4,546 research outputs found

    Model for quantitative tip-enhanced spectroscopy and the extraction of nanoscale-resolved optical constants

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    Near-field infrared spectroscopy by elastic scattering of light from a probe tip resolves optical contrasts in materials at dramatically sub-wavelength scales across a broad energy range, with the demonstrated capacity for chemical identification at the nanoscale. However, current models of probe-sample near-field interactions still cannot provide a sufficiently quantitatively interpretation of measured near-field contrasts, especially in the case of materials supporting strong surface phonons. We present a model of near-field spectroscopy derived from basic principles and verified by finite-element simulations, demonstrating superb predictive agreement both with tunable quantum cascade laser near-field spectroscopy of SiO2_2 thin films and with newly presented nanoscale Fourier transform infrared (nanoFTIR) spectroscopy of crystalline SiC. We discuss the role of probe geometry, field retardation, and surface mode dispersion in shaping the measured near-field response. This treatment enables a route to quantitatively determine nano-resolved optical constants, as we demonstrate by inverting newly presented nanoFTIR spectra of an SiO2_2 thin film into the frequency dependent dielectric function of its mid-infrared optical phonon. Our formalism further enables tip-enhanced spectroscopy as a potent diagnostic tool for quantitative nano-scale spectroscopy.Comment: 19 pages, 9 figure

    A Phase Transition between Small and Large Field Models of Inflation

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    We show that models of inflection point inflation exhibit a phase transition from a region in parameter space where they are of large field type to a region where they are of small field type. The phase transition is between a universal behavior, with respect to the initial condition, at the large field region and non-universal behavior at the small field region. The order parameter is the number of e-foldings. We find integer critical exponents at the transition between the two phases.Comment: 21 pages, 8 figure

    Calibration of a solid state nuclear track detector (SSNTD) with high detection threshold to search for rare events in cosmic rays

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    We have investigated a commercially available polymer for its suitability as a solid state nuclear track detector (SSNTD). We identified that polymer to be polyethylene terephthalate (PET) and found that it has a higher detection threshold compared to many other widely used SSNTDs which makes this detector particularly suitable for rare event search in cosmic rays as it eliminates the dominant low Z background. Systematic studies were carried out to determine its charge response which is essential before any new material can be used as an SSNTD. In this paper we describe the charge response of PET to 129Xe, 78Kr and 49Ti ions from the REX-ISOLDE facility at CERN, present the calibration curve for PET and characterize it as a nuclear track detector
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