Sound transmission testing of polymer compounds

This is the post-print version of the final paper published in Polymer Testing. The published article is available from the link below. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. Copyright @ 2012 Elsevier Ltd.Acoustic properties of polymer compounds are an important consideration for many applications. Currently, there are standard test methods for the determination of these properties. There is, however, no standard for the equipment used in these tests, only a specification for the test conditions. The objective of this work was to evaluate the operation and performance of a bench top laboratory sound testing system for its potential as a simple cost effective method for the initial evaluation of materials that require specific acoustic properties. The work was limited to an investigation of the property of sound transmission loss (STL). A study of the effect of the mounting conditions for the samples on the STL was carried out. Following this, a series of polymer and polymer composite samples was tested. The results presented demonstrate the potential for the testing system as an effective standard test method for the acoustic properties of polymer composites and other materials.Technology Strategy Board, U

A.C.Electroluminescent Lamps: Shedding some light on their mysteries

A.C.powder electroluminescent lamps have been known and used for many years, but their mechanism of operation is still debated. Many thousands of phosphors are known, but the vast majority are not electroluminescent. A number of materials do exhibit the effect. Of these, however, ZnS doped with Cu is absolutely in a class of its own, and is the only material from which viable lamps can be made. In this work studies have been made of the performance of devices under a range of pulsed and continuous excitation conditions and new hypotheses presented which attempt to explain the behavior of this unique material

Structure and morphology of ACEL ZnS:Cu,Cl phosphor powder etched by hydrochloric acid

© The Electrochemical Society, Inc. 2009. All rights reserved. Except as provided under U.S. copyright law, this work may not be reproduced, resold, distributed, or modified without the express permission of The Electrochemical Society (ECS). The archival version is available at the link below.Despite many researches over the last half century, the mechanism of ac powder electroluminescence remains to be fully elucidated and, to this end, a better understanding of the relatively complex structure of alternate current electroluminescence (ACEL) phosphors is required. Consequently, the structure and morphology of ZnS:Cu,Cl phosphor powders have been investigated herein by means of scanning electron microscopy (SEM) on hydrochloric acid-etched samples and X-ray powder diffraction. The latter technique confirmed that, as a result of two-stage firing during their synthesis, the phosphors were converted from the high temperature hexagonal (wurtzite) structure to the low temperature cubic (sphalerite) polymorph having a high density of planar stacking faults. Optical microscopy revealed that the crystal habit of the phosphor had the appearance of the hexagonal polymorph, which can be explained by the sphalerite pseudomorphing of the earlier wurtzite after undergoing the hexagonal to cubic phase transformation during the synthesis. SEM micrographs of the hydrochloric-etched phosphor particles revealed etch pits, a high density of planar stacking faults along the cubic [111] axis, and the pyramids on the (111) face. These observations were consistent with unidirectional crystal growth originating from the face showing the pyramids.EPSRC, DTI, and the Technology Strategy Board-led Technology Program

Environmentally friendly packaging materials from renewable resources as alternatives for oil-based polymers

Nearly 60 m tonnes of waste is produced annually in Europe from “plastic packaging” engendering significant challenges for legislative controls and minimisation of environmental impact. There is an increasing demand for biodegradable packaging, which can be disposed of with minimum environmental impact, but the growing market is still in its infancy predominantly due to a lack of materials having environmental, practical and economic suitability. This research project dealt with some processing challenges of environmentally friendly packaging materials from renewable resources, as a long term solution to mitigate some issues associated with oil based plastic packaging. In this work, novel Polylactic acid (PLA) and starch based composites were developed with the requisite technical properties to fill the gap in the food packaging and cosmetic packaging industry. It was found that starch can be incorporated in a PLA matrix at the 10% level without difficulty in processing in the presence of 2% methyldiphenyl diisocyante. The blend shows properties similar to pure PLA. It was also found that the elongation at break and impact properties of PLA can be increased remarkably by the addition of a biostrength impact modifier. Furthermore, mixing of PLA and starch in the blend is efficient when the PLA particle size is reduced. It was also found that flexible and tougher PLA/starch blend pellets, that can be injection moulded, can be produced by an extrusion process with a range of additives. Each additive has a maximum level that exhibits optimum properties. The blends also established that 15% starch can be incorporated into the PLA matrix to reduce the cost without any processing difficulties. Encouragingly, the presence of an impact modifier in the PLA/starch blends has shown more desirable properties. Furthermore, the mechanical properties of the pellets exposed to increased residence time in the injection moulding barrel and of the test specimens stored for 9 months at 21ºC were also satisfactory for the new blend. The overall results exhibited some attractive properties in the tri blend system, which can be easily adopted by the plastics industry for development of an injection moulded product within the scope of applications such as dry food packaging or cosmetic packaging. A further finding of this project is that biodegradation under a home composting environment can be improved by incorporating starch and certain other modifiers into PLA.EThOS - Electronic Theses Online ServiceGBUnited Kingdo

