4,876 research outputs found

    Engineering a Conformant Probabilistic Planner

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    We present a partial-order, conformant, probabilistic planner, Probapop which competed in the blind track of the Probabilistic Planning Competition in IPC-4. We explain how we adapt distance based heuristics for use with probabilistic domains. Probapop also incorporates heuristics based on probability of success. We explain the successes and difficulties encountered during the design and implementation of Probapop

    Mn-Catalyzed Oxidation of Naphthalenediol

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    This study investigates the effects that manganese(IV) dioxide particles have on 2,3-naphthalenediol at varying pH levels (i.e., initial pH of 4.58, 5.85, and 8.75) and under different organic concentration conditions (4×10−3, 4×10−4, and 4×10−5 M), and assesses the importance of Mn oxides on abiotic catalysis of the multiple-ringed aromatic compound. Proton concentration affected the rates of reductive dissolution; as the pH values increased, the rate of reductive dissolution decreased, as predicted by theory. Also, as the concentration of naphthalenediol increased, the rate of reductive dissolution increased, although not proportionally; thus indicating that a majority of the active sites had been occupied. In addition, the results tend to confirm that electron transfer/organic release from the oxide surface is the rate-limiting step. This study demonstrates that in an oxic environment and in the presence of 2,3-naphthalenediol, MnO2 particles undergo reductive dissolution; in the process, naphthalenediol is oxidized. An oxidation by-product of reductive dissolution is an insoluble polymerized organic. The organic by-product was deep-brown in appearance, very similar to that of humified material. Using infrared spectroscopy, energy-dispersive x-ray analysis, and a microelemental analysis, the humified products appeared to be comprised mainly of constituents originating from naphthalenediol

    Global Properties of Neutral Hydrogen in Compact Groups

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    Compact groups of galaxies provide a unique environment to study the evolution of galaxies amid frequent gravitational encounters. These nearby groups have conditions similar to those in the earlier universe when galaxies were assembled and give us the opportunity to witness hierarchical formation in progress. To understand how the compact group environment affects galaxy evolution, we examine the gas and dust in these groups. We present new single-dish GBT neutral hydrogen (HI) observations of 30 compact groups and define a new way to quantify the group HI content as the HI-to-stellar mass ratio of the group as a whole. We compare the HI content with mid-IR indicators of star formation and optical [g-r] color to search for correlations between group gas content and star formation activity of individual group members. Quiescent galaxies tend to live in HI-poor groups, and galaxies with active star formation are more commonly found in HI-rich groups. Intriguingly, we also find "rogue" galaxies whose star formation does not correlate with group HI content. In particular, we identify three galaxies (NGC 2968 in RSCG 34, KUG 1131+202A in RSCG 42, and NGC 4613 in RSCG 64) whose mid-IR activity is discrepant with the HI. We speculate that this mismatch between mid-IR activity and HI content is a consequence of strong interactions in this environment that can strip HI from galaxies and abruptly affect star-formation. Ultimately, characterizing how and on what timescales the gas is processed in compact groups will help us understand the interstellar medium in complex, dense environments similar to the earlier Universe.Comment: Accepted to A

    Surface Enhanced Second Harmonic Generation from Macrocycle, Catenane, and Rotaxane Thin Films: Experiments and Theory

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    Surface enhanced second harmonic generation (SE SHG) experiments on molecular structures, macrocycles, catenanes, and rotaxanes, deposited as monolayers and multilayers by vacuum sublimation on silver, are reported. The measurements show that the molecules form ordered thin films, where the highest degree of order is observed in the case of macrocycle monolayers and the lowest in the case of rotaxane multilayers. The second harmonic generation activity is interpreted in terms of electric field induced second harmonic (EFISH) generation where the electric field is created by the substrate silver atoms. The measured second order nonlinear optical susceptibility for a rotaxane thin film is compared with that obtained by considering only EFISH contribution to SHG intensity. The electric field on the surface of a silver layer is calculated by using the Delphi4 program for structures obtained with TINKER molecular mechanics/dynamics simulations. An excellent agreement is observed between the calculated and the measured SHG susceptibilities.

