Stability at Random Close Packing

The requirement that packings of hard particles, arguably the simplest structural glass, cannot be compressed by rearranging their network of contacts is shown to yield a new constraint on their microscopic structure. This constraint takes the form a bound between the distribution of contact forces P(f) and the pair distribution function g(r): if P(f) \sim f^{\theta} and g(r) \sim (r-{\sigma})^(-{\gamma}), where {\sigma} is the particle diameter, one finds that {\gamma} \geq 1/(2+{\theta}). This bound plays a role similar to those found in some glassy materials with long-range interactions, such as the Coulomb gap in Anderson insulators or the distribution of local fields in mean-field spin glasses. There is ground to believe that this bound is saturated, offering an explanation for the presence of avalanches of rearrangements with power-law statistics observed in packings

Geometric origin of excess low-frequency vibrational modes in amorphous solids

Glasses have a large excess of low-frequency vibrational modes in comparison with crystalline solids. We show that such a feature is a necessary consequence of the geometry generic to weakly connected solids. In particular, we analyze the density of states of a recently simulated system, comprised of weakly compressed spheres at zero temperature. We account for the observed a) constancy of the density of modes with frequency, b) appearance of a low-frequency cutoff, and c) power-law increase of this cutoff with compression. We predict a length scale below which vibrations are very different from those of a continuous elastic body.Comment: 4 pages, 2 figures. Argument rewritten, identical result

How collective asperity detachments nucleate slip at frictional interfaces

Sliding at a quasi-statically loaded frictional interface can occur via macroscopic slip events, which nucleate locally before propagating as rupture fronts very similar to fracture. We introduce a novel microscopic model of a frictional interface that includes asperity-level disorder, elastic interaction between local slip events, and inertia. For a perfectly flat and homogeneously loaded interface, we find that slip is nucleated by avalanches of asperity detachments of extension larger than a critical radius $A_c$ governed by a Griffith criterion. We find that after slip, the density of asperities at a local distance to yielding $x_\sigma$ presents a pseudo-gap $P(x_\sigma) \sim (x_\sigma)^\theta$, where $\theta$ is a non-universal exponent that depends on the statistics of the disorder. This result makes a link between friction and the plasticity of amorphous materials where a pseudo-gap is also present. For friction, we find that a consequence is that stick-slip is an extremely slowly decaying finite size effect, while the slip nucleation radius $A_c$ diverges as a $\theta$-dependent power law of the system size. We discuss how these predictions can be tested experimentally

Dynamics of Strongly Deformed Polymers in Solution

Bead spring models for polymers in solution are nonlinear if either the finite extensibility of the polymer, excluded volume effects or hydrodynamic interactions between polymer segments are taken into account. For such models we use a powerful method for the determination of the complete relaxation spectrum of fluctuations at {\it steady state}. In general, the spectrum and modes differ significantly from those of the linear Rouse model. For a tethered polymer in uniform flow the differences are mainly caused by an inhomogeneous distribution of tension along the chain and are most pronounced due to the finite chain extensibility. Beyond the dynamics of steady state fluctuations we also investigate the nonlinear response of the polymer to a {\em large sudden change} in the flow. This response exhibits several distinct regimes with characteristic decay laws and shows features which are beyond the scope of single mode theories such as the dumbbell model.Comment: 7 pages, 3 figure

Contact line motion for partially wetting fluids

We study the flow close to an advancing contact line in the limit of small capillary number. To take into account wetting effects, both long and short-ranged contributions to the disjoining pressure are taken into account. In front of the contact line, there is a microscopic film corresponding to a minimum of the interaction potential. We compute the parameters of the contact line solution relevant to the matching to a macroscopic problem, for example a spreading droplet. The result closely resembles previous results obtained with a slip model

Classification of the nickel-like silver spectrum (AgXX) from a fast capillary discharge plasma

Includes bibliographical references (page 25).A study of the Ni-like silver (AgXX) spectra in the 13:7-20:5 nm wavelength region using a plasma generated by a fast high power capillary discharge is reported. Forty-three AgXX transitions have been identified with the assistance of calculations performed using the Slater-Condon method with generalized least-squares fits of the energy parameters. The average difference between the measured transition wavelengths and the theoretical values is 0.0026 nm

Excess Vibrational Modes and the Boson Peak in Model Glasses

The excess low-frequency normal modes for two widely-used models of glasses were studied at zero temperature. The onset frequencies for the anomalous modes for both systems agree well with predictions of a variational argument, which is based on analyzing the vibrational energy originating from the excess contacts per particle over the minimum number needed for mechanical stability. Even though both glasses studied have a high coordination number, most of the additional contacts can be considered to be weak.Comment: 4 pages, 3 figures, submitted to Physical Review Letter

Scaling of phononic transport with connectivity in amorphous solids

The effect of coordination on transport is investigated theoretically using random networks of springs as model systems. An effective medium approximation is made to compute the density of states of the vibrational modes, their energy diffusivity (a spectral measure of transport) and their spatial correlations as the network coordination $z$ is varied. Critical behaviors are obtained as $z\to z_c$ where these networks lose rigidity. A sharp cross-over from a regime where modes are plane-wave-like toward a regime of extended but strongly-scattered modes occurs at some frequency $\omega^*\sim z-z_c$, which does not correspond to the Ioffe-Regel criterion. Above $\omega^*$ both the density of states and the diffusivity are nearly constant. These results agree remarkably with recent numerical observations of repulsive particles near the jamming threshold \cite{ning}. The analysis further predicts that the length scale characterizing the correlation of displacements of the scattered modes decays as $1/\sqrt{\omega}$ with frequency, whereas for $\omega<<\omega^*$ Rayleigh scattering is found with a scattering length $l_s\sim (z-z_c)^3/\omega^4$. It is argued that this description applies to silica glass where it compares well with thermal conductivity data, and to transverse ultrasound propagation in granular matter

On the rigidity of a hard sphere glass near random close packing

We study theoretically and numerically the microscopic cause of the mechanical stability of hard sphere glasses near their maximum packing. We show that, after coarse-graining over time, the hard sphere interaction can be described by an effective potential which is exactly logarithmic at the random close packing $\phi_c$. This allows to define normal modes, and to apply recent results valid for elastic networks: mechanical stability is a non-local property of the packing geometry, and is characterized by some length scale $l^*$ which diverges at $\phi_c$ [1, 2]. We compute the scaling of the bulk and shear moduli near $\phi_c$, and speculate on the possible implications of these results for the glass transition.Comment: 7 pages, 4 figures. Figure 4 had a wrong unit in abscissa, which was correcte