Silver Complexation by Metallacryptates

We report the first complete characterization of metallycryptates encapsulating Ag(i) cations: carboxylato ligands derived from l-proline and l-alanine chelate and bridge six Cu(ii) centres arranged in a slightly distorted octahedral fashion

Anomalous Spin Dynamics of Hubbard Model on Honeycomb Lattices

In this paper, the honeycomb Hubbard model in optical lattices is investigated using O(3) non-linear sigma model. A possible quantum non-magnetic insulator in a narrow parameter region is found near the metal-insulator transition. We study the corresponding dynamics of magnetic properties, and find that the narrow region could be widened by hole doping.Comment: 9 pages, 12 figure

Quench dynamics of topological quantum phase transition in Wen-plaquette model

We study the quench dynamics of the topological quantum phase transition in the two-dimensional transverse Wen-plaquette model, which has a phase transition from a Z2 topologically ordered to a spin-polarized state. By mapping the Wen-plaquette model onto a one-dimensional quantum Ising model, we calculate the expectation value of the plaquette operator Fi during a slowly quenching process from a topologically ordered state. A logarithmic scaling law of quench dynamics near the quantum phase transition is found, which is analogous to the well-known static critical behavior of the specific heat in the one-dimensional quantum Ising model.Comment: 8 pages, 5 figures,add new conten

Quantum Non-Magnetic state near Metal-Insulator Transition - a Possible Candidate of Spin Liquid State

In this paper, based on the formulation of an O(3) non-linear sigma model, we study the two-dimensional Pi-flux Hubbard model at half-filling. A quantum non-magnetic insulator is explored near the metal-insulator transition that may be a possible candidate of the spin liquid state. Such quantum non-magnetic insulator on square lattice is not induced by frustrations. Instead, it originates from quantum spin fluctuations with relatively small effective spin moments. In the strong-coupling limit, our results of the spin velocity and spin order parameter agree with results obtained from earlier calculations.Comment: 6 pages, 6 figures, Version of publication in EPL, removing the contents of honeycomb lattice and adding some contents of square lattic

Magnetism-induced massive Dirac spectra and topological defects in the surface state of Cr-doped Bi2_2Se3_3-bilayer topological insulators

Proximity-induced magnetic effects on the surface Dirac spectra of topological insulators are investigated by scanning tunneling spectroscopic (STS) studies of bilayer structures consisting of undoped Bi2Se3 thin films on top of Cr-doped Bi2Se3 layers. For thickness of the top Bi2Se3 layer equal to or smaller than 3 quintuple layers (QL), a spatially inhomogeneous surface spectral gap \Delta opens up below T_c^{2D}, which is much higher than the bulk Curie temperature T_c^{3D}. The mean value and spatial homogeneity of the gap \Delta generally increase with increasing c-axis magnetic field (H) and increasing Cr doping level (x), suggesting that the physical origin of this surface gap is associated with proximity-induced c-axis ferromagnetism. On the other hand, the temperature (T) dependence of \Delta is non-monotonic, showing an initial increase below T_c^{2D} followed by a dip and then reaching maximum at T << T_c^{3D}. These phenomena may be attributed to proximity magnetism induced by two types of contributions with different temperature dependence: a 3D contribution from the bulk magnetism that dominates at low T, and a 2D contribution associated with the RKKY interactions mediated by surface Dirac fermions, which dominates at T_c^{3D} << T < T_c^{2D}. Additionally, spatially localized sharp resonant spectra are found along the boundaries of gapped and gapless regions. These spectral resonances are long-lived at H = 0 and become suppressed under strong c-axis magnetic fields, and are attributed to magnetic impurity-induced topological defects in the spin texture of surface Dirac fermions.Comment: Manuscript 14 pages, 6 figures. Supplementary Information 7 pages. Accepted for publication in New Journal of Physics (2015

New Family of Robust 2D Topological Insulators in van der Waals Heterostructures

We predict a new family of robust two-dimensional (2D) topological insulators in van der Waals heterostructures comprising graphene and chalcogenides BiTeX (X=Cl, Br and I). The layered structures of both constituent materials produce a naturally smooth interface that is conducive to proximity induced new topological states. First principles calculations reveal intrinsic topologically nontrivial bulk energy gaps as large as 70-80 meV, which can be further enhanced up to 120 meV by compression. The strong spin-orbit coupling in BiTeX has a significant influence on the graphene Dirac states, resulting in the topologically nontrivial band structure, which is confirmed by calculated nontrivial Z2 index and an explicit demonstration of metallic edge states. Such heterostructures offer an unique Dirac transport system that combines the 2D Dirac states from graphene and 1D Dirac edge states from the topological insulator, and it offers new ideas for innovative device designs

Electrochemical integration of graphene with light absorbing copper-based thin films

We present an electrochemical route for the integration of graphene with light sensitive copper-based alloys used in optoelectronic applications. Graphene grown using chemical vapor deposition (CVD) transferred to glass is found to be a robust substrate on which photoconductive Cu_{x}S films of 1-2 um thickness can be deposited. The effect of growth parameters on the morphology and photoconductivity of Cu_{x}S films is presented. Current-voltage characterization and photoconductivity decay experiments are performed with graphene as one contact and silver epoxy as the other

Enhancement of the superconducting transition temperature from the competition between electron-electron correlations and electron-phonon interactions

We uncover that the competition between electron-electron correlations and electron-phonon interactions gives rise to unexpectedly huge enhancement of the superconducting transition temperature, several hundreds percent larger ($\geq$ 200 K) than that of the case when only one of the two is taken into account ($\sim$ 30 K). Our renormalization group analysis claims that this mechanism for the enhancement of the critical temperature is not limited on superconductivity but applied to various Fermi surface instabilities, proposing an underlying universal structure, which turns out to be essentially identical to that of a recent study [Phys. Rev. Lett. {\bf 108}, 046601 (2012)] on the enhancement of the Kondo temperature in the presence of Rashba spin-orbit interactions. We also discuss the stability of superconductivity against nonmagnetic randomness

Growth of High-Mobility Bi2Te2Se Nanoplatelets on hBN Sheets by van der Waals Epitaxy

The electrical detection of the surface states of topological insulators is strongly impeded by the interference of bulk conduction, which commonly arises due to pronounced doping associated with the formation of lattice defects. As exemplified by the topological insulator Bi2Te2Se, we show that via van der Waals epitaxial growth on thin hBN substrates the structural quality of such nanoplatelets can be substantially improved. The surface state carrier mobility of nanoplatelets on hBN is increased by a factor of about 3 compared to platelets on conventional Si/SiOx substrates, which enables the observation of well-developed Shubnikov-de Haas oscillations. We furthermore demonstrate the possibility to effectively tune the Fermi level position in the films with the aid of a back gate