Pemodelan Dan Simulasi Katalitik Konverter Packed Bed Untuk Mengoksidasi Jelaga Pada Gas Buang Kendaraan Bermesin Diesel

Modelling and Simulation of Packed Bed Catalytic Converter for Oxidation of Soot in Diesel Powered VehiclesFlue Gas. Diesel vehicle is used in Indonesia in very big number. This vehicle exhausts pollutants especially diesel sootthat can be reduces by using a catalytic converter to convert the soot to CO2. To obtain the optimal dimension ofcatalytic converter it is needed a model that can represent the profile of soot weight, temperature and pressure along thecatalytic converter. In this study, a model is developed for packed bed catalytic converter in an adiabatic conditionbased on a kinetic study that has been reported previously. Calculation of developed equations in this model usesPolymath 5.X solver with Range Kutta Method. The simulation result shows that temperature profile along catalyticconverter increases with the decrease of soot weight, while pressure profile decreases. The increase of soot weight inentering gas increases the needed converter length. On the other hand, the increase of catalyst diameter does not affectto soot weight along converter and temperature profile, but results a less pressure drop. For 2.500 c diesel engine,packed bed catalytic converter with ellipse's cross sectional of 14,5X7,5 cm diagonal and 0,8 cm catalyst particlediameter, needs 4,1 cm length

Modification of Carbon Nanotube for Synthesis of Titania Nanotube (Tint)-Carbon Nanotube (Cnt) Composite

Carbon nanotube (CNT) is a material widely chosen for object of research in nano technology. Apart from its good absorbent property, CNT also has a unique structure, superior mechanic and electric properties and its high strength. The property of CNT above is to be expected to improve performance of Titania nanotube (TiNT) composite. Properties of pure CNT are hydrophobic at the surface and low dispersion stability. To improve dispersability of CNT then modification need to be modified. Adding Cetyl trimethyl ammonium bromide (CTAB) surfactant on CNT is a way to increase dispersion stability of TiNT-CNT. The objective of the research was to study influence of adding of Cetyl trimethyl ammonium bromide (CTAB) surfactant to synthesis of TiNT-CNT composite in degrading phenol compound. Pure CNT was added with CTAB surfactant in liquid, then was sonificated and dried. Surfactant Cetyl trimethyl ammonium bromide (CTAB) added CNT then composited with TiNT. Phenol degradation then tested by using TiNT-CNT (CTAB) in reactor for 4.5 hours. Then sample was characterized by employing Field Emission Scanning Electron Microscopy (FESEM), X-ray Diffraction (XRD), Fourier Transform Infra-Red (FTIR) and UV-vis Spectroscopy. The result of experiments from FESEM characterization showed forming of TiNT-CNT composites morphology. From X–ray Diffraction (XRD) characterization showed crystal formed on TiNT-CNT only of anatase crystal. Degradation of TiNT-NT composite (CTAB) to phenol was also studied

Biomass Production Chlorella Vulgaris Buitenzorg Using Series of Bubble Column Photo Bioreactor with a Periodic Illumination

Chlorella vulgaris Buitenzorg cultivation using three bubble column photo bioreactors arranged in series with a volume of 200 mL for 130 hours shows an increase of biomass production of Chlorella vulgaris Buitenzorg up to 1.20 times and a decrease of the ability of CO2 fixation compared to single reactor at a periodic sun illumination cycle. The operation conditions on cultivation are as following: T, 29.0oC; P,1 atm.; UG, 2.40 m/h; CO2, 10%; Benneck medium; and illumination source by Phillip Halogen Lamp 20W /12V/ 50Hz. Other research parameters such as microbial carbon dioxide transferred rate (qco2), CO2 transferred rate (CTR), energy consumption for cellular formation (Ex), and cultural bicarbonate species concentration [HCO3] also give better results on series of reactor

Biodegradation of Linear Alkyl Benzene Sulfonate by bacterial consortium

Surface active agents (surfactants) are chemical compounds which are massively used as raw material in detergent production. Synthetic type surfactants are often used because they perform better and are more economical compared to natural detergents. Linear Alkyl Benzene Sulfonate (LAS) is one of the synthetic surfactants that is widely used. Although LAS is biodegradable, its introduction to the environment in big amounts harms water bodies. Research on biodegradation of LAS with 100 ppm, 400 ppm, 700 ppm, 1000 ppm and 1500 ppm concentrations was conducted by using consortium of bacteria comprising of Pseudomonas aeroginosa, Bacillus subtilis, Bacillus aglomerans, Bacillus cereus, Bacillus alvae. Experiments were carried out for twelve days, at 29oC with initial total inoculum of bacteria at 1,59 x 108 CFU/mL. Results showed that this type of bacterial consortium could tolerate 1500 ppm in LAS environment. However, significant growth rate did not occurr, 0.039 – 0.042 hour -1 and not too efficiently reduce Chemical Oxygen Demand (COD) for those systems. Surface tension in several variated concentration of LAS: 0 ppm >100 ppm >400 ppm >700 ppm, LAS 700 ppm = 1000 ppm = 1500 ppm