Superconducting gap variations induced by structural supermodulation in BSCCO

We discuss the possibility that the strain field introduced by the structural supermodulation in Bi-2212 and certain other cuprate materials may modulate the superconducting pairing interaction. We calculate the amplitude of this effect, visible in scanning tunneling spectroscopy experiments, and thereby relate a change in the local superconducting gap with the change in the local dopant displacements induced by the supermodulation. In principle, since this modulation is periodic, sufficiently accurate x-ray measurements or ab initio calculations should enable one to determine which atomic displacements enhance pairing and therefore T_c.Comment: 4 pages, 3 figure

X-ray Dichroism and the Pseudogap Phase of Cuprates

A recent polarized x-ray absorption experiment on the high temperature cuprate superconductor Bi2Sr2CaCu2O8 indicates the presence of broken parity symmetry below the temperature, T*, where a pseudogap appears in photoemission. We critically analyze the x-ray data, and conclude that a parity-breaking signal of the kind suggested is unlikely based on the crystal structures reported in the literature. Possible other origins of the observed dichroism signal are discussed. We propose x-ray scattering experiments that can be done in order to determine whether such alternative interpretations are valid or not.Comment: final version to be published in Phys Rev B: some calculational details added, clarification of XNLD contamination and biaxiality, more discussion on possible space groups and previous optics result

Structure of BSCCO supermodulation from ab initio calculations

We present results of density functional theory (DFT) calculation of the structural supermodulation in BSCCO-2212 structure, and show that the supermodulation is indeed a spontaneous symmetry breaking of the nominal crystal symmetry, rather than a phenomenon driven by interstitial O dopants. The structure obtained is in excellent quantitative agreement with recent x-ray studies, and reproduces several qualitative aspects of scanning tunnelling microscopy (STM) experiments as well. The primary structural modulation affecting the CuO_2 plane is found to be a buckling wave of tilted CuO_5 half-octahedra, with maximum tilt angle near the phase of the supermodulation where recent STM experiments have discovered an enhancement of the superconducting gap. We argue that the tilting of the half-octahedra and concommitant planar buckling are directly modulating the superconducting pair interaction.Comment: 4 pages, 3 figure

Performance improvement of MXene-based perovskite solar cells upon property transition from metallic to semiconductive by oxidation of Ti₃C₂Tₓ in air

The unique properties of MXenes that arise from terminating functional groups and oxidation of MXenes make them attractive for application in photovoltaic devices like perovskite solar cells (PSCs). Here, oxidation of Ti3C2Tx hydrocolloid was carried out to tune its properties desirable for an electron transport layer (ETL) in low-temperature processed PSCs. The calculations of the energy levels were carried out using the Vienna ab initio simulation package (VASP) code based on density functional theory (DFT). Oxidation of Ti_{3}C_{2}T_{x} can generate Ti–O bonds and effectively reduce the macroscopic defects of the film fabricated by spin-coating, while a transition from metallic material to semiconductor occurred after heavy oxidation. A better matching of energy levels between perovskite and ETL layer in the case of a hybrid of oxidized and pristine Ti_{3}C_{2}T_{x} renders a champion power conversion efficiency (PCE) of 18.29%. The improvement in PCE can be attributed to the increased electron mobility in the ETL, which promotes electron transport and reduces the electron–hole recombination. Hence, by presenting a simple method for high performance in PSCs by MXene-derived materials, this work demonstrates the great potential of these materials for applications in low-temperature processed PSCs and other photovoltaic technologies

"Narrow" Graphene Nanoribbons Made Easier by Partial Hydrogenation

It is a challenge to synthesize graphene nanoribbons (GNRs) with narrow widths and smooth edges in large scale. Our first principles study on the hydrogenation of GNRs shows that the hydrogenation starts from the edges of GNRs and proceeds gradually toward the middle of the GNRs so as to maximize the number of carbon-carbon $\pi$-$\pi$ bonds. Furthermore, the partially hydrogenated wide GNRs have similar electronic and magnetic properties as those of narrow GNRs. Therefore, it is not necessary to directly produce narrow GNRs for realistic applications because partial hydrogenation could make wide GNRs "narrower"

