2,540 research outputs found

    An Investigation of the Use of Bandwidth Criteria for Rotorcraft Handling-Qualities Specifications

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    The objective of this study was to investigate bandwidth concepts for deriving rotorcraft handling-qualities criteria from data obtained in two simulator experiments conducted at the Aeromechanics Laboratory. The first experiment was an investigation of the effects of helicopter vertical-thrust-response characteristics on handling qualities; the second experiment investigated the effects of helicopter yaw-control-response characteristics. In both experiments, emphasis was on low-speed Nap-of-the-Earth (NOE) tasks

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    Electronics and Chemistry: Varying Single Molecule Junction Conductance Using Chemical Substituents

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    We measure the low bias conductance of a series of substituted benzene diamine molecules while breaking a gold point contact in a solution of the molecules. Transport through these substituted benzenes is by means of nonresonant tunneling or superexchange, with the molecular junction conductance depending on the alignment of the metal Fermi level to the closest molecular level. Electron-donating substituents, which drive the occupied molecular orbitals up, increase the junction conductance, while electron-withdrawing substituents have the opposite effect. Thus for the measured series, conductance varies inversely with the calculated ionization potential of the molecules. These results reveal that the occupied states are closest to the gold Fermi energy, indicating that the tunneling transport through these molecules is analogous to hole tunneling through an insulating film.Comment: 14 pages, 4 figure

    Formation and Evolution of Single Molecule Junctions

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    We analyze the formation and evolution statistics of single molecule junctions bonded to gold electrodes using amine, methyl sulfide and dimethyl phosphine link groups by measuring conductance as a function of junction elongation. For each link, maximum elongation and formation probability increase with molecular length, strongly suggesting that processes other than just metal-molecule bond breakage play a key role in junction evolution under stress. Density functional theory calculations of adiabatic trajectories show sequences of atomic-scale changes in junction structure, including shifts in attachment point, that account for the long conductance plateau lengths observed.Comment: 10 pages, 4 figures, submitte
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