Recent advances at NASA in calculating the electronic spectra of diatomic molecules

Advanced entry vehicles, such as the proposed Aero-assisted Orbital Transfer Vehicle, provide new and challenging problems for spectroscopy. Large portions of the flow field about such vehicles will be characterized by chemical and thermal nonequilibrium. Only by considering the actual overlap of the atomic and rotational lines emitted by the species present can the impact of radiative transport within the flow field be assessed correctly. To help make such an assessment, a new computer program is described that can generate high-resolution, line-by-line spectra for any spin-allowed transitions in diatomic molecules. The program includes the matrix elements for the rotational energy and distortion to the fourth order; the spin-orbit, spin-spin, and spin-rotation interactions to first order; and the lambda splitting by a perturbation calculation. An overview of the Computational Chemistry Branch at Ames Research Center is also presented

A new solid-state logarithmic radiometer

Combination of temperature-compensated logarithmic amplifiers and p-i-n photodiodes operating in zero-bias mode provides lightweight radiometer for detecting spectral intensities encompassing more than three decades over a range of at least 300 to 800 nanometers at low power levels

A search for 21 cm HI absorption in AT20G compact radio galaxies

We present results from a search for 21 cm associated HI absorption in a sample of 29 radio sources selected from the Australia Telescope 20 GHz survey. Observations were conducted using the Australia Telescope Compact Array Broadband Backend, with which we can simultaneously look for 21 cm absorption in a redshift range of 0.04 < z < 0.08, with a velocity resolution of 7 km/s . In preparation for future large-scale H I absorption surveys we test a spectral-line finding method based on Bayesian inference. We use this to assign significance to our detections and to determine the best-fitting number of spectral-line components. We find that the automated spectral-line search is limited by residuals in the continuum, both from the band-pass calibration and spectral-ripple subtraction, at spectral-line widths of \Deltav_FWHM > 103 km/s . Using this technique we detect two new absorbers and a third, previously known, yielding a 10 per cent detection rate. Of the detections, the spectral-line profiles are consistent with the theory that we are seeing different orientations of the absorbing gas, in both the host galaxy and circumnuclear disc, with respect to our line-of-sight to the source. In order to spatially resolve the spectral-line components in the two new detections, and so verify this conclusion, we require further high-resolution 21 cm observations (~0.01 arcsec) using very long baseline interferometry.Comment: 16 pages, 8 figures and 5 tables; accepted for publication in MNRAS (version 2 based on proof corrections

Finite Element Flow Simulations of the EUROLIFT DLR-F11 High Lift Configuration

This paper presents flow simulation results of the EUROLIFT DLR-F11 multi-element wing configuration, obtained with a highly scalable finite element solver, PHASTA. This work was accomplished as a part of the 2nd high lift prediction workshop. In-house meshes were constructed with increasing mesh density for analysis. A solution adaptive approach was used as an alternative and its effectiveness was studied by comparing its results with the ones obtained with other meshes. Comparisons between the numerical solution obtained with unsteady RANS turbulence model and available experimental results are provided for verification and discussion. Based on the observations, future direction for adaptive research and simulations with higher fidelity turbulence models is outlined.Comment: 52nd Aerospace Sciences Meetin

A selective transformation of enals into chiral γ-amino alcohols

A one-pot synthesis of chiral amino alcohols from α,β-unsaturated aldehydes is reported which circumvents competitive 1,2- versus 1,4-boryl addition, by means of using a sterically hindered amine-derived imine. In addition to the complete chemoselectivity, modification of the Cu(I) catalyst with readily available chiral diphosphines, such as (R)-DM-BINAP, gave the 1,4-boryl addition products with high levels of asymmetric induction

Science objectives and performance of a radiometer and window design for atmospheric entry experiments

This paper describes the techniques developed for measuring stagnation-point radiation in NASA's cancelled Aeroassist Flight Experiment (AFE). It specifies the need for such a measurement; the types and requirements for the needed instruments; the Radiative Heating Experiment (RHE) developed for the AFE; the requirements, design parameters, and performance of the window developed for the RHE; the procedures and summary of the technique; and results of the arc-jet wind tunnel experiment conducted to demonstrate the overall concept. Subjects emphasized are the commercial implications of the knowledge to be gained by this experiment in connection with the Aeroassisted Space Transfer Vehicle (ASTV), the nonequilibrium nature of the radiation, concerns over the contribution of vacuum-ultraviolet radiation to the overall radiation, and the limit on the flight environment of the vehicle imposed by the limitations on the window material. Results show that a technique exists with which the stagnation-point radiation can be measured in flight in an environment of interest to commercial ASTV applications

Practical synthetic strategies towards lipophilic 6-iodotetrahydroquinolines and -dihydroquinolines

The synthesis of novel tetrahydroquinolines (THQ) and dihydroquinolines (DHQ) are reported using three practical, scalable synthetic approaches to access highly lipophilic analogues bearing a 6-iodo substituent, each with a different means of cyclisation. A versatile and stable quinolin-2-one intermediate was identified, which could be reduced to the corresponding THQ with borane reagents, or to the DHQ with diisobutylaluminium hydride via a novel elimination that is more favourable at higher temperatures. Coupling these strongly electron-donating scaffolds to electron-accepting moieties caused the resulting structures to exhibit strong fluorescence