Determination of water content using mass spectrometry

Mass spectrometer is used to measure small quantities of water present in different materials. System has been applied in measuring water and gases desorbed from microcircuitry insulation, can also be used with foods, polymeric materials, and organic solvents

Dynamic delta method for trace gas analysis

Method has been developed in which measurements are made only over viscous flow range, eliminating fractionation before the molecular leak and problems due to surface elution

Study of lee-side flows over conically cambered delta wings at supersonic speeds, part 1

An experimental investigation was performed in which surface pressure data, flow visualization data, and force and moment data were obtained on four conical delta wing models which differed in leading-edge camber only. Wing leading-edge camber was achieved through a deflection of the outboard 30% of the local wind semispan of a reference 75 degrees swept flat delta wing. The four wing models have leading-edge deflection angles delta sub F of 0, 5, 10, and 15 degrees measured streamwise. Data for the wings with delta sub F = 10 and 15 degrees showed that hinge-line separation dominated the lee-side wing loading and prohibited the develpment of leading-edge separation on the deflected portion of wing leading edge. However, data for the wing with delta sub F = 5 degrees, a vortex was positioned on the deflected leading edge with reattachment at the hinge line. Flow visualization results were presented which detail the influence of Mach number, angle of attack, and camber on the lee-side flow characteristics of conically cambered delta wings. Analysis of photgraphic data identified the existence of 12 distinctive lee-side flow types. In general, the aerodynamic force and moment data correlated well with the pressure and flow visualization data

Correspondence between one- and two-equation models for solute\ud transport in two-region heterogeneous porous media

In this work, we study the transient behavior of upscaled models for solute transport in two-region porous media. We focus on the following three models: (1) a time non-local, two-equation model (2eq-nlt). This model does not rely on time constraints and, therefore, is particularly useful in the short-time regime, when the time scale of interest (t) is smaller than the characteristic time (T1) for the relaxation of the effective macroscale parameters (i.e., when t ≤ T1); (2) a time local, two-equation model (2eq). This model can be adopted when (t) is significantly larger than (T1) (i.e., when t » T1); and (3) a one-equation, time-asymptotic formulation (1eq∞). This model can be adopted when (t) is significantly larger than the time scale (T2) associated with exchange processes between the two regions (i.e., when t » T2). In order to obtain some physical insight into this transient behavior, we combine a theoretical approach based on the analysis of spatial moments with numerical and analytical results in simple cases. The main result of this paper is to show that there is weak long-time convergence of the solution of (2eq) toward the solution of (1eq∞) in terms of standardized moments but, interestingly, not in terms of centered moments. Physically, our interpretation of this result is that the spreading of the solute is dominating higher order non-zero perturbations in the asymptotic regime

Investigation of atomic oxygen-surface interactions related to measurements with dual air density explorer satellites

For a number of candidate materials of construction for the dual air density explorer satellites the rate of oxygen atom loss by adsorption, surface reaction, and recombination was determined as a function of surface and temperature. Plain aluminum and anodized aluminum surfaces exhibit a collisional atom loss probability alpha .01 in the temperature range 140 - 360 K, and an initial sticking probability. For SiO coated aluminum in the same temperature range, alpha .001 and So .001. Atom-loss on gold is relatively rapid alpha .01. The So for gold varies between 0.25 and unity in the temperature range 360 - 140 K