612 research outputs found
Bonding-Compatible Corrosion Inhibitor for Rinsing Metals
A corrosion-inhibiting mixture of compounds has been developed for addition to the water used to rinse metal parts that have been cleaned with aqueous solutions in preparation for adhesive bonding of the metals to rubber and rubber-like materials. Prior to the development of this corrosion inhibitor, the parts (made, variously, of D6AC steel and 7075-T73 aluminum) were rinsed by deionized water, which caused corrosion in some places on the steel parts especially in such occluded places as sealing surfaces and threaded blind holes. An integral part of the particular cleaning process is the deposition of a thin layer of silicates and silane primers that increase the strength of the adhesive bond. The corrosion inhibitor is formulated, not only to inhibit corrosion of both D6AC steel and 7075- T73 aluminum, but also to either increase or at least not reduce the strength of the adhesive bond to be formed subsequently. The corrosion inhibitor is a mixture of sodium silicate and sodium tetraborate. The sodium silicate functions as both a corrosion inhibitor and a bond-strength promoter in association with the silane primers. The sodium tetraborate buffers the rinse solution at the optimum pH and functions as a secondary corrosion inhibitor for the steel. For a given application, the concentrations of sodium silicate and sodium tetraborate must be chosen in a compromise among the needs to inhibit corrosion of steel, inhibit corrosion of aluminum, and minimize cosmetic staining of both steel and aluminum. Concentrations of sodium silicate in excess of 150 parts of silicon per million parts of solution (ppm Si) have been determined to enhance inhibition of corrosion; unfortunately, because of the alkalinity of sodium silicate, even a small concentration can raise the pH of the rinse solution to such a level that aluminum becomes corroded despite the inhibiting effect. The pH of a solution that contains a high concentration of sodium silicate can be decreased by adding sodium tetraborate. On the other hand, the addition of sodium tetraborate increases the concentration of dissolved solids to such a high level that cosmetic staining becomes an issue
Hanbury Brown and Twiss interferometry at a free-electron laser
We present measurements of second- and higher-order intensity correlation
functions (so-called Hanbury Brown and Twiss experiment) performed at the
free-electron laser (FEL) FLASH in the non-linear regime of its operation. We
demonstrate the high transverse coherence properties of the FEL beam with a
degree of transverse coherence of about 80% and degeneracy parameter of the
order 10^9 that makes it similar to laser sources. Intensity correlation
measurements in spatial and frequency domain gave an estimate of the FEL
average pulse duration of 50 fs. Our measurements of the higher-order
correlation functions indicate that FEL radiation obeys Gaussian statistics,
which is characteristic to chaotic sources.Comment: 19 pages, 6 figures, 1 table, 40 reference
Statistical properties of a free-electron laser revealed by the Hanbury Brown and Twiss interferometry
We present a comprehensive experimental analysis of statistical properties of
the self-amplified spontaneous emission (SASE) free-electron laser (FEL) FLASH
at DESY in Hamburg by means of Hanbury Brown and Twiss (HBT) interferometry.
The experiments were performed at the FEL wavelengths of 5.5 nm, 13.4 nm, and
20.8 nm. We determined the 2-nd order intensity correlation function for all
wavelengths and different operation conditions of FLASH. In all experiments a
high degree of spatial coherence (above 50%) was obtained. Our analysis
performed in spatial and spectral domains provided us with the independent
measurements of an average pulse duration of the FEL that were below 60 fs. To
explain complicated behaviour of the 2-nd order intensity correlation function
we developed advanced theoretical model that includes the presence of multiple
beams and external positional jitter of the FEL pulses. By this analysis we
determined that in most experiments several beams were present in radiating
field and in one of the experiments external positional jitter was about 25% of
the beam size. We envision that methods developed in our study will be used
widely for analysis and diagnostics of the FEL radiation.Comment: 29 pages, 14 figures, 3 table
The Effects of Silicone Contamination on Bond Performance of Various Bond Systems
The sensitivity to silicone contamination of a wide variety of adhesive bond systems is discussed. Generalizations regarding factors that make some bond systems more sensitive to contamination than others are inferred and discussed. The effect of silane adhesion promoting primer on the contamination sensitivity of two epoxy/steel bond systems is also discussed
Interplay of Mott Transition and Ferromagnetism in the Orbitally Degenerate Hubbard Model
A slave boson representation for the degenerate Hubbard model is introduced.
