, and of the magnetic structure from CE-type to C-type near x=0.75. The experimental results give strong evidence that the Jahn-Teller effect not only plays a key role in stabilizing the CO state, but also determines the magnetic and crystal structures in the CO state for La1-xCaxMnO3.Comment: 13 pages, 3 figures, PD

Infrared Multiple Photon Dissociation Action Spectroscopy and Theoretical Studies of Diethyl Phosphate Complexes: Effects of Protonation and Sodium Cationization on Structure

The gas-phase structures of deprotonated, protonated, and sodium-cationized complexes of diethyl phosphate (DEP) including [DEP − H]−, [DEP + H]+, [DEP + Na]+, and [DEP − H + 2Na]+ are examined via infrared multiple photon dissociation (IRMPD) action spectroscopy using tunable IR radiation generated by a free electron laser, a Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS) with an electrospray ionization (ESI) source, and theoretical electronic structure calculations. Measured IRMPD spectra are compared to linear IR spectra calculated at the B3LYP/6-31G(d,p) level of theory to identify the structures accessed in the experimental studies. For comparison, theoretical studies of neutral complexes are also performed. These experiments and calculations suggest that specific geometric changes occur upon the binding of protons and/or sodium cations, including changes correlating to nucleic acid backbone geometry, specifically P–O bond lengths and ∠OPO bond angles. Information from these observations may be used to gain insight into the structures of more complex systems, such as nucleotides and solvated nucleic acids

A twist in chiral interaction between biological helices

Using an exact solution for the pair interaction potential, we show that long, rigid, chiral molecules with helical surface charge patterns have a preferential interaxial angle ~((RH)^1/2)/L, where L is the length of the molecules, R is the closest distance between their axes, and H is the helical pitch. Estimates based on this formula suggest a solution for the puzzle of small interaxial angles in a-helix bundles and in cholesteric phases of DNA.Comment: 7 pages, 2 figures, PDF file onl

Intermittent QPO properties of MAXI J1820+070 revealed by Insight-HXMT

We investigate the dynamical properties of low frequency quasi-periodic oscillations (QPOs) observed from the black hole X-ray binary MAXI J1820+070 during the early part of its 2018 outburst, when the system was in a bright hard state. To this aim, we use a series of observations from the Hard X-ray Modulation Telescope Insight-HXMT, and apply a wavelet decomposition (weighted wavelet Z-transforms) to the X-ray light-curve. We find that the QPO phenomenon is intermittent within each individual observation, with some sub-intervals where the oscillation is strongly detected (high root-mean-square amplitude) and others where it is weak or absent. The average life time of individual QPO segments is ~ 5 oscillation cycles, with a 3 sigma tail up to ~ 20 cycles. There is no substantial difference between the energy spectra during intervals with strong and weak/absent QPOs. We discuss two possible reasons for the intermittent QPO strength, within the precessing jet model previously proposed for MAXI J1820+070. In the rigid precession model, intermittent QPOs are predicted to occur with a coherence Q ~ a few when the disk alignment time-scale is only a few times the precession time-scale. Alternatively, we suggest that changes in oscillation amplitude can be caused by changes in the jet speed. We discuss a possible reason for the intermittent QPO strength, within the precessing jet model previously proposed for MAXI J1820+070: we suggest that changes in oscillation amplitude are caused by changes in the jet speed. We argue that a misaligned, precessing jet scenario is also consistent with other recent observational findings that suggest an oscillation of the Compton reflection component in phase with the QPOs.Comment: 8 pages, 4 figure

Phase Behavior of Columnar DNA Assemblies

The pair interaction between two stiff parallel linear DNA molecules depends not only on the distance between their axes but on their azimuthal orientation. The positional and orientational order in columnar B-DNA assemblies in solution is investigated, based on the DNA-DNA electrostatic pair potential that takes into account DNA helical symmetry and the amount and distribution of adsorbed counterions. A phase diagram obtained by lattice sum calculations predicts a variety of positionally and azimuthally ordered phases and bundling transitions strongly depending on the counterion adsorption patterns.Comment: 4 pages, 3 figures, submitted to PR

Effective interaction between helical bio-molecules

The effective interaction between two parallel strands of helical bio-molecules, such as deoxyribose nucleic acids (DNA), is calculated using computer simulations of the "primitive" model of electrolytes. In particular we study a simple model for B-DNA incorporating explicitly its charge pattern as a double-helix structure. The effective force and the effective torque exerted onto the molecules depend on the central distance and on the relative orientation. The contributions of nonlinear screening by monovalent counterions to these forces and torques are analyzed and calculated for different salt concentrations. As a result, we find that the sign of the force depends sensitively on the relative orientation. For intermolecular distances smaller than $6\AA$ it can be both attractive and repulsive. Furthermore we report a nonmonotonic behaviour of the effective force for increasing salt concentration. Both features cannot be described within linear screening theories. For large distances, on the other hand, the results agree with linear screening theories provided the charge of the bio-molecules is suitably renormalized.Comment: 18 pages, 18 figures included in text, 100 bibliog

Inducible and reversible inhibition of mirna-mediated gene repression in vivo

Although virtually all gene networks are predicted to be controlled by miRNAs, the contribution of this important layer of gene regulation to tissue homeostasis in adult animals remains unclear. Gain and loss of function experiments have provided key insights into the specific function of individual miRNAs, but effective genetic tools to study the functional consequences of global inhibition of miRNA activity in vivo are lacking. Here we report the generation and characterization of a genetically engineered mouse strain in which miRNA-mediated gene repression can be reversibly inhibited without affecting miRNA biogenesis or abundance. We demonstrate the usefulness of this strategy by investigating the consequences of acute inhibition of miRNA function in adult animals. We find that different tissues and organs respond differently to global loss of miRNA function. While miRNA-mediated gene repression is essential for the homeostasis of the heart and the skeletal muscle, it is largely dispensable in the majority of other organs. Even in tissues where it is not required for homeostasis, such as the intestine and hematopoietic system, miRNA activity can become essential during regeneration following acute injury. These data support a model where many metazoan tissues primarily rely on miRNA function to respond to potentially pathogenic events

Adsorption of mono- and multivalent cat- and anions on DNA molecules

Adsorption of monovalent and multivalent cat- and anions on a deoxyribose nucleic acid (DNA) molecule from a salt solution is investigated by computer simulation. The ions are modelled as charged hard spheres, the DNA molecule as a point charge pattern following the double-helical phosphate strands. The geometrical shape of the DNA molecules is modelled on different levels ranging from a simple cylindrical shape to structured models which include the major and minor grooves between the phosphate strands. The densities of the ions adsorbed on the phosphate strands, in the major and in the minor grooves are calculated. First, we find that the adsorption pattern on the DNA surface depends strongly on its geometrical shape: counterions adsorb preferentially along the phosphate strands for a cylindrical model shape, but in the minor groove for a geometrically structured model. Second, we find that an addition of monovalent salt ions results in an increase of the charge density in the minor groove while the total charge density of ions adsorbed in the major groove stays unchanged. The adsorbed ion densities are highly structured along the minor groove while they are almost smeared along the major groove. Furthermore, for a fixed amount of added salt, the major groove cationic charge is independent on the counterion valency. For increasing salt concentration the major groove is neutralized while the total charge adsorbed in the minor groove is constant. DNA overcharging is detected for multivalent salt. Simulations for a larger ion radii, which mimic the effect of the ion hydration, indicate an increased adsorbtion of cations in the major groove.Comment: 34 pages with 14 figure