Thermal Modeling in Polymer Extrusion

In this paper we consider thermal effects of polymer flows through a cylindrical die. First, we derive a model for the oscillatory behavior of polymer flow in an extruder given a functional relation between the pressure and flow rate. A simple isothermal but temperature dependent model is constructed to find this relation. Unfortunately, the model is shown to be invalid in the physical regime of interest. We present several arguments to suggest that the isothermal assumption is reasonable but that a more detailed understanding of the small-scale molecular dynamics near the boundary may be required. Second, we show that a simplified model for thermoflow multiplicity in a cooled tube is inconsistent, when the stationary non-Newtonian flow is assumed to be incompressible without radial pressure gradients and without radial velocity. This inconsistency can be removed by allowing for weak compressibility effects in the down-steam area

4-Methyl-2,6-bis(phosphonomethyl)phenol dihydrate

The 4-methyl-2,6-bis(phosphomethyl)phenol molecule, which crystallizes with two water molecules per asymmetric unit, has approximate twofold symmetry and is involved in extensive three-dimensional hydrogen bonding in which every available OH group participates. The principal dimensions include P--O 1.4981 (13) and 1.5015 (14) ,~, four P--OH distances in the range 1.5395(14) to 1.5688(13) A, P--C 1.7857(17) and 1.7893 (17) ~k, and O...O intramolecular and intermolecular hydro.gen-bond distances in the range 2.458 (2) to 2.866 (2) A

Comparative effects of carbon dioxide enrichment and pH change on phytoplankton communities in SRS Carolina bay restoration efforts. Progress report, April 1994--March 1995

Impacts of land-use activities on wetland ecosystems are important issues for environmental planners, conservation groups, and government agencies. This project at DOE`s Savannah River Site focused its year one efforts on population changes produced by effects of changes in pH and CO2 resulting from simulated aquatic ecosystem successional processes. Results are being compared with phytoplankton changes induce by added nutrients

The congenital and see-saw nystagmus in the prototypical achiasma of canines: comparison to the human achiasmatic prototype

AbstractWe applied new methods for canine eye-movement recording to the study of achiasmatic mutant Belgian Sheepdogs, documenting their nystagmus waveforms and comparing them to humans with either congenital nystagmus (CN) alone or in conjunction with achiasma. A sling apparatus with head restraints and infrared reflection with either earth- or head-mounted sensors were used. Data were digitized for later evaluation. The horizontal nystagmus (1–6 Hz) was similar to that of human CN. Uniocular and disconjugate nystagmus and saccades were recorded. See-saw nystagmus (SSN), not normally seen with human CN, was present in all mutants (0.5–6 Hz) and in the one human achiasmat studied thus far. This pedigree is an animal model of CN and the SSN caused by achiasma or uniocular decussation. Given the finding of SSN in all mutant dogs and in a human, achiasma may be sufficient for the development of congenital SSN and, in human infants, SSN should alert the clinician to the possibility of either achiasma or uniocular decussation. Finally, the interplay of conjugacy and disconjugacy suggests independent ocular motor control of each eye with variable yoking in the dog

Plumage and ecology of cormorants

The paper draws on data attending the etho-ecology of four species of cormorants (Phalacrocoracidae) in support of an hypothesis for the adaptive significance of the predominantly dark plumage of these birds. It is suggested that a dark plumage, primarily by being most receptive to solar radiation, assists cormorants in supplementing metabolic heat for maintenance of normal body temperature. In those cormorants which have white extending over ventral and frontal aspects of the body, it is suggested that this is an adaptation to the feeding situation and that it promotes 'hunting camouflage' through countershading

Lipids of the stratum corneum vary with cutaneous water loss among larks along a temperature-moisture gradient

We explored the relationship between lipids of the stratum corneum (SC), the barrier to water-vapor diffusion of the skin, and cutaneous water loss (CWL) of species of free-living larks along a temperature-moisture gradient. Our results showed that free fatty acids, cholesterol, and ceramides were the major constituents of SC in larks from different environments including the Netherlands, a mesic environment; Iran, a semiarid region; and several areas in Saudi Arabia, a hot dry desert. We found that CWL was reduced among larks inhabiting deserts, but our data did not support the hypothesis that birds from desert environments have larger quantities of lipids per unit dry mass of the SC than larks from more mesic environments. Instead, larks in arid environments had a higher proportion of ceramides, especially the more polar fractions 4 - 6, and a smaller proportion of free fatty acids in their SC, an adjustment that apparently reduced their CWL. Subtle changes in the ratios of lipid classes can apparently alter the movement of water vapor through the skin. We hypothesize that desert birds have higher proportions of ceramides in their SC and lower proportions of free fatty acids because this combination allows the lipid lamellae to exist in a more highly ordered crystalline phase and consequently creates a tighter barrier to water-vapor diffusion.</p

Information entropy in fragmenting systems

The possibility of facing critical phenomena in nuclear fragmentation is a topic of great interest. Different observables have been proposed to identify such a behavior, in particular, some related to the use of information entropy as a possible signal of critical behavior. In this work we critically examine some of the most widespread used ones comparing its performance in bond percolation and in the analysis of fragmenting Lennard Jones Drops.Comment: 3 pages, 3 figure