Nanocrystalline TiO₂‑Catalyzed Photoreversible Color Switching

We report a novel photoreversible color switching system based on the photocatalytic activity of TiO₂ nanocrystals and the redox-driven color switching property of methylene blue (MB). This system rapidly changes from blue to colorless under UV irradiation and recovers its original blue color under visible light irradiation. We have identified four major competing reactions that contribute to the photoreversible switching, among which two are dominant: the decoloration process is mainly driven by the reduction of MB to leuco MB by photogenerated electrons from TiO₂ nanocrystals under UV irradiation, and the recoloration process operates by the TiO₂-induced self-catalyzed oxidation of LMB under visible irradiation. Compared with the conventional color switching systems based on photoisomerization of chromophores, our system has not only low toxicity but also significantly improved switching rate and cycling performance. It is envisioned that this photoreversible system may promise unique opportunities for many light-driven actuating or color switching applications

Porous TiO₂/C Nanocomposite Shells As a High-Performance Anode Material for Lithium-Ion Batteries

Porous TiO₂/C nanocomposite shells with high capacity, excellent cycle stability, and rate performance have been prepared. The synthesis involves coating colloidal TiO₂ nanoshells with a resorcinol-formaldehyde (RF) layer with controllable thickness through a sol–gel-like process, and calcining the composites at 700 °C in an inert atmosphere to induce crystallization from amorphous TiO₂ to anatase and simultaneous carbonization from RF to carbon. The cross-linked RF polymer contributes to the high stability of the shell morphology and the porous nature of the shells. A strong dependence of the capacity on the amount of incorporated carbon has been revealed, allowing the optimization of the electrode structure for high-rate cell performance

Coassembly of Mixed Weakley-Type Polyoxometalates to Novel Nanoflowers with Tunable Fluorescence for the Detection of Toluene

In this work, three-dimensional nanoflowers with tunable fluorescent properties constructed with mixed Weakley-type polyoxometalates (POMs, Na₉[LnW₁₀O₃₆]·32H₂O, Ln = Eu, Tb, abbreviated to LnW₁₀) and tetraethylenepentamine (TEPA) have been successfully prepared through a facile ionic self-assembly (ISA) method. The shape and petal size of the nanoflower as well as its fluorescent behaviors can be tuned through varying the ratio of EuW₁₀/TbW₁₀. The varied-temperature emission behaviors at 80–260 K show that the fluorescent intensity of both Tb³⁺ and Eu³⁺ decreased with the increase in temperature, which makes them potential luminescent ratiometric thermometers. Moreover, after being mixed with polydimethylsiloxane (PDMS), the as-formed hybrid films showed stable fluorescence along with good transparency. The robustness of the hybrid films was also demonstrated by corrosion resistance upon treatment with strong acid and alkali and thus can be used as a sensor to detect toluene circularly. Our results provide a new avenue to the facile construction of fluorescent composites and demonstrate that the POM complexes can be further used in supramolecular chemistry and nanomaterials

Reversible Assembly and Dynamic Plasmonic Tuning of Ag Nanoparticles Enabled by Limited Ligand Protection

Dynamic manipulation of optical properties through the reversible assembly of plasmonic nanoparticles offers great opportunities for practical applications in many fields. The previous success, however, has been limited to Au nanoparticles. Reversible assembly and plasmonic tuning of Ag nanoparticles (AgNPs) have remained a significant challenge due to difficulty in finding an appropriate surface agent that can effectively stabilize the particle surface and control their interactions. Here, we overcome the challenge by developing a limited-ligand-protection (LLP) strategy for introducing poly­(acrylic acid) with precisely controlled coverage to the AgNP surface to not only sufficiently stabilize the nanoparticles but also enable effective control over the surface charge and particle interaction through pH variation. The as-synthesized AgNPs can be reversibly assembled and disassembled and accordingly display broadly tunable coupling of plasmonic properties. Compared to the Au-based system, the success in the reversible assembly of AgNPs represents a significant step toward practical applications such as colorimetric pressure sensing because they offer many advantages, including broader spectral tuning range, higher color contrast, a one-pot process, and low materials and production cost. This work also highlights LLP as a new avenue for controlling the interparticle forces, their reversible assembly, and dynamic coupling of physical properties

Photocatalytic Color Switching of Transition Metal Hexacyanometalate Nanoparticles for High-Performance Light-Printable Rewritable Paper

Developing efficient photoreversible color switching systems for constructing rewritable paper is of significant practical interest owing to the potential environmental benefits including forest conservation, pollution reduction, and resource sustainability. Here we report that the color change associated with the redox chemistry of nanoparticles of Prussian blue and its analogues could be integrated with the photocatalytic activity of TiO₂ nanoparticles to construct a class of new photoreversible color switching systems, which can be conveniently utilized for fabricating ink-free, light printable rewritable paper with various working colors. The current system also addresses the phase separation issue of the previous organic dye-based color switching system so that it can be conveniently applied to the surface of conventional paper to produce an ink-free light printable rewritable paper that has the same feel and appearance as the conventional paper. With its additional advantages such as excellent scalability and outstanding rewriting performance (reversibility >80 times, legible time >5 days, and resolution >5 μm), this novel system can serve as an eco-friendly alternative to regular paper in meeting the increasing global needs for environment protection and resource sustainability