Design and test of a 100 ampere-hour nickel cadmium battery module

A feasibility study was conducted on the design and construction of a flight-worthy replaceable battery module consisting of four 100 A.H. nickel-cadmium rechargeable cells for large manned space vehicles. The module is planned to weigh less than 43 pounds and be fully maintainable in a zero-g environment by one man without use of special tools. An active environmental control system was designed for the temperature control of the module

Evidence for Crystal-Field Splitting in Surface-Atom Photoemission from Potassium

Photoemission spectra from the shallow 3p3/2 core levels of the surface atoms of metallic potassium exhibit the effects of a small but measurable crystal-field splitting of ∼38 meV. It manifests itself mainly as an apparent angle-dependent modulation of the spin-orbit splitting. This phenomenon may, in general, interfere with accurate determinations of surface-atom core-level shifts

Ta(110) Surface and Subsurface Core-level Shifts and 4f7/2 Lineshapes

High-resolution 4f core-level spectra of the Ta(110) surface region have been obtained at 80 and 300 K with 70- and 100-eV synchrotron radiation. The data show that the subsurface core-level binding-energy shift (compared to deeper-lying atoms) for a close-packed bcc(110) surface can be substantial: 65±15 meV for the first underlayer atoms of Ta(110). The surface core-level shift is 360±12 meV at 80 K and decreases by 13±2 meV at 300 K. Final-state screening in both the bulk and surface layers is well described by a constant singularity index of 0.133±0.012. An enhanced phonon broadening at the surface corresponds to a reduced perpendicular Debye temperature for the surface atoms of 128±18 K compared to the bulk Debye temperature of 225 K

Surface Core-Level Phonon Broadening of Li(110)

High-resolution core-level photoemission data from the 1s level of Li(110) have been obtained between 77 and 280 K. Analysis of the data reveals a significant difference in the zero-temperature phonon broadening between the bulk and surface atoms but only a small difference in the effective surface and bulk Debye temperatures. This latter result is in good agreement with an embedded-atom-method calculation of the bulk and surface Debye temperatures of Li. Implications of these results to surface core-level phonon broadening and surface lattice dynamics of the heavier alkali metals are discussed

Using mean field theory to determine the structure of uniform fluids

The structure of a uniform simple liquid is related to that of a reference fluid with purely repulsive intermolecular forces in a self-consistently determined external reference field (ERF) phi_ R. The ERF can be separated into a harshly repulsive part phi_ R0 generated by the repulsive core of a reference particle fixed at the origin and a more slowly varying part phi_ R1 arising from a mean field treatment of the attractive forces. We use a generalized linear response method to calculate the reference fluid structure, first determining the response to the smoother part phi_ R1 of the ERF alone, followed by the response to the harshly repulsive part. Both steps can be carried out very accurately, as confirmed by MD simulations, and good agreement with the structure of the full LJ fluid is found.Comment: 11 pages, 7 figure

3D imaging of natural volcanic ash fragments and comparison with experimentally-vesiculated volcanic glass

Volcanic particles in ash clouds can cause adverse effects on human health as well as having the potential to cause critical damage to aircraft. In order to improve understanding of the underlying causes for the damage caused by volcanic particles we examined their appearance in 3D using confocal microscopy. We present here results of 3D imaging of volcanic glass particles from two Icelandic volcanoes together with experimentally-vesiculated volcanic glass. True colour 3D images were obtained using an Olympus LEXT 3D laser scanning reflectance confocal microscope. The images show bubble structure, fracture patterns, shape morphology and characteristics of grains. Simulated fragments and bubbles compare well with real material from the Icelandic events, with similar overall bubble sizes. 3D laser confocal microscopy imaging of volcanic glass fragments helps in examining the structure of volcanic particles and hence has the potential of leading to improved understanding of their potential impact

Quasi-Moessbauer effect in two dimensions

Expressions for the absorption spectrum of a nucleus in a three- and a two-dimensional crystal respectively are obtained analytically at zero and at finite temperature respectively. It is found that for finite temperature in two dimensions the Moessbauer effect vanishes but is replaced by what we call a Quasi-Moessbauer effect. Possibilities to identify two-dimensional elastic behavior are discussed.Comment: 18 pages, 5 figures, notation simplifie

Model of a fluid at small and large length scales and the hydrophobic effect

We present a statistical field theory to describe large length scale effects induced by solutes in a cold and otherwise placid liquid. The theory divides space into a cubic grid of cells. The side length of each cell is of the order of the bulk correlation length of the bulk liquid. Large length scale states of the cells are specified with an Ising variable. Finer length scale effects are described with a Gaussian field, with mean and variance affected by both the large length scale field and by the constraints imposed by solutes. In the absence of solutes and corresponding constraints, integration over the Gaussian field yields an effective lattice gas Hamiltonian for the large length scale field. In the presence of solutes, the integration adds additional terms to this Hamiltonian. We identify these terms analytically. They can provoke large length scale effects, such as the formation of interfaces and depletion layers. We apply our theory to compute the reversible work to form a bubble in liquid water, as a function of the bubble radius. Comparison with molecular simulation results for the same function indicates that the theory is reasonably accurate. Importantly, simulating the large length scale field involves binary arithmetic only. It thus provides a computationally convenient scheme to incorporate explicit solvent dynamics and structure in simulation studies of large molecular assemblies

Enhanced Vibrational Broadening of Core-Level Photoemission from the Surface of Na(110)

High-resolution temperature-dependent photoemission data from Na 2p core levels reveal substantially larger phonon broadening in the first atomic layer of Na(110) than in the bulk. We show that the enhanced width is due primarily to the excitation of relatively soft phonon modes perpendicular to the surface. Soft surface-phonon modes also account for previously reported but uninterpreted broadening of transition-metal surface-atom core levels