A method of real-time long-baseline time transfer based on the PPP-RTK

Long-baseline time transfer can nowadays reach rather high frequency stability based on post-processed batch least-squares adjustment using the Precise Point Positioning (PPP) or Integer-PPP (IPPP) methods. For real-time PPP users, time transfer results are degraded due to the filter-based processing mode, and the degraded accuracy of the real-time satellite orbits and clocks compared to the final ones. The Real-Time Kinematic (RTK) time transfer can significantly reduce the satellite-related errors, but has limits on the baseline length similar to the RTK positioning. Also, the delivery of raw observations instead of State-Space Representation (SSR) products could result in pressure on data transfer and difficulties related to latency and prediction. In this study, the PPP-RTK technique, which combines the advantages of the PPP and the RTK methods, is tested for real-time long-baseline time transfer. As an alternative approach to the above two methods, it allows for the time transfer of long baselines, while not relying on external high-sampling and high-precision satellite clocks. By delivering the satellite clocks and satellite phase biases produced within the PPP-RTK regional network, time differences can be estimated between users and the reference network station, with which stable time transfer between users separated by long baselines can be realized. Using dual-frequency GPS and Galileo data, the PPP-RTK time transfer is tested using approximately a thousand-kilometer-scale network in Europe. The time transfer results between two hydrogen masers, i.e., those on the 884 km baseline BRUX-ONSA and the 920 km baseline WTZR-ONSA, are computed. At an averaging time of 105 s, Modified Allan Deviation (MDEV) at the level of sub-10-15 to 10-15 can be reached when processing the user coordinates in the station fixed, static, or kinematic modes. The median clock residuals can converge to 1 ns and 0.3 ns within 2 min and 15 min, respectively, in the kinematic mode, while in the static and fixed modes the convergence times are shorter. With the augmentation of 150 Low Earth Orbit (LEO) satellites having simulated observations, the clock residuals can converge to 1 ns and 0.3 ns within 30 s and 3.5 min, respectively, for all the three estimation modes

From concept to action: a united, holistic and One Health approach to respond to the climate change crisis

It is unequivocal that human influence has warmed the planet, which is seriously affecting the planetary health including human health. Adapting climate change should not only be a slogan, but requires a united, holistic action and a paradigm shift from crisis response to an ambitious and integrated approach immediately. Recognizing the urgent needs to tackle the risk connection between climate change and One Health, the four key messages and recommendations that with the intent to guide further research and to promote international cooperation to achieve a more climate-resilient world are provided

JUNO Conceptual Design Report

The Jiangmen Underground Neutrino Observatory (JUNO) is proposed to determine the neutrino mass hierarchy using an underground liquid scintillator detector. It is located 53 km away from both Yangjiang and Taishan Nuclear Power Plants in Guangdong, China. The experimental hall, spanning more than 50 meters, is under a granite mountain of over 700 m overburden. Within six years of running, the detection of reactor antineutrinos can resolve the neutrino mass hierarchy at a confidence level of 3-4$\sigma$, and determine neutrino oscillation parameters $\sin^2\theta_{12}$, $\Delta m^2_{21}$, and $|\Delta m^2_{ee}|$ to an accuracy of better than 1%. The JUNO detector can be also used to study terrestrial and extra-terrestrial neutrinos and new physics beyond the Standard Model. The central detector contains 20,000 tons liquid scintillator with an acrylic sphere of 35 m in diameter. $\sim$17,000 508-mm diameter PMTs with high quantum efficiency provide $\sim$75% optical coverage. The current choice of the liquid scintillator is: linear alkyl benzene (LAB) as the solvent, plus PPO as the scintillation fluor and a wavelength-shifter (Bis-MSB). The number of detected photoelectrons per MeV is larger than 1,100 and the energy resolution is expected to be 3% at 1 MeV. The calibration system is designed to deploy multiple sources to cover the entire energy range of reactor antineutrinos, and to achieve a full-volume position coverage inside the detector. The veto system is used for muon detection, muon induced background study and reduction. It consists of a Water Cherenkov detector and a Top Tracker system. The readout system, the detector control system and the offline system insure efficient and stable data acquisition and processing.Comment: 328 pages, 211 figure

Role of Esrrg in the Fibrate-Mediated Regulation of Lipid Metabolism Genes in Human ApoA-I Transgenic Mice

We have used a new ApoA-I transgenic mouse model to identify by global gene expression profiling, candidate genes that affect lipid and lipoprotein metabolism in response to fenofibrate treatment. Multilevel bioinformatical analysis and stringent selection criteria (2-fold change, 0% false discovery rate) identified 267 significantly changed genes involved in several molecular pathways. The fenofibrate-treated group did not have significantly altered levels of hepatic human APOA-I mRNA and plasma ApoA-I compared with the control group. However, the treatment increased cholesterol levels to 1.95-fold mainly due to the increase in high-density lipoprotein (HDL) cholesterol. The observed changes in HDL are associated with the upregulation of genes involved in phospholipid biosynthesis and lipid hydrolysis, as well as phospholipid transfer protein. Significant upregulation was observed in genes involved in fatty acid transport and β-oxidation, but not in those of fatty acid and cholesterol biosynthesis, Krebs cycle and gluconeogenesis. Fenofibrate changed significantly the expression of seven transcription factors. The estrogen receptor-related gamma gene was upregulated 2.36-fold and had a significant positive correlation with genes of lipid and lipoprotein metabolism and mitochondrial functions, indicating an important role of this orphan receptor in mediating the fenofibrate-induced activation of a specific subset of its target genes.National Institutes of Health (HL48739 and HL68216); European Union (LSHM-CT-2006-0376331, LSHG-CT-2006-037277); the Biomedical Research Foundation of the Academy of Athens; the Hellenic Cardiological Society; the John F Kostopoulos Foundatio