The location of the metal to insulator transition that occurs at commensurate
densities is shown to depend weakly on the band degeneracy M. The relative
weights of the Hubbard sub-bands depend strongly on M, as well as the magnetic
properties. It is also shown that a sizable Hund's rule coupling is required in
order to have a ferromagnetic instability appearing. The metal to insulator
transition driven by an increase in temperature is a strong function of it.Comment: 5 pages, revtex, 5 postscript figures, submitted to Phys. Rev.
Exact single spin flip for the Hubbard model in
It is shown that the dynamics of a single -electron interacting
with a band of -electrons can be calculated exactly in the limit of
infinite dimension. The corresponding Green function is determined as a
continued fraction. It is used to investigate the stability of saturated
ferromagnetism and the nature of the ground state for two generic non-bipartite
infinite dimensional lattices. Non Fermi liquid behavior is found. For certain
dopings the -electron is bound to the -holes.Comment: 4 pages, 3 figures included with psfig, Revtex; Phys. Rev. Lett. in
press; some amendments made to clarify the calculation of the self-energy,
the extrapolation of the continued fraction, and the statements on
Fermi-liquid theor
Lattice dependence of saturated ferromagnetism in the Hubbard model
We investigate the instability of the saturated ferromagnetic ground state
(Nagaoka state) in the Hubbard model on various lattices in dimensions d=2 and
d=3. A variational resolvent approach is developed for the Nagaoka instability
both for U = infinity and for U < infinity which can easily be evaluated in the
thermodynamic limit on all common lattices. Our results significantly improve
former variational bounds for a possible Nagaoka regime in the ground state
phase diagram of the Hubbard model. We show that a pronounced particle-hole
asymmetry in the density of states and a diverging density of states at the
lower band edge are the most important features in order to stabilize Nagaoka
ferromagnetism, particularly in the low density limit.Comment: Revtex, 18 pages with 18 figures, 7 pages appendices, section on bcc
lattice adde
Disorder Induced Ferromagnetism in Restricted Geometries
We study the influence of on-site disorder on the magnetic properties of the
ground state of the infinite Hubbard model. We find that for one
dimensional systems disorder has no influence, while for two dimensional
systems disorder enhances the spin polarization of the system. The tendency of
disorder to enhance magnetism in the ground state may be relevant to recent
experimental observations of spin polarized ground states in quantum dots and
small metallic grains.Comment: 4 pages, 4 figure
Time- and momentum-resolved photoemission studies using time-of-flight momentum microscopy at a free-electron laser
Time-resolved photoemission with ultrafast pump and probe pulses is an emerging technique with wide application potential. Real-time recording of nonequilibrium electronic processes, transient states in chemical reactions, or the interplay of electronic and structural dynamics offers fascinating opportunities for future research. Combining valence-band and core-level spectroscopy with photoelectron diffraction for electronic, chemical, and structural analyses requires few 10 fs soft X-ray pulses with some 10 meV spectral resolution, which are currently available at high repetition rate free-electron lasers. We have constructed and optimized a versatile setup commissioned at FLASH/PG2 that combines free-electron laser capabilities together with a multidimensional recording scheme for photoemission studies. We use a full-field imaging momentum microscope with time-of-flight energy recording as the detector for mapping of 3D band structures in (kx, ky, E) parameter space with unprecedented efficiency. Our instrument can image full surface Brillouin zones with up to 7 Å−1 diameter in a binding-energy range of several eV, resolving about 2.5 × 105 data voxels simultaneously. Using the ultrafast excited state dynamics in the van der Waals semiconductor WSe2 measured at photon energies of 36.5 eV and 109.5 eV, we demonstrate an experimental energy resolution of 130 meV, a momentum resolution of 0.06 Å−1, and a system response function of 150 fs
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