2,076 research outputs found
Electric dipole rovibrational transitions in HD molecule
The rovibrational electric dipole transitions in the ground electronic state
of the HD molecule are studied. A simple, yet rigorous formula is derived for
the transition rates in terms of the electric dipole moment function ,
which is calculated in a wide range of . Our numerical results for
transition rates are in moderate agreement with experiments and previous
calculations, but are at least an order of magnitude more accurate.Comment: 7 pages, 1 figur
Teleportation of a quantum state of a spatial mode with a single massive particle
Mode entanglement exists naturally between regions of space in ultra-cold
atomic gases. It has, however, been debated whether this type of entanglement
is useful for quantum protocols. This is due to a particle number
superselection rule that restricts the operations that can be performed on the
modes. In this paper, we show how to exploit the mode entanglement of just a
single particle for the teleportation of an unknown quantum state of a spatial
mode. We detail how to overcome the superselection rule to create any initial
quantum state and how to perform Bell state analysis on two of the modes. We
show that two of the four Bell states can always be reliably distinguished,
while the other two have to be grouped together due to an unsatisfied phase
matching condition. The teleportation of an unknown state of a quantum mode
thus only succeeds half of the time.Comment: 12 pages, 1 figure, this paper was presented at TQC 2010 and extends
the work of Phys. Rev. Lett. 103, 200502 (2009
Peak positions and shapes in neutron pair correlation functions from powders of highly anisotropic crystals
The effect of the powder average on the peak shapes and positions in neutron
pair distribution functions of polycrystalline materials is examined. It is
shown that for highly anisotropic crystals, the powder average leads to shifts
in peak positions and to non-Gaussian peak shapes. The peak shifts can be as
large as several percent of the lattice spacing
Benchmark performance of low-cost Sb2Se3 photocathodes for unassisted solar overall water splitting
Determining cost-effective semiconductors exhibiting desirable properties for commercial photoelectrochemical water splitting remains a challenge. Herein, we report a Sb2Se3 semiconductor that satisfies most requirements for an ideal high-performance photoelectrode, including a small band gap and favourable cost, optoelectronic properties, processability, and photocorrosion stability. Strong anisotropy, a major issue for Sb2Se3, is resolved by suppressing growth kinetics via close space sublimation to obtain high-quality compact thin films with favourable crystallographic orientation. The Sb2Se3 photocathode exhibits a high photocurrent density of almost 30mAcm(-2) at 0V against the reversible hydrogen electrode, the highest value so far. We demonstrate unassisted solar overall water splitting by combining the optimised Sb2Se3 photocathode with a BiVO4 photoanode, achieving a solar-to-hydrogen efficiency of 1.5% with stability over 10h under simulated 1 sun conditions employing a broad range of solar fluxes. Low-cost Sb2Se3 can thus be an attractive breakthrough material for commercial solar fuel production. While photoelectrochemical water splitting offers an integrated means to convert sunlight to a renewable fuel, cost-effective light-absorbers are rare. Here, authors report Sb2Se3 photocathodes for high-performance photoelectrochemical water splitting devices
Reactivity of Gold Hydrides: O2 Insertion into the AuâH Bond
Dioxygen reacts with the gold(I) hydride (IPr)AuH under insertion to give the hydroperoxide, (IPr)AuOOH, a long-postulated reaction in gold catalysis and the first demonstration of O2 activation by Au-H in a well-defined system. Subsequent condensation gave the peroxide (IPr)Au-OO-Au(IPr) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazole-2-ylidene). The reaction kinetics are reported, as well as the reactivity of Au(I) hydrides with radical scavengers
Study of relativistic bound states for scalar theories in Bethe-Salpeter and Dyson-Schwinger formalism
The Bethe-Salpeter equation for Wick-Cutkosky like models is solved in
dressed ladder approximation. The bare vertex truncation of the Dyson-Schwinger
equations for propagators is combined with the dressed ladder Bethe-Salpeter
equation for the scalar S-wave bound state amplitudes. With the help of
spectral representation the results are obtained directly in Minkowski space.
We give a new analytic formula for the resulting equation simplifying the
numerical treatment. The bare ladder approximation of Bethe-Salpeter equation
is compared with the one with dressed ladder. The elastic electromagnetic form
factors is calculated within the relativistic impulse approximation.Comment: 30 pages, 10 figures, accepted for publication in Phys. Rev.
The ZEUS Forward Plug Calorimeter with Lead-Scintillator Plates and WLS Fiber Readout
A Forward Plug Calorimeter (FPC) for the ZEUS detector at HERA has been built
as a shashlik lead-scintillator calorimeter with wave length shifter fiber
readout. Before installation it was tested and calibrated using the X5 test
beam facility of the SPS accelerator at CERN. Electron, muon and pion beams in
the momentum range of 10 to 100 GeV/c were used. Results of these measurements
are presented as well as a calibration monitoring system based on a Co
source.Comment: 38 pages (Latex); 26 figures (ps
Heavy quark supermultiplet excitations
Lorentz covariant wave functions for meson and baryon supermultiplets are
simply derived by boosting representations corresponding to
multiquark systems at rest.Comment: 12 pages (Revtex), UTAS-PHYS-93-4
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