Multicolour correlative imaging using phosphor probes

Correlative light and electron microscopy exploits the advantages of optical methods, such as multicolour probes and their use in hydrated live biological samples, to locate functional units, which are then correlated with structural details that can be revealed by the superior resolution of electron microscopes. One difficulty is locating the area imaged by the electron beam in the much larger optical field of view. Multifunctional probes that can be imaged in both modalities and thus register the two images are required. Phosphor materials give cathodoluminescence (CL) optical emissions under electron excitation. Lanthanum phosphate containing thulium or terbium or europium emits narrow bands in the blue, green and red regions of the CL spectrum; they may be synthesised with very uniform-sized crystals in the 10- to 50-nm range. Such crystals can be imaged by CL in the electron microscope, at resolutions limited by the particle size, and with colour discrimination to identify different probes. These materials also give emissions in the optical microscope, by multiphoton excitation. They have been deposited on the surface of glioblastoma cells and imaged by CL. Gadolinium oxysulphide doped with terbium emits green photons by either ultraviolet or electron excitation. Sixty-nanometre crystals of this phosphor have been imaged in the atmospheric scanning electron microscope (JEOL ClairScope). This probe and microscope combination allow correlative imaging in hydrated samples. Phosphor probes should prove to be very useful in correlative light and electron microscopy, as fiducial markers to assist in image registration, and in high/super resolution imaging studies

In situ Raman analyses of deep-sea hydrothermal and cold seep systems (Gorda Ridge and Hydrate Ridge)

Author Posting. © American Geophysical Union, 2006. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Geochemistry Geophysics Geosystems 7 (2006): Q05023, doi:10.1029/2005GC001204.The Deep Ocean Raman In Situ Spectrometer (DORISS) instrument was deployed at the Sea Cliff Hydrothermal Field and Hydrate Ridge in July 2004. The first in situ Raman spectra of hydrothermal minerals, fluids, and bacterial mats were obtained. These spectra were analyzed and compared to laboratory Raman measurements of standards and samples collected from the site. Spectra of vent fluid (∼294°C at the orifice) at ∼2700 m depth were collected with noncontact and immersion sampling optics. Compared to spectra of ambient (∼2°C) seawater, the vent fluid spectra show changes in the intensity and positions of the water O-H stretch bands due to the elevated temperature. The sulfate band observed in seawater spectra is reduced in vent fluid spectra as sulfate is removed from vent fluid in the subseafloor. Additional components of hydrothermal fluid are present in concentrations too low to be detected with the current Raman system. A precision underwater positioner (PUP) was used to focus the laser spot on opaque samples such as minerals and bacterial mats. Spectra were obtained of anhydrite from actively venting chimneys, and of barite deposits in hydrothermal crusts. Laboratory analysis of rock samples collected in the vent field also detected the presence of gypsum. Spectra of bacterial mats revealed the presence of elemental sulfur (S8) and the carotenoid beta-carotene. Challenges encountered include strong fluorescence from minerals and organics and insufficient sensitivity of the instrument. The next generation DORISS instrument addresses some of these challenges and holds great potential for use in deep-sea vent environments.Funding was provided by the David & Lucile Packard Foundation