472 research outputs found
Giant electrocaloric effect in thin film Pb Zr_0.95 Ti_0.05 O_3
An applied electric field can reversibly change the temperature of an
electrocaloric material under adiabatic conditions, and the effect is strongest
near phase transitions. This phenomenon has been largely ignored because only
small effects (0.003 K V^-1) have been seen in bulk samples such as
Pb0.99Nb0.02(Zr0.75Sn0.20Ti0.05)0.98O3 and there is no consensus on macroscopic
models. Here we demonstrate a giant electrocaloric effect (0.48 K V^-1) in 300
nm sol-gel PbZr0.95Ti0.05O3 films near the ferroelectric Curie temperature of
222oC. We also discuss a solid state device concept for electrical
refrigeration that has the capacity to outperform Peltier or magnetocaloric
coolers. Our results resolve the controversy surrounding macroscopic models of
the electrocaloric effect and may inspire ab initio calculations of
electrocaloric parameters and thus a targeted search for new materials.Comment: 5 pages, 4 figure
Octahedral tilting, monoclinic phase and the phase diagram of PZT
Anelastic and dielectric spectroscopy measurements on PZT close to the
morphotropic (MPB) and antiferroelectric boundaries provide new insight in some
controversial aspects of its phase diagram. No evidence is found of a border
separating monoclinic (M) from rhombohedral (R) phases, in agreement with
recent structural studies supporting a coexistence of the two phases over a
broad composition range x < 0.5, with the fraction of M increasing toward the
MPB. It is also discussed why the observed maximum of elastic compliance
appears to be due to a rotational instability of the polarisation and therefore
cannot be explained by extrinsic softening from finely twinned R phase alone,
but indicates the presence also of M phase, not necessarily homogeneous.
A new diffuse transition is found within the ferroelectric phase near x ~
0.1, at a temperature T_IT higher than the well established boundary T_T to the
phase with tilted octahedra. It is proposed that around T_IT the octahedra
start rotating in a disordered manner and finally become ordered below T_T. In
this interpretation, the onset temperature for octahedral tilting monotonically
increases up to the antiferroelectric transition of PbZrO3, and the depression
of T_T(x) below x = 0.18 would be a consequence of the partial relieve of the
mismatch between the cation radii with the initial stage of tilting below T_IT.Comment: submitted to J. Phys.: Condens. Matte
Influence of charged walls and defects on DC resistivity and dielectric relaxation in Cu-Cl boracite
Electrostatic model of atomic ordering in complex perovskite alloys
We present a simple ionic model which successfully reproduces the various
types of compositional long-range order observed in a large class of complex
insulating perovskite alloys. The model assumes that the driving mechanism
responsible for the ordering is simply the electrostatic interaction between
the different ionic species. A possible new explanation for the anomalous
long-range order observed in some Pb relaxor alloys, involving the proposed
existence of a small amount of Pb^4+ on the B sublattice, is suggested by an
analysis of the model.Comment: 4 pages, two-column style with 1 postscript figure embedded. Uses
REVTEX and epsf macros. Also available at
http://www.physics.rutgers.edu/~dhv/preprints/index.html#lb_orde
Robotic milking technologies and renegotiating situated ethical relationships on UK dairy farms
Robotic or automatic milking systems (AMS) are novel technologies that take over the labor of dairy farming and reduce the need for human-animal interactions. Because robotic milking involves the replacement of 'conventional' twice-a-day milking managed by people with a system that supposedly allows cows the freedom to be milked automatically whenever they choose, some claim robotic milking has health and welfare benefits for cows, increases productivity, and has lifestyle advantages for dairy farmers. This paper examines how established ethical relations on dairy farms are unsettled by the intervention of a radically different technology such as AMS. The renegotiation of ethical relationships is thus an important dimension of how the actors involved are re-assembled around a new technology. The paper draws on in-depth research on UK dairy farms comparing those using conventional milking technologies with those using AMS. We explore the situated ethical relations that are negotiated in practice, focusing on the contingent and complex nature of human-animal-technology interactions. We show that ethical relations are situated and emergent, and that as the identities, roles, and subjectivities of humans and animals are unsettled through the intervention of a new technology, the ethical relations also shift. © 2013 Springer Science+Business Media Dordrecht
Ethics, space, and somatic sensibilities: comparing relationships between scientific researchers and their human and animal experimental subjects
Drawing on geographies of affect and nature-society relations, we propose a radical rethinking of how scientists, social scientists, and regulatory agencies conceptualise human and animal participants in scientif ic research. The scientific rationale for using animal bodies to simulate what could be done in human bodies emphasises shared somatic capacities that generate comparable responses to clinical interventions. At the same time, regulatory guidelines and care practices stress the differences between human and animal subjects. In this paper we consider the implications of this differentiation between human and animal bodies in ethical and welfare protocols and practices. We show how the bioethical debates around the use of human subjects tend to focus on issues of consent and language, while recent work in animal welfare reflects an increasing focus on the affectual dimensions of ethical practice. We argue that this attention to the more-than-representational dimensions of ethics and welfare might be equally important for human subjects. We assert that paying attention to these somatic sensibilities can offer insights into how experimental environments can both facilitate and restrict the development of more care-full and response-able relations between researchers and their experimental subjects. <br/
Hydrogen Sulfide Is a Novel Protector of the Retinal Glycocalyx and Endothelial Permeability Barrier
This is the final version. Available on open access from Frontiers Media via the DOI in this recordData Availability Statement:
The original contributions presented in the study are included in the article/supplementary material. The raw data supporting the conclusions of this article will be made available by the authors, without undue reservation.Significantly reduced levels of the anti-inflammatory gaseous transmitter hydrogen sulfide (H2S) are observed in diabetic patients and correlate with microvascular dysfunction. H2S may protect the microvasculature by preventing loss of the endothelial glycocalyx. We tested the hypothesis that H2S could prevent or treat retinal microvascular endothelial dysfunction in diabetes. Bovine retinal endothelial cells (BRECs) were exposed to normal (NG, 5.5 mmol/L) or high glucose (HG, 25 mmol/L) ± the slow-release H2S donor NaGYY4137 in vitro. Glycocalyx coverage (stained with WGA-FITC) and calcein-labeled monocyte adherence were measured. In vivo, fundus fluorescein angiography (FFA) was performed in normal and streptozotocin-induced (STZ) diabetic rats. Animals received intraocular injection of NaGYY4137 (1 μM) or the mitochondrial-targeted H2S donor AP39 (100 nM) simultaneously with STZ (prevention) or on day 6 after STZ (treatment), and the ratio of interstitial to vascular fluorescence was used to estimate apparent permeability. NaGYY4137 prevented HG-induced loss of BREC glycocalyx, increased monocyte binding to BRECs (p ≤ 0.001), and increased overall glycocalyx coverage (p ≤ 0.001). In rats, the STZ-induced increase in apparent retinal vascular permeability (p ≤ 0.01) was significantly prevented by pre-treatment with NaGYY4137 and AP39 (p < 0.05) and stabilized by their post-STZ administration. NaGYY4137 also reduced the number of acellular capillaries (collagen IV + /IB4-) in the diabetic retina in both groups (p ≤ 0.05). We conclude that NaGYY4137 and AP39 protected the retinal glycocalyx and endothelial permeability barrier from diabetes-associated loss of integrity and reduced the progression of diabetic retinopathy (DR). Hydrogen sulfide donors that target the glycocalyx may therefore be a therapeutic candidate for DR.Medical Research Council (MRC)British Heart FoundationRoyal SocietyBrian Ridge ScholarshipNational Eye Research CentreMasonic Charitable Foundatio
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