Determination of the oxidative stability of perfluoropolyalkyl ethers and correlation with chemical structure

The oxidative stabilities of several perfluoropolyalkyl ethers (PFPAE) with related chemical structures were determined by thermal gravimetric analysis and correlated with their chemical structures. These results show that oxidative stability increases as the number of difluoroformal groups decreases and as trifluoromethyl substituents are added. They are also consistent with a recently proposed intramolecular disproportionation reaction mechanism involving coordination of successive ether oxygens to a Lewis acid. Since polytetrafluoroethylene contains no oxygen, it provides an indication of the upper limit to oxidative stability of PFPAE fluids. These results also show that oxidative decomposition of PFPAE fluids requires the presence of an active metal as well as air. Consequently, it may be possible to minimize decomposition and thus improve oxidative stability by passivating reactive metal surfaces

Determination of the thermal stability of perfluoroalkylethers

The thermal decomposition temperatures of several commercial and custom synthesized perfluoroalkylether fluids were determined with a computerized tensimeter. In general, the decomposition temperatures of the commercial fluids were all similar and significantly higher than those for custom synthesized fluids. Correlation of the decomposition temperatures with the molecular structures of the primary components of the commercial fluids revealed that the stability of the fluids is not affected by intrinsic factors such as carbon chain length, branching, or cumulated difluoroformal groups. Instead, correlation with extrinsic factors revealed that the stability may be limited by the presence of small quantities of thermally unstable material and/or chlorine-containing material arising from the use of chlorine-containing solvents during synthesis. Finally, correlation of decomposition temperatures with molecular weights for Demnum and Krytox fluids supports a chain cleavage reaction mechanism for Demnum fluids and an unzipping reaction mechanism for Krytox fluids

Conceptual design studies for surface infrastructure

The utimate design of a manned Mars base will be the result of considerable engineering analysis and many trade studies to optimize the configuration. Many options and scenarios are available and all need to be considered at this time. Initial base elements, two base configuration concepts, internal space architectural concerns, and two base set-up scenarios are discussed. There are many variables as well as many unknowns to be reckoned with before people set foot on the red planet

Tribological characteristics of perfluoropolyether liquid lubricants under sliding conditions in high vacuum

Tribological characteristics of three PFPE's (Fomblin Z, Demnum, and Krytox) were studied under high vacuum using a four-ball apparatus with 440C steel specimens. Fomblin Z and Demnum exhibited initial scuffing-like high friction whereas Krytox did not. Steady state friction with Fomblin Z was the lowest among the three oils. Frictional values for Demnum and Krytox were almost the same. The lowest wear rate in air was provided by Krytox regardless of load, and low wear rates in vacuum at high load were achieved with Krytox and Demnum. Results are explained by reactivity and pressure-viscosity characteristics of the oils

Standoff Distance of Bow Shocks in Galaxy Clusters as Proxy for Mach Number

X-ray observations of merging clusters provide many examples of bow shocks leading merging subclusters. While the Mach number of a shock can be estimated from the observed density jump using Rankine-Hugoniot condition, it reflects only the velocity of the shock itself and is generally not equal to the velocity of the infalling subcluster dark matter halo or to the velocity of the contact discontinuity separating gaseous atmospheres of the two subclusters. Here we systematically analyze additional information that can be obtained by measuring the standoff distance, i.e. the distance between the leading edge of the shock and the contact discontinuity that drives this shock. The standoff distance is influenced by a number of additional effects, e.g. (1) the gravitational pull of the main cluster (causing acceleration/deceleration of the infalling subcluster), (2) the density and pressure gradients of the atmosphere in the main cluster, (3) the non-spherical shape of the subcluster, and (4) projection effects. The first two effects tend to bias the standoff distance in the same direction, pushing the bow shock closer to (farther away from) the subcluster during the pre- (post-)merger stages. Particularly, in the post-merger stage, the shock could be much farther away from the subcluster than predicted by a model of a body moving at a constant speed in a uniform medium. This implies that a combination of the standoff distance with measurements of the Mach number from density/temperature jumps can provide important information on the merger, e.g. differentiating between the pre- and post-merger stages.Comment: 11 pages, 12 figures. Including major revision and matched to accepted version in MNRA

Airborne Doppler radar detection of low altitude windshear

As part of an integrated windshear program, the Federal Aviation Administration, jointly with NASA, is sponsoring a research effort to develop airborne sensor technology for the detection of low altitude windshear during aircraft take-off and landing. One sensor being considered is microwave Doppler radar operating at X-band or above. Using a Microburst/Clutter/Radar simulation program, a preliminary feasibility study was conducted to assess the performance of Doppler radars for this application. Preliminary results from this study are presented. Analysis show, that using bin-to-bin Automatic Gain Control (AGC), clutter filtering, limited detection range, and suitable antenna tilt management, windshear from a wet microburst can be accurately detected 10 to 65 seconds (.75 to 5 km) in front of the aircraft. Although a performance improvement can be obtained at higher frequency, the baseline X-band system that was simulated detected the presence of a windshear hazard for the dry microburst. Although this study indicates the feasibility of using an airborne Doppler radar to detect low altitude microburst windshear, further detailed studies, including future flight experiments, will be required to completely characterize the capabilities and limitations