185,398 research outputs found
Computer program for transient response of structural rings subjected to fragment impact
Mathematical optimization of containment/deflection system would save time, effort, and material as well as afford designer greater opportunity to investigate new ideas and variety of materials
Analytical Mechanics of Chemical Reactions. V. Application to the Linear Reactive H +H_2 Systems
Natural collision coordinates and a zeroth‐order vibrational–adiabatic approximation are used to treat linear reactive collisions. Nonadiabatic effects on barrier transmission and on vibrational state of products are calculated. The present results are classical and are compared with exact classical numerical results for the H+H_2 reaction in the range 7–20 kcal/mol of initial relative translational energy. The agreement is encouraging and the results support the concepts introduced earlier of statistical adiabaticity and of nonadiabatic leak. At low energies the reaction is adiabatic on the average (initial vibrational phase average), thus justifying activated complex theory for this system. The relative importance of reaction path curvature and of vibrational frequency variation along the reaction path in inducing nonadiabatic effects is described. Implications for a quantum treatment, activated complex theory, and highly nonadiabatic systems are noted
Analytical Mechanics of Chemical Reactions. VI. Rotational and Vibrational Distributions of the H + H_2 Reaction in a Plane
Rotational and vibrational distributions for the exchange reaction H+H_(2)→H_(2)+H are obtained numerically for reaction in a plane and compared with the vibrationally adiabatic solutions. Evidence is obtained regarding the two adiabatic solutions for the final rotational state predicted earlier and for the disappearance of one of these at higher initial relative velocity. Good agreement between calculations based on natural collision coordinates and these based on Cartesian coordinates was found, where tested. The vibrational motion for reaction in a plane is fairly adiabatic on the average at energies of thermal interest. Connections with other properties are noted. The results support the idea of statistical adiabaticity suggested earlier in this series and thus support a derivation of activated complex theory based on this concept
An Upper Limit on Omega_matter Using Lensed Arcs
We use current observations on the number statistics of gravitationally
lensed optical arcs towards galaxy clusters to derive an upper limit on the
cosmological mass density of the Universe. The gravitational lensing statistics
due to foreground clusters combine properties of both cluster evolution, which
is sensitive to the matter density, and volume change, which is sensitive to
the cosmological constant. The uncertainties associated with the predicted
number of lensing events, however, currently do not allow one to distinguish
between flat and open cosmological models with and without a cosmological
constant. Still, after accounting for known errors, and assuming that clusters
in general have dark matter core radii of the order ~ 35 h^-1 kpc, we find that
the cosmological mass density, Omega_m, is less than 0.56 at the 95%
confidence. Such a dark matter core radius is consistent with cluster
potentials determined recently by detailed numerical inversions of strong and
weak lensing imaging data. If no core radius is present, the upper limit on
Omega_m increases to 0.62 (95% confidence level). The estimated upper limit on
Omega_m is consistent with various cosmological probes that suggest a low
matter density for the Universe.Comment: 6 pages, 3 figures. Accepted version (ApJ in press
X-ray Polarization Signatures of Compton Scattering in Magnetic Cataclysmic Variables
Compton scattering within the accretion column of magnetic cataclysmic
variables (mCVs) can induce a net polarization in the X-ray emission. We
investigate this process using Monte Carlo simulations and find that
significant polarization can arise as a result of the stratified flow structure
in the shock-ionized column. We find that the degree of linear polarization can
reach levels up to ~8% for systems with high accretion rates and low
white-dwarf masses, when viewed at large inclination angles with respect to the
accretion column axis. These levels are substantially higher than previously
predicted estimates using an accretion column model with uniform density and
temperature. We also find that for systems with a relatively low-mass white
dwarf accreting at a high accretion rate, the polarization properties may be
insensitive to the magnetic field, since most of the scattering occurs at the
base of the accretion column where the density structure is determined mainly
by bremsstrahlung cooling instead of cyclotron cooling.Comment: 7 pages, 8 figures, accepted by MNRA
Tunneling Effect Near Weakly Isolated Horizon
The tunneling effect near a weakly isolated horizon (WIH) has been studied.
By applying the null geodesic method of Parikh and Wilczek and Hamilton-Jacibi
method of Angheben et al. to a weakly isolated horizon, we recover the
semiclassical emission rate in the tunneling process. We show that the
tunneling effect exists in a wide class of spacetimes admitting weakly isolated
horizons. The general thermodynamic nature of WIH is then confirmed.Comment: 7 pages, accepted for publication in Physical Review
Accelerating charging dynamics in sub-nanometer pores
Having smaller energy density than batteries, supercapacitors have
exceptional power density and cyclability. Their energy density can be
increased using ionic liquids and electrodes with sub-nanometer pores, but this
tends to reduce their power density and compromise the key advantage of
supercapacitors. To help address this issue through material optimization, here
we unravel the mechanisms of charging sub-nanometer pores with ionic liquids
using molecular simulations, navigated by a phenomenological model. We show
that charging of ionophilic pores is a diffusive process, often accompanied by
overfilling followed by de-filling. In sharp contrast to conventional
expectations, charging is fast because ion diffusion during charging can be an
order of magnitude faster than in bulk, and charging itself is accelerated by
the onset of collective modes. Further acceleration can be achieved using
ionophobic pores by eliminating overfilling/de-filling and thus leading to
charging behavior qualitatively different from that in conventional, ionophilic
pores
Towards a guided atom interferometer based on a superconducting atom chip
We evaluate the realization of a novel geometry of a guided atom
interferometer based on a high temperature superconducting microstructure. The
interferometer type structure is obtained with a guiding potential realized by
two current carrying superconducting wires in combination with a closed
superconducting loop sustaining a persistent current. We present the layout and
realization of our superconducting atom chip. By employing simulations we
discuss the critical parameters of the interferometer guide in particular near
the splitting regions of the matter waves. Based on measurements of the
relevant chip properties we discuss the application of a compact and reliable
on-chip atom interferometer.Comment: 14 pages, 7 figures, accepted for New Journal of Physic
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