    Book Reviews

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    GOVERNMENTAL REORGANIZATIONS: CASES AND COMMENTARY. Edited by Frederick C. Moshe. THE CHANGING LAW OF NATIONS: ESSAYS ON INTERNATIONAL LAW. By Josef L. Kunz. THE BOOM IN GOING BUST: THE GROWING SCANDAL IN PERSONAL BANKRUPTCY. By George Sullivan. INVISIBLE WITNESS: THE USE AND ABUSE OF THE NEW TECHNOLOGY OF CRIME INVESTIGATION. By William W. Turner

    Adventures of the Coupled Yang-Mills Oscillators: I. Semiclassical Expansion

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    We study the quantum mechanical motion in the x2y2x^2y^2 potentials with n=2,3n=2,3, which arise in the spatially homogeneous limit of the Yang-Mills (YM) equations. These systems show strong stochasticity in the classical limit (=0\hbar = 0) and exhibit a quantum mechanical confinement feature. We calculate the partition function Z(t)Z(t) going beyond the Thomas-Fermi (TF) approximation by means of the semiclassical expansion using the Wigner-Kirkwood (WK) method. We derive a novel compact form of the differential equation for the WK function. After separating the motion in the channels of the equipotential surface from the motion in the central region, we show that the leading higher-order corrections to the TF term vanish up to eighth order in \hbar, if we treat the quantum motion in the hyperbolic channels correctly by adiabatic separation of the degrees of freedom. Finally, we obtain an asymptotic expansion of the partition function in terms of the parameter g24t3g^2\hbar^4t^3

    Electron-impact ionization of atomic hydrogen at 2 eV above threshold

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    The convergent close-coupling method is applied to the calculation of fully differential cross sections for ionization of atomic hydrogen by 15.6 eV electrons. We find that even at this low energy the method is able to yield predictive results with small uncertainty. As a consequence we suspect that the experimental normalization at this energy is approximately a factor of two too high.Comment: 10 page

    Multimedia Environmental Pollutant Assessment System (MEPAS{reg_sign}): Groundwater pathway formulations

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    This report describes the mathematical formulations used for contaminant fate and transport in the groundwater pathway of the Multimedia Environmental Pollutant Assessment System (MEPAS). It is one in a series of reports that collectively describe the components of MEPAS. The groundwater component of the MEPAS methodology models solute transport through the groundwater environment (i.e., partially saturated and saturated zones). Specifically, this component provides estimates of groundwater contaminant fluxes at various transporting medium interfaces (e.g., water table or aquifer/river interface) and contaminant concentrations at withdrawal wells. Contaminant fluxes at transporting medium interfaces represent boundary conditions for the next medium in which contaminant migration and fate is to be simulated (e.g., groundwater contamination entering a surface-water environment). Contaminant concentrations at withdrawal wells provide contaminant levels for the exposure assessment component of MEPAS. A schematic diagram illustrating the groundwater environment is presented. The migration and fate of contaminants through the groundwater environment are described by the three-dimensional, advective-dispersive equation for solute transport. The results are based on semianalytical solutions (i.e., solutions that require numerical integration) that are well established in the scientific literature. To increase computational efficiency, limits of integration are also identified

    Gravitational waves from Sco X-1: A comparison of search methods and prospects for detection with advanced detectors

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    The low-mass X-ray binary Scorpius X-1 (Sco X-1) is potentially the most luminous source of continuous gravitational-wave radiation for interferometers such as LIGO and Virgo. For low-mass X-ray binaries this radiation would be sustained by active accretion of matter from its binary companion. With the Advanced Detector Era fast approaching, work is underway to develop an array of robust tools for maximizing the science and detection potential of Sco X-1. We describe the plans and progress of a project designed to compare the numerous independent search algorithms currently available. We employ a mock-data challenge in which the search pipelines are tested for their relative proficiencies in parameter estimation, computational efficiency, robust- ness, and most importantly, search sensitivity. The mock-data challenge data contains an ensemble of 50 Scorpius X-1 (Sco X-1) type signals, simulated within a frequency band of 50-1500 Hz. Simulated detector noise was generated assuming the expected best strain sensitivity of Advanced LIGO and Advanced VIRGO (4×10244 \times 10^{-24} Hz1/2^{-1/2}). A distribution of signal amplitudes was then chosen so as to allow a useful comparison of search methodologies. A factor of 2 in strain separates the quietest detected signal, at 6.8×10266.8 \times 10^{-26} strain, from the torque-balance limit at a spin frequency of 300 Hz, although this limit could range from 1.2×10251.2 \times 10^{-25} (25 Hz) to 2.2×10262.2 \times 10^{-26} (750 Hz) depending on the unknown frequency of Sco X-1. With future improvements to the search algorithms and using advanced detector data, our expectations for probing below the theoretical torque-balance strain limit are optimistic.Comment: 33 pages, 11 figure
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