Three-meter balloon-borne telescope

The Three-Meter Balloon-Borne Telescope is planned as a general purpose facility for making far-infrared and submillimeter astronomical observations from the stratosphere. It will operate throughout the spectral range 30 microns to 1 millimeter which is largely obscurred from the ground. The design is an f/13.5 Cassegrain telescope with an f/1.33 3-meter primary mirror supported with a 3-axis gimbal and stabilization system. The overall structure is 8.0 m high by 5.5 m in width by 4.0 m in depth and weighs 2000 kg. This low weight is achieved through the use of an ultra lightweight primary mirror of composite construction. Pointing and stabilization are achieved with television monitoring of the star field, flex-pivot bearing supports, gyroscopes, and magnetically levitated reaction wheels. Two instruments will be carried on each flight; generally a photometric camera and a spectrometer. A 64-element bolometer array photometric camera operating from 30 to 300 microns is planned as part of the facility. Additional instruments will be derived from KAO and other development programs

Balloon-borne three-meter telescope for far-infrared and submillimeter astronomy

The scientific objectives, engineering analysis and design, results of technology development, and focal-plane instrumentation for a two-meter balloon-borne telescope for far-infrared and submillimeter astronomy are presented. The unique capabilities of balloon-borne observations are discussed. A program summary emphasizes the development of the two-meter design. The relationship of the Large Deployable Reflector (LDR) is also discussed. Detailed treatment is given to scientific objectives, gondola design, the mirror development program, experiment accommodations, ground support equipment requirements, NSBF design drivers and payload support requirements, the implementation phase summary development plan, and a comparison of three-meter and two-meter gondola concepts

Resolved Mid-Infrared Emission Around AB Aur and V892 Tau with Adaptive Optics Nulling Interferometric Observations

We present the results of adaptive optics nulling interferometric observations of two Herbig Ae stars, AB Aur and V892 Tau. Our observations at 10.3 microns show resolved circumstellar emission from both sources. Further analysis of the AB Aur emission suggests that there is an inclined disk surrounding the star. The diameter of the disk is derived to be 24 to 30 AU with an inclination of 45 to 65 degrees from face-on, and a major-axis PA of 30 +/- 15 degrees (E of N). Differences in the physical characteristics between the mid-IR emission and emission at other wavelengths (near-IR and millimeter), found in previous studies, suggest a complex structure for AB Aur's circumstellar environment, which may not be explained by a disk alone. The similarity in the observed size of AB Aur's resolved emission and that of another Herbig Ae star, HD 100546, is likely coincidental, as their respective evolutionary states and spectral energy distributions suggest significantly different circumstellar environments.Comment: 11 pages, 1 figure, Accepted for publication in ApJ Letter

Understanding the Catalytic Active Sites of Crystalline CoSbxOy for Electrochemical Chlorine Evolution

The chlorine evolution reaction (CER) is a key reaction in electrochemical oxidation (EO) of water treatment. Conventional anodes based on platinum group metals can be prohibitively expensive, which hinders further application of EO systems. Crystalline cobalt antimonate (CoSbxOy) was recently identified as a promising alternative to conventional anodes due to its high catalytic activity and stability in acidic media. However, its catalytic sites and reaction mechanism have not yet been elucidated. This study sheds light on the catalytically active sites in crystalline CoSbxOy anodes by using scanning electrochemical microscopy to compare the CER catalytic activities of a series of anode samples with different bulk Sb/Co ratios (from 1.43 to 2.80). The results showed that Sb sites served as more active catalytic sites than the Co sites. The varied Sb/Co ratios were also linked with slightly different electronic states of each element, leading to different CER selectivities in 30 mM chloride solutions under 10 mA cm–2 current density. The high activity of Sb sites toward the CER highlighted the significance of the electronic polarization that changed the oxidation states of Co and Sb

Effects of light and temperature on germination of Pyxidanthera brevifolia Wells (Diapensiaceae)

Pyxidanthera brevifolia is an evergreen semiwoody cushion plant endemic to the Sandhills of North and South Carolina, with the majority of populations occurring on Fort Bragg Military Reservation in North Carolina. Currently the species is listed as Endangered in North Carolina and is designated as a Species at Risk (SAR) by the US Department of Defense. Previous studies have suggested that seeds may not be viable because they failed to germinate under controlled conditions. Our objectives in this study were to attempt germination of Pyxidanthera brevifolia seeds, determine the best temperature conditions for germination, and understand more about germination requirements to aid in future restoration efforts. Using seeds that had been stored at room temperature for six months, we performed a germination experiment at the NCSU Phytotron with six treatments, all combinations of three temperature regimes (low (18 uC day / 14 uC night), medium (22/18 uC), and high (26/ 22 uC)) and two light conditions (light and dark). We monitored the experiment for 13 weeks, recording the number of seeds germinating per dish and the number of days to germination for seeds in each treatment. We found that Pxyidanthera brevifolia produces germinable seeds and that there are significant effects of light and temperature on germination. Highest germination occurred under low temperature and high light conditions (78%); the combination of high temperature and no light produced the lowest germination (6%). Seeds exposed to light germinated significantly earlier at the coolest temperature, compared to medium and high temperatures. These results indicate that it is possible to germinate seeds of this rare plant and suggest that germination of Pyxidanthera brevifolia likely occurs in late fall and is dependent on adequate light availability

Brønsted basicity of the air–water interface

Differences in the extent of protonation of functional groups lying on either side of water–hydrophobe interfaces are deemed essential to enzymatic catalysis, molecular recognition, bioenergetic transduction, and atmospheric aerosol–gas exchanges. The sign and range of such differences, however, remain conjectural. Herein we report experiments showing that gaseous carboxylic acids RCOOH(g) begin to deprotonate on the surface of water significantly more acidic than that supporting the dissociation of dissolved acids RCOOH(aq). Thermodynamic analysis indicates that > 6 H_(2)O molecules must participate in the deprotonation of RCOOH(g) on water, but quantum mechanical calculations on a model air–water interface predict that such event is hindered by a significant kinetic barrier unless OH− ions are present therein. Thus, by detecting RCOO− we demonstrate the presence of OH− on the aerial side of on pH > 2 water exposed to RCOOH(g). Furthermore, because in similar experiments the base (Me)_(3)N(g) is protonated only on pH 1 nm) deeper shear planes probed in electrophoresis, thereby implying the existence of OH− gradients in the interfacial region. This fact could account for the weak OH− signals detected by surface-specific spectroscopies