Ion molecule reactions in vinyl fluoride by photoionization. Effects of vibrational excitation on major reaction pathways

Photoionization methods have been used to study the reactions of the molecular ion in vinyl fluoride to yield the ionic products C_3H_3F_2^+, C_3H_4F^+, and C_3H_5^+. Quantitative measurements are reported of the effect of the vibrational state of the reactant ion on the product distribution and overall reaction cross section. Reaction cross sections for all three channels decrease with reactant internal energy. The effect on the reaction pathway producing C_3H_3F_2^+ is especially pronounced, with 0.18 eV of vibrational excitation being sufficient to reduce the reaction probability by 75%. Deactivation of vibrationally excited reactant ions competes with the reaction and is shown to be an efficient process

Higgs alignment from extended supersymmetry

We consider the effective type-II Two-Higgs doublet model originating from Dirac gaugino models with extended supersymmetry in the gauge sector, which is automatically aligned in the simplest realisations. We show that raising the scale at which the extended supersymmetry is manifest and including quantum corrections actually improves the alignment. Using an effective field theory approach including new threshold corrections and two-loop RGEs, plus two-loop corrections to the Higgs mass in the low-energy theory, we study the implications from the Higgs mass and other experimental constraints on the scale of superpartners. We contrast the results of the minimal Dirac gaugino model, where alignment is automatic, with the hMSSM and the MRSSM, where it is not, also providing an hMSSM-inspired analysis for the new models.Comment: 37 pages, 13 figures. References added. Published versio

Shifts in hexapod diversification and what Haldane could have said

Data on species richness and taxon age are assembled for the extant hexapod orders (insects and their six-legged relatives). Coupled with estimates of phylogenetic relatedness, and simple statistical null models, these data are used to locate where, on the hexapod tree, significant changes in the rate of cladogenesis (speciation-minus-extinction rate) have occurred. Significant differences are found between many successive pairs of sister taxa near the base of the hexapod tree, all of which are attributable to a shift in diversification rate after the origin of the Neoptera (insects with wing flexion) and before the origin of the Holometabola (insects with complete metamorphosis). No other shifts are identifiable amongst supraordinal taxa. Whilst the Coleoptera have probably diversified faster than either of their putative sister lineages, they do not stand out relative to other closely related clades. These results suggest that any Creator had a fondness for a much more inclusive clade than the Coleoptera, definitely as large as the Eumetabola (Holometabola plus bugs and their relatives), and possibly as large as the entire Neoptera. Simultaneous, hence probable causative events are discussed, of which the origin of wing flexion has been the focus of much attention

Health Risks, Past Usage, and Intention to Use Weight Loss Products in Normal Weight Women with High and Low Body Dysphoria

Objective: There are many health risks involved with the use of weight loss products by normal weight women. The mass media may compound this problem through the promotion of weight loss products and a thin body size. This study tested women\u27s perceptions of different weight loss product ads to determine if body dysphoria (i.e., an over concern with body size and shape in normal weight people) was associated with risk beliefs, past behaviors, and intention toward using weight loss products. Method: Normal weight women (age range = 18-41 yr), who were classified as either high (n=45) or low (n=43) on a measure of body dysphoria, rated different weight loss products according to their perception of health risks, past behavior, and their intention to consume the products. These products were a dietary fat substitute (olestra), a prescription obesity medication (sibutramine), and an over-the-counter appetite suppressant (phenylpropanolamine). Results: High body dysphoric women reported higher intentions to use the products as well as increased prior use of two of the three weight loss products. High body dysphoric women did not believe that these weight loss products were harmless. They recognized potential health risks associated with using such products, but nonetheless, expressed intention to use these weight loss products at a higher frequency. Also, several variables related to body image were found to effectively discriminate normal weight women at risk for abusing weight loss products. Discussion: This study found that women who do not need to lose weight but have significant body image concerns were willing to use potentially harmful weight loss products despite the knowledge that such products might pose significant health risks. Techniques utilized by advertising regulatory agencies such as warning labels did not have a strong deterrent effect for stated intentions to use the products. Implications of these findings for public health policy issues were discussed

Diurnal variation in harbour porpoise detection – potential implications for management

Peer reviewedPublisher PD

Why taking moderate positions may help the Democrats to retake the House this fall

Partisan polarization has steadily increased in recent decades, culminating in record highs in recent years. In new research, Jamie Carson and Ryan Williamson compare the ideology of winning and losing candidates in US House elections between 1992 and 2012. They find that winning candidates are much less ideologically extreme than those who lose elections. Though some districts prefer more extreme representatives, these are a minority. Together, these findings show that if challengers were more skilled at winning elections, polarization in Congress might be even greater than it is now

Oxidative Stress Response to Short Duration Bout of Submaximal Aerobic Exercise in Healthy Young Adults

The purpose of this study was to investigate the oxidative stress response to a short duration bout of submaximal exercise in a cohort of healthy young adults. 15 apparently healthy college age males and females completed a modified Bruce-protocol treadmill test to 75–80% of their heart rate reserve. Blood samples collected immediately before (pre-exercise), immediately after, 30, 60 and 120 minutes post-exercise were assayed for total antioxidant capacity (TAC), superoxide disumutase (SOD), thiobarbituric acid-reactive substances (TBARS), and protein carbonyls (PC). SOD activity was significantly increased from pre-exercise levels at 30 minutes (77%), 60 minutes (33%), and 120 minutes (37%) post-exercise. TAC levels were also significantly increased from pre-exercise levels at 60 minutes (30%) and 120 minutes (33%) post-exercise. There were no significant changes in biomarkers for reactive oxygen/nitrogen species (RONS) mediated damage (TBARS and PC) across all post-exercise time points. In a cohort of healthy young adults, a short duration bout of submaximal aerobic exercise elicited increases in antioxidant activity/concentration, but did not evoke changes in oxidative stress-induced damage. These results may suggest that: (1) short duration bouts of submaximal aerobic exercise are sufficient to induce RONS generation; and (2) the antioxidant defense system is capable of protecting against enhanced RONS production induced by a short duration, submaximal exercise bout in healthy young adults

The story of the midterms is the triumph of the moderates – on both sides

Following this week’s midterm elections, in 2019 the Democratic Party will be in the majority in the US House of Representatives. Ryan Williamson and Jamie Carson have previously argued that more moderate Democratic candidates were more likely to win House seats. Analyzing the midterm results, they find that this year Democratic candidates who were more moderate were indeed able to win back seats from incumbent conservative candidates, and were also more likely to outperform Clinton’s vote from 2016

Dispersion and damping of potential surface waves in a degenerate plasma

Potential (electrostatic) surface waves in plasma half-space with degenerate electrons are studied using the quasi-classical mean-field kinetic model. The wave spectrum and the collisionless damping rate are obtained numerically for a wide range of wavelengths. In the limit of long wavelengths, the wave frequency $\omega$ approaches the cold-plasma limit $\omega=\omega_p/\sqrt{2}$ with $\omega_p$ being the plasma frequency, while at short wavelengths, the wave spectrum asymptotically approaches the spectrum of zero-sound mode propagating along the boundary. It is shown that the surface waves in this system remain weakly damped at all wavelengths (in contrast to strongly damped surface waves in Maxwellian electron plasmas), and the damping rate nonmonotonically depends on the wavelength, with the maximum (yet small) damping occuring for surface waves with wavelength of $\approx5\pi\lambda_{F}$, where $\lambda_{F}$ is the Thomas-Fermi length.Comment: 22 pages, 6 figure