40 research outputs found

    Composition dependence of ion diffusion coefficients in gas mixtures at arbitrary field strengths

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    Expressions for the diffusion coefficient of ions in gas mixtures are obtained from momentum transfer theory, and are given in terms of the diffusion coefficients and drift velocities of the ions in the pure component gases. Blanc's law holds exactly at all field strengths if the mean free time between collisions is independent of velocity (Maxwell model), but otherwise there may be either positive or negative deviations from Blanc's law at high fields. Such deviations are of comparable magnitude for the diffusion coefficients and the mobility, but are not identical. Specific cases of inverse-power potentials are treated in further detail, and some numerical examples are given for rigid-sphere interactions

    Composition dependence of ion transport coefficients in gas mixtures

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    A simple momentum-transfer theory for the composition dependence of ion mobilities and diffusion coefficients in gas mixtures at arbitrary field strengths is corrected, extended, and compared with a similar theory based on momentum and energy transfer, and with results based on direct solution of the Boltzmann equation by Kihara's method. Final equations are recommended for predicting composition dependences, given only results on ion mobilities and diffusion coefficients in the pure component gases

    Revised theory of transient mass fluctuations

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    Abstract Several publications during the last 10 years by Woodward and colleagues have indicated a theory, based on general relativity, that has: (1) predicted transient mass fluctuations; (2) cited a specific embodiments where a net average force would be present; (3) suggested a few ways that this theory might be tested in the laboratory; and (4) have reported such test results incorporating these embodiments. In this paper we show that: (1) the average force predicted by Woodward occurred only because of a neglected term in a product derivative, and that when the neglected term is correctly returned, the average force vanishes; (2) this vanishment of the average force occurs for arbitrary forcing functions, not just the sinusoidal one considered by Woodward; (3) the transient mass fluctuation, predicted by Woodward, was developed in a theory which neglected local gravitational and electrodynamic forces which are several dozen orders of magnitude greater; (4) a less incomplete theory considering local gravitational forces produces a vastly smaller transient mass fluctuation
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