The Impact of Roaming Radicals on the Combustion Properties of Transportation Fuels

A systematic investigation on the effects of roaming radical reactions on global combustion properties for transportation fuels is presented. New software was developed that can automatically discover all the possible roaming pathways within a given chemical kinetic mechanism. This novel approach was applied to two mechanisms taken from the literature, one for heptane and one for butanol. Ignition delay times and laminar flame speeds were computed over a broad range of conditions, while testing varying degrees of roaming. As the degree of roaming is increased, the ignition delays increased, consistent with the hypothesis that roaming decreases the reactivity of the system. The percent increase in the ignition delay is strongly temperature dependent, with the largest effect seen in the negative temperature coefficient regime. Outside of this temperature range, the effect of roaming on global combustion properties is small, on the order of a few percent for ignition delays and less than a percent for flame speeds. The software that was used to create the new mechanisms and test the effects of roaming on combustion properties are freely available, with detailed tutorials that will enable it to be applied to fuels other than heptane and butanol.Comment: 25 pages, 6 figures; added hydroperoxide decomposition pathways, repeated analysis, regenerated results, expanded discussio

Technology and Urban Management. Semiannual Report, October 1, 1967 through March 31, 1968

The projects under Technology and Urban Management (TAUM) have continued during the last few months with considerable success. The individual studies conducted in the City of Oakland and the progress made are described in this report

Stopping Sexual Harassment in the Empire State: Past, Present, and a Possible Future

This report maps current patterns of workplace sexual harassment and their impact in New York State. It also provides a broader frame for understanding how efforts to confront sexual and gender-based harassment and assault have evolved over time, and charts possible directions for future organizing, policy, and research in New York and beyond. The findings presented here are drawn from the 2018 Empire State Poll, an annual statewide survey of 800 New Yorkers conducted by the Cornell Survey Research Institute. Questions added to the survey reflecting existing legal definitions of workplace sexual harassment reveal the following: 10.9 percent of New York residents have experienced quid pro quo workplace sexual harassment, and 21.9 percent have experienced workplace sexual harassment that created a hostile work environment; 31.1 percent of women and 18.9 percent of men have experienced at least one of these forms of harassment. 13.9 percent of people of color and people of Hispanic origin have experienced quid pro quo workplace sexual harassment, as opposed to 8.5 percent of non-Hispanic whites. 38.9 percent of those experiencing at least one form of workplace sexual harassment say it impacted their work or careers; 48.9 percent who experienced quid pro quo harassment reported such an impact. 83.4 percent of New York residents think their leaders should do more to address workplace sexual harassment. There is notable variation by politics and ideology, but regardless of worldview, strong majorities think leaders should do more. In addition to sharing the survey findings, the report discusses experiences and responses of survivors and how they are shaped by different identities and relations of power. It highlights black women’s leadership in propelling wide-reaching shifts in law and culture; efforts initiated by diverse survivors to effect change in specific industries; and culture change work engaging men and women as allies

Physical States and String Symmetries

It is shown that if the momenta belong to an integral lattice, then every physical state of string theory leads to a symmetry of the scattering amplitudes. We discuss the role of this symmetry when the momenta are those provided by the usual D.D.F construction and show that the string compactified on the torus associated with the self-dual Lorentzian lattice, $\Pi^{25,1}$ possess the Fake Monster Lie algebra as a symmetry.Comment: 14 pages, ( Some references are added.

A New Massive Type IIA Supergravity From Compactification

We consider the most general form for eleven dimensional supersymmetry compatible with on-shell superfields. This allows for the introduction of a conformal Spin(1,10) connection. In eleven dimensional Minkowski space this modification is trivial and can be removed by a field redefinition, however, upon compactification on S^1 it is possible to introduce a non-trivial `Wilson line'. The resulting ten dimensional supergravity has massive 1-form and 3-form potentials and a cosmological constant. This theory does not possess a supersymmetric eightbrane soliton but it does admit a supersymmetric non-static cosmological solution.Comment: 13 pages, phyzzx. The introduction is clarifed and a reference adde

Estimates from a Consumer Demand System: Implications for the Incidence of Environmental Taxes

Most studies suggest that environmental taxes are regressive, and thus are unattractive policy options. We consider the distributional effects of a gasoline tax increase using three welfare measures and under three scenarios for gas tax revenue use. To incorporate behavioral responses we use Consumer Expenditure Survey data to estimate a consumer demand system that includes gasoline, other goods, and leisure. We find that the gas tax is regressive, but that returning the revenue through a lump-sum transfer more than offsets this, yielding a net increase in progressivity. We also find that ignoring behavioral changes in distributional calculations overstates both the overall burden of the tax and its regressivity.